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US4717434A Expired / Lapsed US ⏱️ 0.0 years remaining

Zirconium alloy products

Assignee: Westinghouse Electric Co LLC
•
Filing: 1986-03-12
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Granted: 1988-01-05
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Expires: 2006-03-12
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Abstract

Abstract It has been found that modifying standard Zircaloy alloy processing techniques by limiting the working and annealing temperatures utilized after conventional beta treatment results in Zircaloy alloy product having superior high temperature steam corrosion resistance.

Inventors

  • 👤 Samuel G. McDonald
  • 👤 George P. Sabol

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-10 01:58
CPC Classifications
C; C22; C22F; C22F1/00; C22F1/16; C22F1/18; C22F1/186; G; G21; G21C; G21C3/00; G21C3/02; G21C3/04; G21C3/06; G21C3/07; Y; Y02; Y02E; Y02E30/00; Y02E30/30; Y10; Y10S; Y10S148/00; Y10S148/902; Y10S148/909; Y10S376/00; Y10S376/90

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 93 words
A final size Zircaloy alloy, nuclear fuel cladding tube comprising: said Zircaloy alloy selected from the group consisting of Zircaloy-2 and Zircaloy-4; a microstructure adjacent to the outer circumferential surface of said fuel cladding tube, said microstructure containing precipitates; said precipitates having an average size below about 1100 angstroms and distributed substantially randomly throughout said microstructure; the outer circumferential surface of said fuel cladding tube characterized by excellent nodular corrosion resistance as evidenced by a uniform, continuous and adherent oxide film after five days exposure to a 454° C. 10.3 MPa steam test.
Claim 2
Dependent Claim 93 words
A final size Zircaloy alloy, nuclear fuel cladding tube comprising: said Zircaloy alloy selected from the group consisting of Zircaloy-2 and Zircaloy-4; a microstructure adjacent to the outer circumferential surface of said fuel cladding tube, said microstructure containing precipitates; said precipitates having an average size below about 1100 angstroms and distributed substantially randomly throughout said microstructure; the outer circumferential surface of said fuel cladding tube characterized by excellent nodular corrosion resistance as evidenced by a uniform, continuous and adherent oxide film after five days exposure to a 454° C. 10.3 MPa steam test.
Claim 3
Dependent Claim 24 words
The final size Zircaloy alloy, nuclear fuel cladding tube according to claim 1 wherein said precipitates have an average size below about 800 angstroms.
Claim 4
Dependent Claim 26 words
The final size Zircaloy alloy, nuclear fuel cladding tube according to claim 1 wherein said microstructure further containing a cold worked and stress relieved grain structure.
Claim 5
Dependent Claim 23 words
The final size Zircaloy alloy, nuclear fuel cladding tube according to claim 3 wherein said precipitates have an average size below 800 angstroms.
Claim 6
Dependent Claim 17 words
The final size Zircaloy alloy fuel cladding tube according to claim 1 further comprising anisotropic crystallographic texture.
Claim 7
Dependent Claim 23 words
The final size Zircaloy alloy, nuclear fuel cladding tube according to claim 5 wherein said precipitates have an average size below 800 angstroms.
Claim 8
Dependent Claim 22 words
The final size Zircaloy alloy, nuclear fuel cladding tube according to claim 1 wherein said microstructure containing a fully recrystallized grain structure.
Claim 9
Dependent Claim 23 words
The final size Zircaloy alloy, nuclear fuel cladding tube according to claim 7 wherein said precipitates have an average size below 800 angstroms.
Claim 10
Dependent Claim 74 words
A final size Zircaloy alloy, water reactor component comprising: said Zircaloy alloy selected from the group consisting of Zircaloy-2 and Zircaloy-4; a microstructure containing precipitates; said precipitates having an average size below about 1100 angstroms and distributed substantially randomly throughout said microstructure; said water reactor component characterized by excellent nodular corrosion rsistance as evidenced by a uniform, continuous and adherent oxide film after five days exposure to a 454° C. 10.3 MPa steam test.
Claim 11
Dependent Claim 74 words
A final size Zircaloy alloy, water reactor component comprising: said Zircaloy alloy selected from the group consisting of Zircaloy-2 and Zircaloy-4; a microstructure containing precipitates; said precipitates having an average size below about 1100 angstroms and distributed substantially randomly throughout said microstructure; said water reactor component characterized by excellent nodular corrosion rsistance as evidenced by a uniform, continuous and adherent oxide film after five days exposure to a 454° C. 10.3 MPa steam test.
Claim 12
Dependent Claim 23 words
The final size Zircaloy alloy water reactor component according to claim 9 wherein said precipitates have an average size below about 800 angstroms.
Claim 13
Dependent Claim 25 words
The final size Zircaloy alloy water reactor component according to claim 9 wherein said microstructure further containing a cold worked and stress relieved grain structure.
Claim 14
Dependent Claim 21 words
The final size Zircaloy water reactor component according to claim 11 wherein said precipitate have an average size below 800 angstroms.
Claim 15
Dependent Claim 17 words
The final size Zircaloy alloy water reactor component according to claim 9 further comprising anisotropic crystallographic texture.
Claim 16
Dependent Claim 21 words
The final size Zircaloy water reactor component according to claim 13 wherein said precipitates have an average size below 800 angstroms.
Claim 17
Dependent Claim 20 words
The final size Zircaloy water reactor component according to clain 9 wherein said microstructure containing a fully recrystallized grain structure.
Claim 18
Dependent Claim 20 words
The final size Zircaloy water reactor component according to clain 9 wherein said microstructure containing a fully recrystallized grain structure.
Claim 19
Dependent Claim 21 words
The final size Zircaloy water reactor component according to claim 15 wherein said precipitates have an average size below 800 angstroms.

References Cited (Backward Citations)

CA705863A Cited
GB923212A Cited
US3865635A Cited
US4360389A Cited
JPS57116739A Cited
JPS57210961A Cited
US4450016A Cited
JPS5822366A Cited
JPS5822365A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-01-04 1991-07-06 1992-01-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-01-04 1995-07-06 1996-01-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-01-04 1999-07-06 2000-01-05 $7700.00 Window Closed / Lapsed

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