US4720515A
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Epoxy resin composition for encapsulating semiconductor
Assignee: Denka Co Ltd
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Filing: 1986-05-16
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Granted: 1988-01-19
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Expires: 2006-05-16
Abstract
Abstract An epoxy resin composition is provided for encapsulating a semiconductor. The resin composition contains an epoxy resin, a phenol resin, a phenol-modified silicon-containing compound and an inorganic filler. The phenol-modified silicon-containing compound is obtained by reacting a first and/or second organic silicone compound (formulae (1-a), (1-b) and (2)) with an organic silicon compound (formula (3)) and with a phenol resin: ##STR1## wherein X stands for an organic group containing an epoxy group, Y for a polyoxyalkylene group and Z for a mercapto group, an amino group or a ureido group.
Inventors
- 👤 Masatoshi Iji
- 👤 Masayuki Kobayashi
- 👤 Shinichiro Asai
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 08:51
CPC Classifications
H; H01; H01B; H01B3/00; H01B3/18; H01B3/30; H01B3/40; C; C08; C08L; C08L63/00
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
311 words
An epoxy resin composition for encapsulating a semiconductor comprising: (a) an epoxy resin; (b) a phenol resin; (c) a phenol-modified silicon-containing compound obtained by reacting an organic silicone compound selected from the group consisting of a first organic silicone compound having an epoxy equivalent of from 500 to 20,000 and a molecular weight of from 2,000 to 200,000 represented by the following formulae (1-a) and (1-b), a second organic silicone compond having an epoxy equivalent of from 500 to 20,000 annd a molecular weight of from 2,000 to 200,000 represented by the following formula (2), and mixtures of said first and second organic silicone compounds, with from 0.2 to 10 molar equivalents of an organic silicon compound represented by the following formula (3) per molar equivalent of the epoxy group of the compound of the formulae (1-a), (1-b) and (2) and with a phenol resin; ##STR12## wherein in the formulae (1-a), (1-b) and (2) R 1 stands for a hydrogen atom, a methyl group, an ethyl group or a phenyl group, R2 for an alkylene group having 1 to 5 carbon atoms, X for an organic group containing an epoxy group, Y is a polyoxyalkylene group having a polymerization degree of from 5 to 500 and stands for a polyoxyethylene group, a polyoxypropylene group and a copolymer group thereof, and l, m, n, o and p each represents an integer; and wherein the formula (3) Z is a functional group reactable with an epoxy group and stands for a mercapto group, an amino group or a ureido group, R 3 for an alkylene group having 2 to 5 carbon atoms, R 4 for a methyl group or an ethyl group and q is 0, 1 or 2; and (d) an inorganic filler, wherein 5 to 50 parts by weight of (c) is present for each 100 parts by weight of (a).
Claim 2
Dependent Claim
311 words
An epoxy resin composition for encapsulating a semiconductor comprising: (a) an epoxy resin; (b) a phenol resin; (c) a phenol-modified silicon-containing compound obtained by reacting an organic silicone compound selected from the group consisting of a first organic silicone compound having an epoxy equivalent of from 500 to 20,000 and a molecular weight of from 2,000 to 200,000 represented by the following formulae (1-a) and (1-b), a second organic silicone compond having an epoxy equivalent of from 500 to 20,000 annd a molecular weight of from 2,000 to 200,000 represented by the following formula (2), and mixtures of said first and second organic silicone compounds, with from 0.2 to 10 molar equivalents of an organic silicon compound represented by the following formula (3) per molar equivalent of the epoxy group of the compound of the formulae (1-a), (1-b) and (2) and with a phenol resin; ##STR12## wherein in the formulae (1-a), (1-b) and (2) R 1 stands for a hydrogen atom, a methyl group, an ethyl group or a phenyl group, R2 for an alkylene group having 1 to 5 carbon atoms, X for an organic group containing an epoxy group, Y is a polyoxyalkylene group having a polymerization degree of from 5 to 500 and stands for a polyoxyethylene group, a polyoxypropylene group and a copolymer group thereof, and l, m, n, o and p each represents an integer; and wherein the formula (3) Z is a functional group reactable with an epoxy group and stands for a mercapto group, an amino group or a ureido group, R 3 for an alkylene group having 2 to 5 carbon atoms, R 4 for a methyl group or an ethyl group and q is 0, 1 or 2; and (d) an inorganic filler, wherein 5 to 50 parts by weight of (c) is present for each 100 parts by weight of (a).
