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US4703022A Expired / Lapsed US ⏱️ 0.0 years remaining

Alumina and MgO preheatable insulating refractory liners and methods of use thereof

Assignee: Consolidated Ceramic Products Inc
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Filing: 1984-10-30
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Granted: 1987-10-27
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Expires: 2004-10-30
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Abstract

Abstract Novel preheatable molded refractory insulating liners and methods of use thereof for lining metallurgical vessels, such as hot tops, ladels, tundishes, troughs and pipes, etc., which serve to transfer molten metals, such as ferrous alloys, are disclosed. The new and vastly improved preheatable liners are suitable for developing effectively the required hot strength needed for casting molten metals at vessel preheat temperatures and casting temperatures. The unique preheatable liners additionally possess the needed hot strength during the range of casting temperatures as are experienced in the metal making industry. The preheatable molded refractory insulating liners comprise a liner structure of predetermined shape, the liner structure comprising a molded uniform mixture containing a particulate refractory component comprised of alumina and MgO refractory grain and a binder therefore wherein the alumina and MgO refractory grain are in amounts proportioned such that the hot strength is developed at vessel preheat and metal casting temperatures which are in the range of about 1900° F. to about 3000° C. when such liners are heated for sufficient periods of time.

Inventors

  • 👤 Howard B. Johnson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 09:39
CPC Classifications
B; B22; B22D; B22D41/00; B22D41/02; C; C04; C04B; C04B14/00; C04B14/02; C04B14/30; C04B30/00; C04B30/02; C04B38/00; C04B2111/00; C04B2111/00034; C04B2111/0012; C04B2111/00474; C04B2111/0087; Y; Y02; Y02W; Y02W30/00; Y02W30/50; Y02W30/91

