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US4718748A Expired / Lapsed US ⏱️ 0.0 years remaining

Optical glass fibre having a synthetic resin cladding and method of manufacturing same

Assignee: US Philips Corp
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Filing: 1985-03-04
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Granted: 1988-01-12
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Expires: 2005-03-04
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Abstract

Abstract The invention provides an optical glass fibre having a synthetic resin cladding and a method of manufacturing same, in which the first layer of the synthetic resin cladding is formed from a curable polysiloxane composition. The curing rate is increased by the presence of acrylate groups. The refractive index (exceeding 1.46) and the glass transition temperature (lower than -50° C.) can be adjusted by the ratio of the dimethyl siloxane groups, methyl phenyl siloxane groups and diphenyl siloxane groups present. The curing rate can furthermore be increased by the addition of monomeric acrylate compounds.

Inventors

  • 👤 Dirk J. Broer
  • 👤 Grietje N. Mol

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 18:32
CPC Classifications
C; C03; C03C; C03C25/00; C03C25/10; C03C25/104; C03C25/106; C08; C08L; C08L83/00; C08L83/04; C08L83/06; C08L83/10; G; G02; G02B; G02B6/00; G02B6/02; G02B6/02395; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/2962; Y10T428/2964

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 232 words
An optical fibre having a synthetic resin cladding, comprising a glass fibre and an enveloping layer of a synthetic rubber having a refractive index which is higher than the refractive index of the outermost layer of the glass fibre, the synthetic rubber being formed from a curable synthetic resin composition which comprises a copolymer which has monomeric units comprising dimethyl siloxane and at least one siloxane selected from the group consisting of methyl phenyl siloxane and diphenyl siloxane, characterized in that the copolymer is a compound of the formula ##STR3## where R 1 and R 8 are organic groups which are selected from the group consisting of alkyl groups, aryl groups and acrylate-containing alkyl groups, wherein R 2 , R 3 , R 4 , R 6 and R 7 are organic groups which are selected from the group consisting of alkyl groups and aryl groups, and wherein R 5 is an acrylate-containing organic group, the average molecular weight of the polymer molecules being between 1,000 and 1,000,000, the average fractions of the monomeric units per polymer molecule being within the following limits: ______________________________________ 0.005 ≦ p ≦ 0.995 0≦ q ≦ 0.995 0≦ r ≦ 0.49 0≦ s ≦ 0.1 ______________________________________ wherein 0.005≦(q+2r)≦0.995 and wherein the monomeric units may be distributed in the molecule blockwise, alternatingly or randomly and in which the copolymer comprises at least two acrylate groups per molecule.
Claim 2
Dependent Claim 232 words
An optical fibre having a synthetic resin cladding, comprising a glass fibre and an enveloping layer of a synthetic rubber having a refractive index which is higher than the refractive index of the outermost layer of the glass fibre, the synthetic rubber being formed from a curable synthetic resin composition which comprises a copolymer which has monomeric units comprising dimethyl siloxane and at least one siloxane selected from the group consisting of methyl phenyl siloxane and diphenyl siloxane, characterized in that the copolymer is a compound of the formula ##STR3## where R 1 and R 8 are organic groups which are selected from the group consisting of alkyl groups, aryl groups and acrylate-containing alkyl groups, wherein R 2 , R 3 , R 4 , R 6 and R 7 are organic groups which are selected from the group consisting of alkyl groups and aryl groups, and wherein R 5 is an acrylate-containing organic group, the average molecular weight of the polymer molecules being between 1,000 and 1,000,000, the average fractions of the monomeric units per polymer molecule being within the following limits: ______________________________________ 0.005 ≦ p ≦ 0.995 0≦ q ≦ 0.995 0≦ r ≦ 0.49 0≦ s ≦ 0.1 ______________________________________ wherein 0.005≦(q+2r)≦0.995 and wherein the monomeric units may be distributed in the molecule blockwise, alternatingly or randomly and in which the copolymer comprises at least two acrylate groups per molecule.
Claim 3
Dependent Claim 19 words
An optical glass fibre as claimed in claim 1, characterized in that R 5 is an acrylate-containing alkyl group.
Claim 4
Dependent Claim 15 words
An optical glass fibre as claimed in claim 1, characterized in that s exceeds 0.02.
Claim 5
Dependent Claim 29 words
An optical glass fibre as claimed in claim 1, characterized in that r and s are equal to zero and R 1 and R 8 are acrylate-containing alkyl groups.
Claim 6
Dependent Claim 37 words
An optical glass fibre as claimed in claim 1, characterized in that R 5 is an acrylate-containing polysiloxane chain of the same type and of the same average composition as the main chain of the polymer molecule.
Claim 7
Dependent Claim 20 words
An optical glass fibre as claimed in claim 1, characterized in that (q+2r) is between the limits 0.25 and 0.6.
Claim 8
Dependent Claim 20 words
An optical glass fibre as claimed in claim 6, characterized in that (q+2r) is between the limits 0.4 and 0.6.
Claim 9
Dependent Claim 27 words
An optical glass fibre as claimed in claim 1, characterized in that the curable synthetic resin composition comprises 1 to 5% by weight of the photosensitive initiator.
Claim 10
Dependent Claim 27 words
An optical glass fibre as claimed in claim 8, characterized in that the photosensitive initiator is selected from the group consisting of 2,2-dimethoxy-2-phenyl acetophenone, 2,2,diethoxy-acetophenone and 2,2-dimethyl-2-hydroxy-acetophenone.
Claim 11
Dependent Claim 30 words
An optical glass fibre as claimed in claim 1, characterized in that the curable synthetic resin composition comprises 0 to 20% by weight of one or more monomeric acrylate compounds.
Claim 12
Dependent Claim 33 words
An optical glass fibre as claimed in claim 10, characterized in that the monomeric acrylate compounds are selected from the group consisting of hexanediol diacrylate, 2-ethoxy-ethyl acrylate, 2'-ethoxy-2-ethoxy-ethyl acrylate and trimethylol propane triacrylate.

References Cited (Backward Citations)

SU293013A1 Cited
CA653550A Cited
US3865588A Cited
US4270840A Cited
US4344669A Cited
US4348454A Cited
US4496210A Cited
US4472021A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-01-11 1991-07-13 1992-01-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-01-11 1995-07-13 1996-01-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-01-11 1999-07-13 2000-01-12 $7700.00 Window Closed / Lapsed

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