Claim 3
Dependent Claim
22 words
The epoxy resin composition according to claim 1, wherein said epoxy resin (a) has at least two epoxy bonds in one molecule.
Claim 4
Dependent Claim
32 words
The epoxsy resin composition according to claim 2, wherein said epoxy resin (a) is selected from the group consisting of bisphenol-A epoxy resins, phenol novolak epoxy resins and cresol novolak epoxy resins.
Claim 5
Dependent Claim
27 words
The epoxy resin composition according to claim 1, wherein said phenol resin (b) is selected from the group consistint of phenol novolak resins and cresol novolak resins.
Claim 6
Dependent Claim
56 words
The epoxy resin composition according to claim 1, wherein each of said first asnd seocnd organic silicone compounds has a terminal group selected from the group consisting of --OR, --R, --OSi(R) 3 and --Si(R) 3 (wherein R is a hydrogen atom, an alkyl group, an aryl group, an epoxy-containing organic group or a vinyl-containing organic group).
Claim 7
Dependent Claim
36 words
The epoxy resin composition according to claim 1, wherein said phenol resin used in the preparation of said phenol-modified silicon-containing compound (c) is selected from the group consisting of phenol novolak resins and cresol novolak resins.
Claim 8
Dependent Claim
38 words
The epoxy resin composition according to claim 1, wherein 50 wt % or more of the epoxy groups contained in said first and/or second organic silicone compounds are reacted with said phenol resin and said organic silicon compound.
Claim 9
Dependent Claim
37 words
The epoxy resin composition according to claim 1, wherein said inorganic filler (d) is selected from the group consisting of crystalline silica, fused silica, calcium silicate, alumina, calcium carbonate, talc, barium sulfate, fiber glass and mixtures thereof.
Claim 10
Dependent Claim
34 words
The epoxy resin composition according to claim 1, wherein 100 parts by weight of the resinous ingredients of said composition are mixed with 150 to 900 parts by weight of said inorganic filler (d).
Claim 11
Dependent Claim
44 words
The epoxy resin composition according to claim 1, wherein said inorganic filler (d) comprises 5 to 100 wt % of a first filler (I) having substantially no fractured faces, and 95 to 0 wt % of a second filler (II) having substantially fractured faces.
Claim 12
Dependent Claim
29 words
The epoxy resin composition according to claim 10, wherein said first filler (I) has a shape selected from the group consisting of spherical, oval, gourd-like, tubular and bar-like shapes.
Claim 13
Dependent Claim
30 words
The epoxy resin composition according to claim 10, wherein each of said first and second fillers (I) and (II) has an average particle size of from 0.5 to 150 microns.
Claim 14
Dependent Claim
32 words
The epoxy resin composition according to claim 10, wherein each of said first and second fillers (I) and (II) has a specific surface area of from 0.1 to 15 m 2 /g.
Claim 15
Dependent Claim
82 words
The epoxy resin composition according to claim 10, wherein each of said first and second fillers (I) and (II) has a particle size distribution of: ______________________________________
Particle Size wt %
______________________________________
less than 1 micron 0 to 5
1 to less than 10 microns
1 to 40
10 to less than 30 microns
5 to 40
30 to less than 60 microns
5 to 60
60 to less than 90 microns
2 to 30
90 to 150 microns 0 to 10
______________________________________
Claim 16
Dependent Claim
36 words
The epoxy resin composition according to claim 1, further comprising an additive selected from the group consisting of a silane coupling agent, a curing accelerator, a releasing agent, a flame retarding agent and a mixture thereof.
References Cited (Backward Citations)
US4291144A
Cited
JPS56160055A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-01-18 | 1991-07-20 | 1992-01-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-01-18 | 1995-07-20 | 1996-01-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-01-18 | 1999-07-20 | 2000-01-19 | $7700.00 | Window Closed / Lapsed |