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US4721540A Expired / Lapsed US ⏱️ 0.0 years remaining

Low density single crystal super alloy

Assignee: Cannon Muskegon Corp
•
Filing: 1984-12-04
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Granted: 1988-01-26
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Expires: 2004-12-04
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Abstract

Abstract A single crystal nickel alloy is provided having many of the foundry and performance characteristics of the higher density, single crystal, nickel base super alloys from which the vanes and blades are cast for high performance turbine aircraft engines. The lower density of this alloy permits its use for rebuilding and upgrading the performance of older turbine aircraft engines of designs which cannot withstand the centrifugal forces generated by the new state of the art higher density single crystal super alloys. The alloy for the first time provides a lower density single crystal alloy capable of heat treatment to stabilize its microstructure for high temperature, high stress use. It also provides for the first time a lower density alloy having acceptable resistance to the effects of high temperature sulfidation, salt corrosion and also to have good coating life. By significant changes in the alloy composition the resulting alloy has creep rupture and stress rupture performance characteristics similar to that of the high density nickel base super alloys while maintaining a density characteristic of equiaxe alloys.

Inventors

  • 👤 Kenneth Harris
  • 👤 Gary L. Erickson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 03:25
CPC Classifications
C; C30; C30B; C30B21/00; C30B29/00; C30B29/10; C30B29/52

