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US4716144A Expired / Lapsed US ⏱️ 0.0 years remaining

Dye-barrier and subbing layer for dye-donor element used in thermal dye transfer

Assignee: Eastman Kodak Co
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Filing: 1986-11-25
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Granted: 1987-12-29
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Expires: 2006-11-25
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Abstract

Abstract A dye-donor element for thermal dye transfer comprising a support having on one side thereof a dye layer and on the opposite side thereof a slipping layer comprising a lubricating material, and wherein a hydrophilic dye-barrier layer is located between the dye layer and the support, and a subbing layer is located between the dye-barrier layer and the support. The dye-barrier layer prevents wrong-way transfer of dye into the support which provides improved dye transfer densities. The subbing layer improves adhesion between the dye-barrier layer and the support.

Inventors

  • 👤 Noel R. Vanier
  • 👤 Kin K. Lum
  • 👤 Wayne A. Bowman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 05:55
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/26; B41M5/40; B41M5/42; B41M5/44; B41M2205/00; B41M2205/30; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10S428/914; Y10S430/00; Y10S430/146; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31786; Y10T428/31797; Y10T428/31855; Y10T428/31935; Y10T428/31971

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 61 words
In a dye-donor element for thermal dye transfer comprising a support having on one side thereof a dye layer and on the opposite side thereof a slipping layer comprising a lubricating material, the improvement wherein a hydrophilic dye-barrier layer is located between said dye layer and said support, and a subbing layer is located between said dye-barrier layer and said support.
Claim 2
Dependent Claim 61 words
In a dye-donor element for thermal dye transfer comprising a support having on one side thereof a dye layer and on the opposite side thereof a slipping layer comprising a lubricating material, the improvement wherein a hydrophilic dye-barrier layer is located between said dye layer and said support, and a subbing layer is located between said dye-barrier layer and said support.
Claim 3
Dependent Claim 24 words
The element of claim 1 wherein said dye-barrier layer is present in an amount of from about 0.1 to about 1.6 g/m 2 .
Claim 4
Dependent Claim 62 words
The element of claim 1 wherein said hydrophilic polymer is gelatin, poly(acrylamide), poly(isopropylacrylamide), butyl methacrylate graft on gelatin, ethyl acrylate graft on gelatin, ethyl methacrylate graft on gelatin, cellulose monoacetate, methyl cellulose, poly(vinyl alcohol), poly(ethyleneimine), poly(acrylic acid), a mixture of poly(vinyl alcohol) and poly(vinyl acetate), a mixture of poly(vinyl alcohol) and poly(acrylic acid), or a mixture of cellulose monoacetate and poly(acrylic acid).
Claim 5
Dependent Claim 16 words
The element of claim 1 wherein said dye layer comprises a sublimable dye in a binder.
Claim 6
Dependent Claim 17 words
The element of claim 1 wherein said hydrophilic polymer is poly(acrylic acid), cellulose monoacetate or poly(vinyl alcohol).
Claim 7
Dependent Claim 28 words
The element of claim 1 wherein said subbing layer is poly(acrylonitrile-co-vinylidene chloride-co-acrylic acid), poly(butyl acrylate-co-2-aminoethyl methacrylate-co-2-hydroxyethyl methacrylate), a linear saturated polyester, or a chlorinated high density poly(ethylene-trichloroethylene) resin.
Claim 8
Dependent Claim 19 words
The element of claim 1 wherein said support comprises poly(ethylene terephthalate) and said subbing layer comprises poly(acrylonitrile-co-vinylidene chloride-co-acrylic acid).
Claim 9
Dependent Claim 19 words
The element of claim 7 wherein said dye layer comprises sequential repeating areas of cyan, magenta and yellow dye.
Claim 10
Dependent Claim 82 words
In a process of forming a dye transfer image comprising imagewise-heating a dye-donor element comprising a support having on one side thereof a dye layer and on the opposite side thereof a slipping layer comprising a lubricating material and transferring a dye image to a dye-receiving element to form said dye transfer image, the improvement wherein a hydrophilic dye-barrier layer is located between said dye layer and said support, and a subbing layer is located between said dye-barrier layer and said support.
Claim 11
Dependent Claim 82 words
