Process for the production of polyisocyanates containing urea and/or biuret groups, preparations obtainable thereby and their use

Claim 2

A urea- and/or biuret-modified polyisocyanate having an NCO-content of about 0.7 to 45% by weight which is prepared by reacting (A) at least one organic polyisocyanate having an NCO content of about 10 to 50% by weight with (B) organic compounds containing isocyanate-reactive groups comprising (a) a polyether or polyester having a molecular weight of 500 to about 20,000 and containing at least two isocyanate-reactive groups comprising a member selected from the group consisting of alcoholic hydroxyl groups attached to primary carbon atoms, alcoholic hydroxyl groups attached to secondary carbon atoms, aromatically bound primary amino groups, aromatically bound secondary amino groups, cycloaliphatically bound primary amino groups, cycloaliphatically bound secondary amino groups, aliphatically bound primary amino groups, aliphatically bound secondary amino groups and mixtures thereof, and (b) a low molecular weight organic compound comprising (1) an aromatic diamine or triamine having a molecular weight of 108 to 499 and containing primary and/or secondary amino groups, (3) an aliphatic or cycloaliphatic diamine or triamine having a molecular weight of 60 to 499 and containing primary and/or secondary amino groups, (3) an organic compound having a molecular weight of 61 to 499 and containing at least one alcoholic hydroxyl group attached to a primary or secondary carbon atom and at least one aliphatically-, cycloaliphatically- or aromatically-bound primary or secondary amino group, (4) a compound containing at least two alcoholic hydroxyl groups and optionally at least one ether or ester group and (5) mixtures of (1) to (4), wherein the equivalent ratio of isocyanate groups in component (A) to isocyanate-reactive groups in component (B) is about 2:1 to 100:1, the equivalent ratio of isocyanate-reactive groups in component (a) to component (b) is about 100:1 to 0.1:1 and at least 25% of the isocyanate-reactive groups in components (a) and (b) are primary or secondary amino groups.

Claim 3

The polyisocyanate of claim 1 wherein component (A) comprises a modified polyisocyanate of the diphenylmethane series which is liquid at room temperature and has an NCO content of about 20 to 32% and comprises a member selected from the group consisting of urethane groups, carbodiimide groups, uretone imine groups and mixtures thereof.

Claim 4

The polyisocyanate of claim 1 wherein , component (a) comprises a polyether having a molecular weight of about 1000 to 7000 and wherein at least 50% of the isocyanate-reactive groups of said polyether are selected from the group consisting of aromatically-bound primary amino groups, aliphatically-bound primary amino groups and cycloaliphatically-bound primary amino groups.

Claim 5

The polyisocyanate of claim 2 wherein component (a) comprises a polyether having a molecular weight of about 1000 to 7000 and wherein at least about 50% of the isocyanate-reactive groups of said polyether are selected from the group consisting of aromatically-bound primary amino groups, aliphatically-bound primary amino groups and cycloaliphatically-bound primary amino groups.

Claim 6

The polyisocyanate of claim 1 wherein component (b) consists of an aromatic diamine containing a C 1 -C 4 alkyl substituent in at least one ortho position to each amino group.

Claim 7

The polyisocyanate of claim 2 wherein component (b) consists of an aromatic diamine containing a C 1 -C 4 alkyl substituent in at least one ortho position to each amino group.

Claim 8

The polyisocyanate of claim 3 wherein component (b) consists of an aromatic diamine containing a C 1 -C 4 alkyl substituent in at least one ortho position to each amino group.

Claim 9

The polyisocyanate of claim 4 wherein component (b) consists of an aromatic diamine containing a C 1 -C 4 alkyl substituent in at least one ortho position to each amino group.

Claim 10

The polyisocyanate of claim 1 wherein at least 75% of the isocyanate-reactive groups in components (a) and (b) are primary amino groups.

Claim 11

The polyisocyanate of claim 1 wherein the equivalent ratio of isocyanate groups in component (A) to isocyanate-reactive groups in component (B) is about 4:1 to 50:1.

Claim 12

The polyisocyanate of claim 1 which comprises reacting components (A) and (B) at a temperature of about 20° to 140° C.

