US4704453A
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Preparation of alkylglucosides
Assignee: BASF SE
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Filing: 1983-09-02
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Granted: 1987-11-03
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Expires: 2003-09-02
Abstract
Abstract Alkylglucosides are prepared by acetalization of glucose with an equivalent amount or an excess of a C 3 -C 5 -alkanol in the presence of an acidic catalyst by a method wherein the acetalization is carried out in the presence of an alkali metal salt of a boric acid used in an amount which is equivalent to or in excess of the amount of the catalyst. The alkylglucosides obtained can be used directly, for example as solubilizers, in particular in the cosmetic sector, or can be reacted further to give higher alkylglucosides.
Inventors
- 👤 Klaus Lorenz
- 👤 Wolf-Dieter Balzer
- 👤 Helmut Wolf
- 👤 Wolfgang Trieselt
- 👤 Gerd Busse
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 11:46
CPC Classifications
C; C07; C07H; C07H15/00; C07H15/02; C07H15/04
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
119 words
A process for the preparation of an alkylglucoside by acetalization of glucose in the anhydrous form with a C 3 -C 5 -alkanol in the presence of an acidic catalyst, wherein the acetalization is carried out with 1.5 to 5 parts of alcohol per part of anhydrous glucose and with an acidic catalyst selected from the group consisting of sulfuric acid, phosphoric acid, hydrochloric acid and p-toluenesulfonic acid, used in an amount of about 0.2-5% by weight, based on glucose, and in the presence of an alkali metal salt selected from the group consisting of sodium metalborate, borax and sodium perborate, used in an amount which is equivalent to or in excess of the amount of the acidic catalyst.
Claim 2
Dependent Claim
119 words
A process for the preparation of an alkylglucoside by acetalization of glucose in the anhydrous form with a C 3 -C 5 -alkanol in the presence of an acidic catalyst, wherein the acetalization is carried out with 1.5 to 5 parts of alcohol per part of anhydrous glucose and with an acidic catalyst selected from the group consisting of sulfuric acid, phosphoric acid, hydrochloric acid and p-toluenesulfonic acid, used in an amount of about 0.2-5% by weight, based on glucose, and in the presence of an alkali metal salt selected from the group consisting of sodium metalborate, borax and sodium perborate, used in an amount which is equivalent to or in excess of the amount of the acidic catalyst.
Claim 3
Dependent Claim
56 words
A process as claimed in claim 1, wherein the alkali metal salt selected from the group consisting of sodium metaborate, borax and sodium perborate is added to the solution obtained after the alkanol, glucose and acidic catalyst have been heated, and the reaction is then completed, the water of reaction formed being separated off by distillation.
Claim 4
Dependent Claim
17 words
A process is claimed in claim 1, wherein glucose in the anhydrous form is reacted with n-butanol.
References Cited (Backward Citations)
US3547828A
Cited
US4298728A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-11-02 | 1991-05-04 | 1991-11-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-11-02 | 1995-05-04 | 1995-11-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-11-02 | 1999-05-04 | 1999-11-03 | $7700.00 | Window Closed / Lapsed |