US4721828A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Methane conversion
Assignee: Atlantic Richfield Co
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Filing: 1984-10-31
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Granted: 1988-01-26
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Expires: 2004-10-31
Abstract
Abstract A method for synthesizing hydrocarbons from a methane source which comprises contacting methane with a reducible oxide of Fe. The iron oxide is preferably combined with an amount of alkali and/or alkaline earth metal which is sufficient to improve the selectively to higher hydrocarbon products. The oxide is reduced by the contact which is carried at about 500° to 1000° C. Reducible oxides of Fe are regenerated by oxidizing the reduced composition with oxygen. The oxide Fe 3 O 4 is particularly effective in the process. Bulk iron oxides promoted by sodium and/or compounds thereof are particularly preferred contact solids.
Inventors
- 👤 Howard P. Withers
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 02:40
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/14; B01J23/08; B01J23/10; B01J23/16; B01J23/18; B01J23/32; B01J23/34; B01J27/00; B01J27/14; B01J27/16; B01J27/18; C; C07; C07C; C07C2/00; C07C2/76; C07C2/82; C07C2/84; C07C2523/00; C07C2523/10; C07C2523/38; C07C2523/40; C07C2523/46; C07C2523/70; C07C2523/74; C07C2523/745; C07C2527/00; C07C2527/14; C07C2527/16; C07C2527/18; Y; Y10; Y10S; Y10S585/00; Y10S585/929; Y10S585/943
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
168 words
A method for synthesizing hydrocarbons from a methane source which comprises: (a) contacting at a temperature within the range of about 500°-1000° C. a gas comprising methane and a solid comprising: (1) a reducible oxide of Fe and (2) at least one member of the group consisting of alkali metals, alkaline earth metals, and compounds thereof in an amount sufficient to improve the selectivity to higher hydrocarbons, said contacting producing C 2 + hydrocarbons, coproduct water and solids comprising a reduced Fe oxide, provided that when said solid comprises an alkaline earth metal or compound thereof, said contacting is carried out in the substantial absence of catalytically effective Ni, Rh, Pd, Ag, Os, Ir, Pt, Au and compounds thereof; (b) recovering C 2 + hydrocarbons; (c) at least periodically contacting the solids comprising reduced Fe oxide with an oxygen-containing gas to produce a solid comprising a reducible Fe oxide; and (d) contacting a gas comprising methane with the solids produced in step (c) as recited in step (a).
Claim 2
Independent Claim
168 words
A method for synthesizing hydrocarbons from a methane source which comprises: (a) contacting at a temperature within the range of about 500°-1000° C. a gas comprising methane and a solid comprising: (1) a reducible oxide of Fe and (2) at least one member of the group consisting of alkali metals, alkaline earth metals, and compounds thereof in an amount sufficient to improve the selectivity to higher hydrocarbons, said contacting producing C 2 + hydrocarbons, coproduct water and solids comprising a reduced Fe oxide, provided that when said solid comprises an alkaline earth metal or compound thereof, said contacting is carried out in the substantial absence of catalytically effective Ni, Rh, Pd, Ag, Os, Ir, Pt, Au and compounds thereof; (b) recovering C 2 + hydrocarbons; (c) at least periodically contacting the solids comprising reduced Fe oxide with an oxygen-containing gas to produce a solid comprising a reducible Fe oxide; and (d) contacting a gas comprising methane with the solids produced in step (c) as recited in step (a).
Claim 3
Dependent Claim
19 words
The method of claim 1 wherein the said solid of step (a) comprises an alkali metal or compound thereof.
Claim 4
Dependent Claim
29 words
The method of claim 2 wherein the said solid of step (a) comprises an alkali metal or compound thereof on a support consisting essentially of said reducible Fe oxide.
Claim 5
Dependent Claim
21 words
The method of claim 1 wherein the temperature of step (c) is within the range of about 300° to 1200° C.
Claim 6
Dependent Claim
20 words
The method of claim 1 wherein the gas comprising methane contains from about 40 to about 100 volume percent methane.
Claim 7
Dependent Claim
20 words
The method of claim 1 wherein the gas comprising methane contains from about 80 to about 100 volume percent methane.
Claim 8
Dependent Claim
20 words
The method of claim 1 wherein the gas comprising methane contains from about 90 to about 100 volume percent methane.
Claim 9
Dependent Claim
13 words
The method of claim 1 wherein the gas comprising methane is natural gas.
Claim 10
Dependent Claim
14 words
The method of claim 1 wherein the gas comprising methane is processed natural gas.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-01-25 | 1991-07-27 | 1992-01-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-01-25 | 1995-07-27 | 1996-01-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-01-25 | 1999-07-27 | 2000-01-26 | $7700.00 | Window Closed / Lapsed |