Claim 13

A process for the production of an ureaand/or biuret-modified polyisocyanate having an NCO-content of about 0.7 to 45% by weight which comprises reacting (A) at least one organic polyisocyanate having an NCO content of about 10 to 50% by weight with (B) organic compounds containing isocyanate-reactive groups comprising (a) a polyether or polyester having a molecular weight of 500 to about 20,000 and containing at least two isocyanate-reactive groups comprising a member selected from the group consisting of alcoholic hydroxyl groups attached to primary carbon atoms, alcoholic hydroxyl groups attached to secondary carbon atoms, aromatically bound primary amino groups, aromatically bound secondary amino groups, cycloaliphatically bound primary amino groups, cycloaliphatically bound secondary amino groups, aliphatically bound primary amino groups, aliphatically bound secondary amino groups and mixtures thereof, and (b) a low molecular weight organic compound comprising (1) an aromatic diamine or triamine having a molecular weight of 108 to 499 and containing primary and/or secondary amino groups, (2) an aliphatic or cycloaliphatic diamine or triamine having a molecular weight of 60 to 499 and containing primary and/or secondary amino groups, (3) an organic compound having a molecular weight of 61 to 499 and containing at least one alcoholic hydroxyl group attached to a primary or secondary carbon atom and at least one aliphatically-, cycloaliphatically- or aromatically-bound primary or secondary amino group, (4) a compound containing at least two alcoholic hydroxyl groups and optionally at least one ether or ester group and (5) mixtures of (1) to (4), wherein the equivalent ratio of isocyanate groups in component (A) to isocyanate-reactive groups in component (B) is about 2:1 to 100:1, the equivalent ratio of isocyanate-reactive groups in component (a) to component (b) is about 100:1 to 0.1:1 and at least 25% of the isocyanate-reactive groups in components (a) and (b) are primary or secondary amino groups.

Claim 14

A process for the production of an ureaand/or biuret-modified polyisocyanate having an NCO-content of about 0.7 to 45% by weight which comprises reacting (A) at least one organic polyisocyanate having an NCO content of about 10 to 50% by weight with (B) organic compounds containing isocyanate-reactive groups comprising (a) a polyether or polyester having a molecular weight of 500 to about 20,000 and containing at least two isocyanate-reactive groups comprising a member selected from the group consisting of alcoholic hydroxyl groups attached to primary carbon atoms, alcoholic hydroxyl groups attached to secondary carbon atoms, aromatically bound primary amino groups, aromatically bound secondary amino groups, cycloaliphatically bound primary amino groups, cycloaliphatically bound secondary amino groups, aliphatically bound primary amino groups, aliphatically bound secondary amino groups and mixtures thereof, and (b) a low molecular weight organic compound comprising (1) an aromatic diamine or triamine having a molecular weight of 108 to 499 and containing primary and/or secondary amino groups, (2) an aliphatic or cycloaliphatic diamine or triamine having a molecular weight of 60 to 499 and containing primary and/or secondary amino groups, (3) an organic compound having a molecular weight of 61 to 499 and containing at least one alcoholic hydroxyl group attached to a primary or secondary carbon atom and at least one aliphatically-, cycloaliphatically- or aromatically-bound primary or secondary amino group, (4) a compound containing at least two alcoholic hydroxyl groups and optionally at least one ether or ester group and (5) mixtures of (1) to (4), wherein the equivalent ratio of isocyanate groups in component (A) to isocyanate-reactive groups in component (B) is about 2:1 to 100:1, the equivalent ratio of isocyanate-reactive groups in component (a) to component (b) is about 100:1 to 0.1:1 and at least 25% of the isocyanate-reactive groups in components (a) and (b) are primary or secondary amino groups.

Claim 15

A process for the production of a polyisocyanate polyaddition product which comprises reacting the urea- and/or biuret-modified polyisocyanate of claim 1 with at least one compound containing isocyanate-reactive hydrogens.

Claim 16

The process of claim 13 wherein said polyisocyanate polyaddition product is a molded plastic having a density of about 0.8 to 1.4 g/cm 3 and said process is a reaction injection molding process.