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US4719266A Expired / Lapsed US ⏱️ 0.0 years remaining

Vulcanization formulations with cobalt compounds

Assignee: Goodyear Tire and Rubber Co
•
Filing: 1986-07-22
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Granted: 1988-01-12
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Expires: 2006-07-22
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Abstract

Abstract The use of metal salts in vulcanizable elastomer compounds is described. In sufficient amounts, the metal salts function as both vulcanization accelerators and adhesion promoters for rubber to metal adhesion, thus eliminating the need for a separate ingredient for each purpose. Certain of the salts also promote the adhesion of the elastomer to metal adherends which have heretofore been unknown, for example, to a zinc surface. Curing characteristics of elastomer formulations using the metal salts are comparable to those using prior art accelerators.

Inventors

  • 👤 David P. Craig

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 20:50
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/04; C08J5/10; C08K; C08K3/00; C08K3/10; C08K3/11; C08K5/00; C08K5/04; C08K5/09; C08K5/098; C08J2321/00; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T428/31692; Y10T428/31696; Y10T428/31707

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 132 words
An elastomer formulation, consisting essentially of: a sulfur curable elastomer selected from the group consisting of natural rubber, copolymers of styrene and butadiene, polybutadiene, synthetic polyisoprene, and chlorinated rubbers; a quantity of sulfur; conventional compounding ingredients other than accelerators; and at least one cobalt salt accelerator consisting essentially of a salt selected from the group consisting of cobalt octoate, cobalt naphthenate, cobalt sterate, cobalt abietate and cobalt hydroxide, said at least one cobalt salt accelerator being present in the formulation in an amount of from about 2 to about 12 parts per 100 parts by weight of said elastomer, said at least one cobalt salt accelerator being the sole accelerator present; said formulation being curable and adherent to the surface of a metal selected from the group consisting of steel and zinc.
Claim 2
Dependent Claim 132 words
An elastomer formulation, consisting essentially of: a sulfur curable elastomer selected from the group consisting of natural rubber, copolymers of styrene and butadiene, polybutadiene, synthetic polyisoprene, and chlorinated rubbers; a quantity of sulfur; conventional compounding ingredients other than accelerators; and at least one cobalt salt accelerator consisting essentially of a salt selected from the group consisting of cobalt octoate, cobalt naphthenate, cobalt sterate, cobalt abietate and cobalt hydroxide, said at least one cobalt salt accelerator being present in the formulation in an amount of from about 2 to about 12 parts per 100 parts by weight of said elastomer, said at least one cobalt salt accelerator being the sole accelerator present; said formulation being curable and adherent to the surface of a metal selected from the group consisting of steel and zinc.
Claim 3
Dependent Claim 28 words
An elastomer formulation according to claim 1, wherein said at least one cobalt salt accelerator is selected from the group consisting of cobalt abietate, cobalt naphthenate,and cobalt hydroxide.
Claim 4
Dependent Claim 13 words
An elastomer formulation according to claim 1 wherein said elastomer is natural rubber.
Claim 5
Dependent Claim 33 words
A formulation according to claim 1, wherein said metal comprises a plurality of wires embedded in said formulation; and wherein the vulcanized formulation is used in the manufacture of a reinforced rubber article.
Claim 6
Dependent Claim 35 words
A formulation according to claim 1, wherein at least one cobalt salt accelerator is cobalt naphthenate present in said formulation in an amount of from about 4 to about 7 parts per hundred parts elastomer.

References Cited (Backward Citations)

CA609120A Cited
GB993045A Cited
GB1389800A Cited
US3993847A Cited
US4203874A Cited
EP0031398A2 Cited
US4549594A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-01-11 1991-07-13 1992-01-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-01-11 1995-07-13 1996-01-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-01-11 1999-07-13 2000-01-12 $7700.00 Window Closed / Lapsed

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