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US4715958A Expired / Lapsed US ⏱️ 0.0 years remaining

Process and means for conducting the denitrification of water

Assignee: Linde GmbH
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Filing: 1985-10-21
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Granted: 1987-12-29
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Expires: 2005-10-21
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Abstract

Abstract In a denitrification process wherein denitrifying agents are supported on a carrier material, the invention comprises conducting denitrification in the presence of a carrier impregnated with an organic substance capable of serving as a reducing agent for the denitrifying agents. In another aspect the invention relates to a method of preparing such a carrier and to the carrier itself.

Inventors

  • 👤 Uwe Fuchs

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 07:27
CPC Classifications
C; C02; C02F; C02F3/00; C02F3/30; C02F3/302; C02F3/02; C02F3/10; C02F3/28; C02F3/2806; Y; Y02; Y02W; Y02W10/00; Y02W10/10

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 224 words
In a process for the biological denitrification of water which is at least substantially free of carbon, and wherein the water is denitrified in a reactor in the presence of a carrier material supporting denitrifying microorganisms thereon, the improvement comprising conducting denitrification in a reactor in the presence of a carrier material which is not a carbon source for denitrifying microorganisms carried thereon and which is impregnated with organic substances separate from the carrier material in a manner such that the organic substances do not effectively enter into solution with the water being treated, with no substantial increase in BOD 5 , said organic substances being biodegradable and at least partially insoluble in water and being employed as a carbon source by the denitrifying microorganisms, and the carrier material having been impregnated with said organic substances prior to being placed in the reactor for conducting the denitrification process whereby the requirement of providing a separate carbon source for the denitrifying microorganisms to effect denitrification is avoided, said carrier material being non-surface active and comprising at least one of sand, gravel, plastic filler bodies, porous mineral material, urea-formaldehyde resins, polyethylene, polypropylene, polyurethane, silicone polymers and natural sponges, and is in at least one of open-celled, foam and sintered lump form, and wherein influent water introduced into the reactor has a COD-content of about 1-200 mg/l.
Claim 2
Dependent Claim 224 words
In a process for the biological denitrification of water which is at least substantially free of carbon, and wherein the water is denitrified in a reactor in the presence of a carrier material supporting denitrifying microorganisms thereon, the improvement comprising conducting denitrification in a reactor in the presence of a carrier material which is not a carbon source for denitrifying microorganisms carried thereon and which is impregnated with organic substances separate from the carrier material in a manner such that the organic substances do not effectively enter into solution with the water being treated, with no substantial increase in BOD 5 , said organic substances being biodegradable and at least partially insoluble in water and being employed as a carbon source by the denitrifying microorganisms, and the carrier material having been impregnated with said organic substances prior to being placed in the reactor for conducting the denitrification process whereby the requirement of providing a separate carbon source for the denitrifying microorganisms to effect denitrification is avoided, said carrier material being non-surface active and comprising at least one of sand, gravel, plastic filler bodies, porous mineral material, urea-formaldehyde resins, polyethylene, polypropylene, polyurethane, silicone polymers and natural sponges, and is in at least one of open-celled, foam and sintered lump form, and wherein influent water introduced into the reactor has a COD-content of about 1-200 mg/l.
Claim 3
Dependent Claim 29 words
A process according to claim 1 further comprising passing the water, after denitrification, through a biological filter to remove any biomass or non-oxidized reducing substance that may be present.
Claim 4
Dependent Claim 43 words
A process according to claim 1 further comprising removing the carrier material from the reactor after depletion of the organic substances thereon, reimpregnating the carrier materials with said organic substances, and reintroducing the carrier material into the reactor to continue conducting of denitrification.
Claim 5
Dependent Claim 18 words
A process according to claim 3, wherein said removal, reimpregnation and reintroduction of carrier material is conducted continuously.
Claim 6
Dependent Claim 21 words
A process according to claim 3, wherein said removal reimpregnation and reintroduction of carrier material is conducted on a batch basis.
Claim 7
Dependent Claim 17 words
A process according to claim 1 wherein the COD of the influent wastewater is about 1-50 mg/l.
Claim 8
Dependent Claim 23 words
A process according to claim 1 wherein said organic substances are applied in a thin layer of 0.1-10 mm on said carrier material.
Claim 9
Dependent Claim 43 words
A process according to claim 1 conducted with the carrier material of polyurethane foam particles of a size of about 5-20 mm having pores of about 0.5-3 mm which are impregnated with a thin layer of about 0.1-10 mm of carbohydrates or cellulose.
Claim 10
Dependent Claim 13 words
A process according to claim 1, wherein said carrier material comprises polyurethane foam.
Claim 11
Dependent Claim 112 words
A carrier for use in an attached growth biological denitrification process wherein said carrier is adapted for supporting denitrifying microorganisms thereon, and is not a carbon source for the denitrifying microorganisms and is impregnated with a separate organic substance to serve as a carbons source for said denitrifying microorganisms in a manner such that the organic substance will not dissolve into water when the carrier is immersed in water, said carrier being non-surface active and comprising one of sand, gravel, plastic filler bodies, particles of polyurethane foam, porous mineral materials, silicone polymers, natural sponges, ureaformaldehyde resins, polyethylene and polypropylene, and is in at least one of open-celled, foam and sintered lump form.
Claim 12
Dependent Claim 112 words
A carrier for use in an attached growth biological denitrification process wherein said carrier is adapted for supporting denitrifying microorganisms thereon, and is not a carbon source for the denitrifying microorganisms and is impregnated with a separate organic substance to serve as a carbons source for said denitrifying microorganisms in a manner such that the organic substance will not dissolve into water when the carrier is immersed in water, said carrier being non-surface active and comprising one of sand, gravel, plastic filler bodies, particles of polyurethane foam, porous mineral materials, silicone polymers, natural sponges, ureaformaldehyde resins, polyethylene and polypropylene, and is in at least one of open-celled, foam and sintered lump form.
Claim 13
Dependent Claim 24 words
A carrier according to claim 10 comprising a nonsurface active material impregnated with a thin layer of at least one of carbohydrates and cellulose.
Claim 14
Dependent Claim 41 words
A carrier according to claim 11 wherein the carrier comprises polyurethane foam particles of a size of about 5-20 mm having pores of about 0.5-3 mm which are impregnated with a thin layer of about 0.1-10 mm of carbohydrates or cellulose.
Claim 15
Dependent Claim 12 words
A carrier according to claim 10, wherein said carrier comprises polyurethane foam.
Claim 16
Dependent Claim 10 words
A carrier according to claim 13, further comprising denitrifying microorganisms.
Claim 17
Dependent Claim 10 words
A carrier according to claim 10, further comprising denitrifying microorganisms.

References Cited (Backward Citations)

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FR2476629A2 Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-12-28 1991-06-29 1991-12-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-12-28 1995-06-29 1995-12-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-12-28 1999-06-29 1999-12-29 $7700.00 Window Closed / Lapsed

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