In a process of forming a dye transfer image comprising imagewise-heating a dye-donor element comprising a support having on one side thereof a dye layer and on the opposite side thereof a slipping layer comprising a lubricating material and transferring a dye image to a dye-receiving element to form said dye transfer image, the improvement wherein a hydrophilic dye-barrier layer is located between said dye layer and said support, and a subbing layer is located between said dye-barrier layer and said support.
Claim 12
Dependent Claim 24 words
The process of claim 9 wherein said dye-barrier layer is present in an amount of from about 0.1 to about 1.6 g/m 2 .
Claim 13
Dependent Claim 17 words
The process of claim 9 wherein said hydrophilic polymer is poly(acrylic acid), cellulose monoacetate or poly(vinyl alcohol).
Claim 14
Dependent Claim 49 words
The process of claim 9 wherein said support is poly(ethylene terephthalate) which is coated with sequential repeating areas of cyan, magenta and yellow dye and said subbing layer comprises poly(acrylonitrile-co-vinylidene chloride-co-acrylic acid), and said process steps are sequentially performed for each color to obtain a three-color dye transfer image.
Claim 15
Dependent Claim 103 words
In a thermal dye transfer assemblage comprising: (a) a dye-donor element comprising a support having on one side thereof a dye layer and on the opposite side thereof a slipping layer comprising a lubricating material, and (b) a dye-receiving element comprising a support having thereon a dye image-receiving layer, said dye-receiving element being in a superposed relationship with said dye-donor element so that said dye layer is in contact with said dye image-receiving layer, the improvement wherein a hydrophilic dye-barrier layer is located between said dye layer and said support, and a subbing layer is located between said dye-barrier layer and said support.
Claim 16
Dependent Claim 103 words
In a thermal dye transfer assemblage comprising: (a) a dye-donor element comprising a support having on one side thereof a dye layer and on the opposite side thereof a slipping layer comprising a lubricating material, and (b) a dye-receiving element comprising a support having thereon a dye image-receiving layer, said dye-receiving element being in a superposed relationship with said dye-donor element so that said dye layer is in contact with said dye image-receiving layer, the improvement wherein a hydrophilic dye-barrier layer is located between said dye layer and said support, and a subbing layer is located between said dye-barrier layer and said support.
Claim 17
Dependent Claim 24 words
The assemblage of claim 13 wherein said dye-barrier layer is present in an amount of from about 0.1 to about 1.6 g/m 2 .
Claim 18
Dependent Claim 62 words
The assemblage of claim 13 wherein said hydrophilic polymer is methyl cellulose, gelatin, poly(acrylamide), poly(isopropylacrylamide), cellulose monoacetate, poly(vinyl alcohol), a mixture of poly(vinyl alcohol) and poly(vinyl acetate), poly(ethyleneimine), poly(acrylic acid), a mixture of poly(vinyl alcohol) and poly(acrylic acid), a mixture of cellulose monoacetate and poly(acrylic acid), butyl methacrylate graft on gelatin, ethyl acrylate graft on gelatin, or ethyl methacrylate graft on gelatin.
Claim 19
Dependent Claim 16 words
The assemblage of claim 13 wherein said dye layer comprises a sublimable dye in a binder.
Claim 20
Dependent Claim 17 words
The assemblage of claim 13 wherein said hydrophilic polymer is poly(acrylic acid), cellulose monoacetate or poly(vinyl alcohol).
Claim 21
Dependent Claim 29 words
The assemblage of claim 13 wherein said subbing layer is poly(acrylonitrile-co-vinylidene chloride-co-acrylic acid), poly(butyl acrylate-co-2-aminoethyl methacrylate-co-2-hydroxyethyl methacrylate), a linear saturated polyester, or a chlorinated high density poly(ethylene trichloroethylene) resin.
Claim 22
Dependent Claim 23 words
The assemblage of claim 13 wherein said support of the dye-donor element comprises poly(ethylene terephthalate) and said subbing layer comprises poly(acrylonitrile-co-vinylidene chloride-co-acrylic acid).
Claim 23
Dependent Claim 19 words
The assemblage of claim 19 wherein said dye layer comprises sequential repeating areas of cyan, magenta and yellow dye.

References Cited (Backward Citations)

US4253838A Cited
US4027345A Cited
US4021591A Cited
EP0109295A2 Cited
JPS6019138A Cited
EP0138483A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-12-28 1991-06-29 1991-12-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-12-28 1995-06-29 1995-12-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-12-28 1999-06-29 1999-12-29 $7700.00 Window Closed / Lapsed

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