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 228 words
A preheatable molded refractory insulating liner structure prior to preheating of predetermined shape having insulating porosity for a metal casting vessel suitable for developing sufficient hot strength to maintain the integrity of the structure at vessel preheat and molten metal casting temperatures which are in the range of about 1900° F. to about 3000° F. comprising a molded uniform mixture having a substantial insulating porosity on the order of about 50% prior to preheating containing a particulate refractory component in an amount of about 75% to about 98.5% by weight of said preheatable liner structure of a mixture of alumina and MgO refractory grain wherein said alumina and MgO refractory grain are in a ratio of about 1:1 to about 1:94, respectively, and a binder for said component and inorganic fibrous material in sufficient amounts to maintain the predetermined shape of insulating porosity at least prior to the preheat temperatures wherein said alumina and MgO refractory grain are of a particle size in said preheatable liner structure to facilitate the formation of spinel bonding which results in increased hot strength with substantial maintenance of insulating porosity and shape without substantial shrinkage at both the vessel preheat temperatures of about 1900° F. to about 2400° F. and higher metal casting temperatures when said preheatable liner structure is used in a casting vessel heated for a sufficient period of time.
Claim 2
Dependent Claim 228 words
A preheatable molded refractory insulating liner structure prior to preheating of predetermined shape having insulating porosity for a metal casting vessel suitable for developing sufficient hot strength to maintain the integrity of the structure at vessel preheat and molten metal casting temperatures which are in the range of about 1900° F. to about 3000° F. comprising a molded uniform mixture having a substantial insulating porosity on the order of about 50% prior to preheating containing a particulate refractory component in an amount of about 75% to about 98.5% by weight of said preheatable liner structure of a mixture of alumina and MgO refractory grain wherein said alumina and MgO refractory grain are in a ratio of about 1:1 to about 1:94, respectively, and a binder for said component and inorganic fibrous material in sufficient amounts to maintain the predetermined shape of insulating porosity at least prior to the preheat temperatures wherein said alumina and MgO refractory grain are of a particle size in said preheatable liner structure to facilitate the formation of spinel bonding which results in increased hot strength with substantial maintenance of insulating porosity and shape without substantial shrinkage at both the vessel preheat temperatures of about 1900° F. to about 2400° F. and higher metal casting temperatures when said preheatable liner structure is used in a casting vessel heated for a sufficient period of time.
Claim 3
Dependent Claim 26 words
A preheatable insulating liner structure of claim 1 wherein said vessel is selected from the class consisting of a hot top, ladle, tundish, pipe or trough.
Claim 4
Dependent Claim 22 words
A preheatable insulating liner structure of claim 1 wherein said liner structure is in the form of a plurality of shaped inserts.
Claim 5
Dependent Claim 16 words
A preheatable insulating liner structure of claim 1 wherein said liner structure is a tundish board.
Claim 6
Dependent Claim 16 words
A preheatable insulating liner structure of claim 1 wherein said molten metal is a ferrous alloy.
Claim 7
Dependent Claim 19 words
A preheatable insulating liner structure of claim 5 wherein said ferrous alloy is a low hydrogen grade of steel.
Claim 8
Dependent Claim 25 words
A preheatable insulating liner structure of claim 1 wherein said MgO refractory grain is derived from the class consisting of magnesite, periclase or mixtures thereof.
Claim 9
Dependent Claim 27 words
A preheatable insulating liner structure of claim 1 wherein said binder component is selected from the class consisting of an inorganic or organic binder or mixtures thereof.
Claim 10
Dependent Claim 29 words
A preheatable insulating liner structure of claim 8 wherein said organic binder is selected from the class consisting of urea-formaldehyde resin or phenolformaldehyde resin or starch or mixtures thereof.
Claim 11
Dependent Claim 15 words
A preheatable insulating liner structure of claim 8 wherein said inorganic binder is boric acid.
Claim 12
Dependent Claim 14 words
A preheatable insulating liner structure of claim 1 further comprising an organic fibrous material.
Claim 13
Dependent Claim 19 words
A preheatable insulating liner structure of claim 1 wherein said inorganic fibrous material is slag wool or alumina silicate.
Claim 14
Dependent Claim 17 words
A preheatable insulating liner structure of claim 11 wherein said organic fibrous material is a cellulose fiber.
Claim 15
Dependent Claim 23 words
A preheatable insulating liner structure of claim 1 wherein said alumina is about 5% to about 15% by weight of said liner structure.
Claim 16
Dependent Claim 42 words
A preheatable insulating liner structure of claim 1 wherein said alumina is about 10% by weight and said MgO refractory grain is about 80% by weight of said liner structure wherein said MgO refractory grain is derived from about 95% MgO magnesite.
Claim 17
Dependent Claim 45 words
A preheatable insulating liner structure of claim 1 wherein said liner structure comprises about 75% to about 98.5% weight said particulate refractory component, 1% to about 10% fibrous material, about 1.5% to about 15% said binder component and 0% to about 5% a thixotropic substance.
Claim 18
Dependent Claim 52 words
A preheatable insulating liner structure of claim 1 comprising by weight: ______________________________________ (a) phenol-formaldehyde resin: about 2.3% hexamethylenetetraamine about 0.2% slag wool: about 3.3% paper: about 1.4% bentonite: about 1.6% magnesite - about 95% MgO: about 81.2% alumina: about 10%; and (b) boric acid: about 2.5% of dry weight of (a). ______________________________________
Claim 19
Dependent Claim 23 words
A preheatable insulating liner structure of claim 1 wherein said particulate refractory component further contains a suitable refractory filler in an acceptable amount.
Claim 20
Dependent Claim 56 words
A preheatable insulating liner structure of claim 18 wherein said refractory filldr is selected from the class consisting of spinel, zirconia or alumina wherein said fillers are in an amount by weight of said liner structure as follows: ______________________________________ spinel 0% to about 70%; zirconia 0% to about 80%; or alumina 0% to about 80%. ______________________________________
Claim 21
Dependent Claim 51 words
A preheatable insulating liner structure of claim 19 comprising by weight: ______________________________________ (a) phenol-formaldehyde resin: about 2.3% hexamethylenetetraamine about 0.2% slag wool: about 3.3% paper: about 1.4% bentonite: about 1.6% magnesite: about 23.3% alumina: about 4.1% Zirconia: about 63.8%; and (b) boric acid: about 2.5% of dry weight of (a). ______________________________________
Claim 22
Dependent Claim 59 words
A preheatable insulating liner structure of claim 1 wherein said alumina comprises particles wherein about 95% of the alumina particles pass through a 325 mesh screen and said MgO refractory grain comprises particles wherein no more than about 40% of the MgO refractory grain particles are retained on a 50 mesh screen or pass through a 325 mesh screen.

References Cited (Backward Citations)

US3514302A Cited
US3578473A Cited
NL7005048A Cited
US3993620A Cited
US3917110A Cited
US4387173A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-10-26 1991-04-27 1991-10-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-10-26 1995-04-27 1995-10-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-10-26 1999-04-27 1999-10-27 $7700.00 Window Closed / Lapsed

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