Stable ammonium polyphosphate liquid fertilizer from merchant grade phosphoric acid

Claim 2

A stable ammonium polyphosphate liquid fertilizer prepared by reaction of ammonia with concentrated wet-process phosphoric acid having a P205 concentration of 54 to 62 weight percent with substantially all of the P205 therein being in ortho form, said wet-process phosphoric acid prior to concentration having been contacted with a cation exchange resin to remove magnesium and calcium without appreciable reduction of iron and aluminum, said concentrated acid still containing on a weight percent basis referenced to 60% P205: (i) 1.0% or greater iron and aluminum calculated as Fe203 and Al203, (ii) less than 0.3% magnesium calculated as MgO, and (iii) less than 0.15% total of sodium, potassium and calcium calculated as Na20, K20, and CaO, said liquid fertilizer being further characterized by remaining substantially sludge-free when stored at 25° C. for 6 months without addition of any sequestering or suspending agent.

Claim 3

The liquid fertilizer of claim 1 in which from 35 to 65% of the phosphate therein is in polyphosphate form.

Claim 4

The liquid fertilizer of claim 1 in which said iron and aluminum are still present in the concentrated acid in amounts greater than 1.5% by weight referenced to 60% P205.

Claim 5

A stable ammonium polyphosphate liquid fertilizer prepared by reaction of ammonia with concentrated wet-process phosphoric acid having a P205 concentration of 54 to 62% weight percent with substantially all of the P205 therein being in ortho form, said wet-process phosphoric acid prior to concentration having been contacted with a cation exchange resin to remove magnesium and calcium without appreciable reduction of iron and aluminum, said concentrated acid containing iron, aluminum, magnesium, calcium, sodium, and potassium in the following amounts referenced to 60% P205: ______________________________________ Calculated as Weight % ______________________________________ Fe2O3 0.5 to 2.5 Al2O3 1 to 2.5 MgO Below 0.3 CaO Below 0.04 Na2O Below 0.05 K2O Below 0.03 ______________________________________ said liquid fertilizer being further characterized by remaining sludge-free when stored at 25° C. for 6 months without addition of any sequestering or suspending agent.

Claim 6

A stable ammonium polyphosphate liquid fertilizer prepared by reaction of ammonia with concentrated wet-process phosphoric acid having a P205 concentration of 54 to 62% weight percent with substantially all of the P205 therein being in ortho form, said wet-process phosphoric acid prior to concentration having been contacted with a cation exchange resin to remove magnesium and calcium without appreciable reduction of iron and aluminum, said concentrated acid containing iron, aluminum, magnesium, calcium, sodium, and potassium in the following amounts referenced to 60% P205: ______________________________________ Calculated as Weight % ______________________________________ Fe2O3 0.5 to 2.5 Al2O3 1 to 2.5 MgO Below 0.3 CaO Below 0.04 Na2O Below 0.05 K2O Below 0.03 ______________________________________ said liquid fertilizer being further characterized by remaining sludge-free when stored at 25° C. for 6 months without addition of any sequestering or suspending agent.

Claim 7

The liquid fertilizer of claim 4 in which from 35 to 65% of the phosphate therein is in polyphosphate form.

Claim 8

The liquid fertilizer of claim 4 in which said concentrated acid contains from 56 to 62% P205.

Claim 9

The liquid fertilizer of claim 6 in which from 40 to 55% of the phosphate therein is in polyphosphate form.

Claim 10

The liquid fertilizer of claim 1 which contains on a weight basis substantially 10% N and 34% P205 to provide a 10-34-0 fertilizer.

Claim 11

The liquid fertilizer of claim 4 which contains on a weight basis substantially 10% N and 34% P205 to provide a 10-34-0 fertilizer.

Claim 12

The liquid fertilizer of claim 1 which contains on a weight percent basis substantially 11% N and 37% P205 to provide an 11-37-0 fertilizer.

Claim 13

The liquid fertilizer of claim 4 which contains on a weight percent basis substantially 11% N and 37% P205 to provide an 11-37-0 fertilizer.

Claim 14

A liquid fertilizer as defined in claim 1 which has not over 65% of the phosphate therein in polyphosphate form.

Claim 15

A liquid fertilizer as defined in claim 1 which has not over 55% of the phosphate therein in polyphosphate form.