Abstract An oligomer or a mixture of organopolysiloxane oligomers is polymerized in the presence of a strong acid, e.g. trifluoromethane sulfonic acid, as the catalyst to give an organopolysiloxane containing a considerable amount of silanolic hydroxy groups at the molecular chain ends. Thereafter, the mixture is admixed with water and a hexaorganodisilazane or triorganosilyl amine compound in combination so as to neutralize the acid catalyst by the ammonia produced by the hydrolysis of the disilazane or silyl amine compound with simultaneous silylation of the terminal hydroxy groups. Thus, the organopolysiloxane contains a greatly decreased amount of the residual silanolic hydroxy groups at the molecular chain ends to be imparted with remarkably improved heat stability.
A method for the preparation of an organopolysiloxane which comprises: (a) polymerizing an organopolysiloxane oligomer or a mixture of organopolysiloxane oligomers in a mixture containing a strong acid as a catalyst to give an organopolysiloxane; and (b) admixing the mixture with water and an organosilicon compound selected from the class consisting of hexaorganodisilazanes represented by the general formula (R 1 3 Si) 2 NH and triorganosilyl amine compounds represented by the general formula R 1 3 SiNHR 2 , in which each of the groups denoted by R 1 and R 2 is, independently from the others, a substituted or unsubstituted monovalent hydrocarbon group, in an amount sufficient to neutralize the strong acid as the catalyst and to ailylate the terminal silanol groups at the molecular chain ends of the organopolysiloxane.
Claim 2
Independent Claim
131 words
A method for the preparation of an organopolysiloxane which comprises: (a) polymerizing an organopolysiloxane oligomer or a mixture of organopolysiloxane oligomers in a mixture containing a strong acid as a catalyst to give an organopolysiloxane; and (b) admixing the mixture with water and an organosilicon compound selected from the class consisting of hexaorganodisilazanes represented by the general formula (R 1 3 Si) 2 NH and triorganosilyl amine compounds represented by the general formula R 1 3 SiNHR 2 , in which each of the groups denoted by R 1 and R 2 is, independently from the others, a substituted or unsubstituted monovalent hydrocarbon group, in an amount sufficient to neutralize the strong acid as the catalyst and to ailylate the terminal silanol groups at the molecular chain ends of the organopolysiloxane.
Claim 3
Dependent Claim
45 words
The method for the preparation of an organopolysiloxane as claimed in claim 1 wherein the amounts of water and the organosilicon compound added to the mixture are each in the range from 1 to 5 moles per mole of the strong acid as the catalyst.
Claim 4
Dependent Claim
24 words
The method for the preparation of an organopolysiloxane as claimed in claim 1 wherein the strong acid as the catalyst is trifluoromethane sulfonic acid.