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 120 words
A single crystal turbine engine blade or vane characterized by its resistance to creep and microstructural stability when operated under high temperature, high stress conditions and capability of being heat treated to effect total solutioning of the gamma prime while maintaining a thermal differential of approximately 20° F. (11° C.) between the final solutioning temperature and the incipient melting temperature, cast from an alloy consisting essentially of the nominal composition (wt/% or wt ppm): ______________________________________ Cr 9.8 C 33 ppm Co 5.0 V <10 ppm Mo 3.0 B <30 ppm Al 4.85 Zr <75 ppm Ti 4.75 Hf .11 Ta 2.0 Al + Ti 9.60 W <.02 Ni Balance ______________________________________ and having a density of 0.288 lbs/cu. in. (7.98 gms/cc).
Claim 2
Dependent Claim 120 words
A single crystal turbine engine blade or vane characterized by its resistance to creep and microstructural stability when operated under high temperature, high stress conditions and capability of being heat treated to effect total solutioning of the gamma prime while maintaining a thermal differential of approximately 20° F. (11° C.) between the final solutioning temperature and the incipient melting temperature, cast from an alloy consisting essentially of the nominal composition (wt/% or wt ppm): ______________________________________ Cr 9.8 C 33 ppm Co 5.0 V <10 ppm Mo 3.0 B <30 ppm Al 4.85 Zr <75 ppm Ti 4.75 Hf .11 Ta 2.0 Al + Ti 9.60 W <.02 Ni Balance ______________________________________ and having a density of 0.288 lbs/cu. in. (7.98 gms/cc).
Claim 3
Dependent Claim 126 words
A single crystal turbine engine blade characterized by its resistance to creep and microstructural stability when operated under high temperature, high stress conditions and capability of being heat treated to effect total solutioning of the gamma prime and substantial solutioning of the gamma/gamma prime eutectic, while maintaining a thermal differential of approximately 20° F. (11° C.) between the final solutioning temperature and the incipient melting temperature cast from an alloy consisting essentially of the nominal composition (wt/% or wt ppm); ______________________________________ Cr 9.8 C 33 ppm Co 5.0 V <10 ppm Mo 3.0 B <30 ppm Al 4.85 Zr <75 ppm Ti 4.75 Hf 0.11 Ta 2.0 Al + Ti 9.60 W <.02 Ni Balance ______________________________________ and having a density of 0.288 lbs/cu. in. (7.98 gms/cc).
Claim 4
Dependent Claim 126 words
A single crystal turbine engine blade characterized by its resistance to creep and microstructural stability when operated under high temperature, high stress conditions and capability of being heat treated to effect total solutioning of the gamma prime and substantial solutioning of the gamma/gamma prime eutectic, while maintaining a thermal differential of approximately 20° F. (11° C.) between the final solutioning temperature and the incipient melting temperature cast from an alloy consisting essentially of the nominal composition (wt/% or wt ppm); ______________________________________ Cr 9.8 C 33 ppm Co 5.0 V <10 ppm Mo 3.0 B <30 ppm Al 4.85 Zr <75 ppm Ti 4.75 Hf 0.11 Ta 2.0 Al + Ti 9.60 W <.02 Ni Balance ______________________________________ and having a density of 0.288 lbs/cu. in. (7.98 gms/cc).
Claim 5
Dependent Claim 133 words
A single crystal turbine engine blade characterized by its resistance to creep and microstructural stability when operated under high temperature, high stress conditions and having a liquidus of 2410° F. (1321° C.) and totally solutioned gamma prime and substantially solutioned gamma/gamma prime eutectic after solutioning for three hours at 2260° F. (1238° C.) plus three hours at 2320° F. (1271° C.) plus three hours at 2330° F. (1272° C.) with total absence of incipient melting, cast from an alloy consisting essentially of the nominal composition (wt/% or wt ppm): ______________________________________ Cr 9.8 C 33 ppm Co 5.0 V <10 ppm Mo 3.0 B <30 ppm Al 4.85 Zr <75 ppm Ti 4.75 Hf 0.11 Ta 2.0 Al + Ti 9.60 W <.02 Ni Balance ______________________________________ and having a density of 0.188 lbs/cu. in.
Claim 6
Dependent Claim 133 words
A single crystal turbine engine blade characterized by its resistance to creep and microstructural stability when operated under high temperature, high stress conditions and having a liquidus of 2410° F. (1321° C.) and totally solutioned gamma prime and substantially solutioned gamma/gamma prime eutectic after solutioning for three hours at 2260° F. (1238° C.) plus three hours at 2320° F. (1271° C.) plus three hours at 2330° F. (1272° C.) with total absence of incipient melting, cast from an alloy consisting essentially of the nominal composition (wt/% or wt ppm): ______________________________________ Cr 9.8 C 33 ppm Co 5.0 V <10 ppm Mo 3.0 B <30 ppm Al 4.85 Zr <75 ppm Ti 4.75 Hf 0.11 Ta 2.0 Al + Ti 9.60 W <.02 Ni Balance ______________________________________ and having a density of 0.188 lbs/cu. in.
Claim 7
Dependent Claim 219 words
A single crystal turbine engine blade or vane characterized by a density of 0.288 lb/cu. in., (7.98 gms/cc) its resistance to creep and microstructural stability under an operating condition equivalent to 51.0 ksi/1600° F. (351.6 MPa/870° C.) for 620.8 hrs. after solutioning sufficient to totally solution its gamma prime and substantially solution its gamma/gamma prime eutectic without any incipient melting, cast from an alloy consisting essentially of the composition: ______________________________________ Cr 9.5/10.3 Co 4.7/5.3 Mo 2.8/3.2 Al 4.7/4.9 Ti 4.6/4.8 Ta 1.8/2.2 W 0.10 max C 150 ppm max V 0.10 max B 50 ppm max Zr 100 ppm max Hf 0.0/0.12 Al + Ti 9.3/9.7 Ni Balance Si 0.05 max Mn 0.05 max Fe 0.25 max Cb 0.10 max Cu 0.01 max N 16 ppm max O 12 ppm max S 20 ppm max Mg 0.01 max Pb 2 ppm max Ag 2 ppm max Bi 0.3 ppm max Se 0.5 ppm max Te 0.3 ppm max Tl 0.3 ppm max Ga 25 ppm max Cd 2 ppm max Sn 25 ppm max Zn 5 ppm max Na 25 ppm max K 25 ppm max Sb 3 ppm max Au 2 ppm max In 2 ppm max Ge 2 ppm max As 5 ppm max Hg 3 ppm max Th 5 ppm max U 5 ppm max ______________________________________
Claim 8
Dependent Claim 219 words
A single crystal turbine engine blade or vane characterized by a density of 0.288 lb/cu. in., (7.98 gms/cc) its resistance to creep and microstructural stability under an operating condition equivalent to 51.0 ksi/1600° F. (351.6 MPa/870° C.) for 620.8 hrs. after solutioning sufficient to totally solution its gamma prime and substantially solution its gamma/gamma prime eutectic without any incipient melting, cast from an alloy consisting essentially of the composition: ______________________________________ Cr 9.5/10.3 Co 4.7/5.3 Mo 2.8/3.2 Al 4.7/4.9 Ti 4.6/4.8 Ta 1.8/2.2 W 0.10 max C 150 ppm max V 0.10 max B 50 ppm max Zr 100 ppm max Hf 0.0/0.12 Al + Ti 9.3/9.7 Ni Balance Si 0.05 max Mn 0.05 max Fe 0.25 max Cb 0.10 max Cu 0.01 max N 16 ppm max O 12 ppm max S 20 ppm max Mg 0.01 max Pb 2 ppm max Ag 2 ppm max Bi 0.3 ppm max Se 0.5 ppm max Te 0.3 ppm max Tl 0.3 ppm max Ga 25 ppm max Cd 2 ppm max Sn 25 ppm max Zn 5 ppm max Na 25 ppm max K 25 ppm max Sb 3 ppm max Au 2 ppm max In 2 ppm max Ge 2 ppm max As 5 ppm max Hg 3 ppm max Th 5 ppm max U 5 ppm max ______________________________________

References Cited (Backward Citations)

US4222794A Cited
US4459160A Cited
US4582548A Cited
US4402772A Cited
US4543235A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-01-25 1991-07-27 1992-01-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-01-25 1995-07-27 1996-01-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-01-25 1999-07-27 2000-01-26 $7700.00 Window Closed / Lapsed

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