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US4701273A Expired / Lapsed US ⏱️ 0.0 years remaining

Lubricant compositions containing antioxidants, amine phosphates and 4- (5-) methyl-1-[di-(2-ethylhexyl) aminomethyl]-benzotriazole

Assignee: BASF Corp
•
Filing: 1986-09-10
•
Granted: 1987-10-20
•
Expires: 2006-09-10
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Abstract

Abstract Lubricant formulations containing a combination, which has a synergistic action in respect of metal deactivation, composed of 1-[di-(2-ethylhexyl)-aminomethyl]-benztriazole which is methylated in the benzene ring in the 4-position and/or 5-position, and an antioxidant selected from a small group of antioxidants. Further additives can be added to these lubricant formulations. The compositions mentioned above reduce the abrasion phenomena in the components to be lubricated if they are added to mineral and synthetic lubricating oils, hydraulic fluids and lubricating greases.

Inventors

  • 👤 Arthur Brady
  • 👤 Ulrich Kristen
  • 👤 Hermann F. Angerer
  • 👤 Franz Regenass

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 02:34
CPC Classifications
C; C10; C10M; C10M141/00; C10M129/00; C10M129/02; C10M129/04; C10M129/10; C10M129/14; C10M129/68; C10M129/76; C10M133/00; C10M133/02; C10M133/04; C10M133/12; C10M133/38; C10M133/44; C10M135/00; C10M135/20; C10M135/22; C10M135/26; C10M137/00; C10M137/02; C10M137/04; C10M137/08; C10M2207/00; C10M2207/02; C10M2207/023; C10M2207/024; C10M2207/026; C10M2207/027; C10M2207/28; C10M2207/287; C10M2207/288; C10M2207/289; C10M2215/00; C10M2215/02; C10M2215/06; C10M2215/064; C10M2215/065; C10M2215/066; C10M2215/067; C10M2215/068; C10M2215/22; C10M2215/221; C10M2215/223; C10M2215/225; C10M2215/226; C10M2215/24; C10M2215/30; C10M2219/00; C10M2219/08; C10M2219/082; C10M2219/085; C10M2223/00; C10M2223/02; C10M2223/04; C10M2223/043

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 64 words
A stabilizer system which contains (a) 1-[di-(2-ethylhexyl)-aminomethyl[-benztriazole which is substituted by methyl in the 4-position and/or 5-position in the benzene ring, and (b) at least one antioxidant selected from the group consisting of pentaerythrityl tetrakis-[3-(3,5-di-tert.-butyl-4-hydroxyphenyl)-propionate], isooctyl 3,5-di-tert.-butyl-4-hydroxybenzylmercaptoacetate, o-tert.-butylphenol, 2,6-di-tert.-butyl-4-methylphenol, 4,4'-methylenebis-(2,6-di-tert.-butylphenol), tert.-octylated N-phenyl-1-naphthylamine, and a mixture of monoalkylated and dialkylated tert.-butyldiphenyl-amines/tert.-octyldiphenylamines, where the weight ratio between component (a) and component (b) is 1:2 to 1:10.
Claim 2
Dependent Claim 64 words
A stabilizer system which contains (a) 1-[di-(2-ethylhexyl)-aminomethyl[-benztriazole which is substituted by methyl in the 4-position and/or 5-position in the benzene ring, and (b) at least one antioxidant selected from the group consisting of pentaerythrityl tetrakis-[3-(3,5-di-tert.-butyl-4-hydroxyphenyl)-propionate], isooctyl 3,5-di-tert.-butyl-4-hydroxybenzylmercaptoacetate, o-tert.-butylphenol, 2,6-di-tert.-butyl-4-methylphenol, 4,4'-methylenebis-(2,6-di-tert.-butylphenol), tert.-octylated N-phenyl-1-naphthylamine, and a mixture of monoalkylated and dialkylated tert.-butyldiphenyl-amines/tert.-octyldiphenylamines, where the weight ratio between component (a) and component (b) is 1:2 to 1:10.
Claim 3
Dependent Claim 87 words
A stabilizer system according to claim 1 which additionally contains (c) a compound of formula I ##STR2## in which R 1 , R 2 and R 3 are identical or different and R 1 , R 2 and R 3 are each hydrogen or C 1 -C 18 -alkyl, C 16 -C 18 -alkenyl methyl, phenyl, naphthyl or C 5 -C 6 -cycloalkyl and R is C 4 -C 12 -alkyl, where the weight ratio between component (c) and components (a) plus (b) is 1:0.5 to 1:4.
Claim 4
Dependent Claim 59 words
A lubricant composition which comprises (a) a mineral or snythetic lubricating oil, fluid or grease, (b) 0.01 to 5% by weight, based on the total weight of the composition, of an antioxidant according to claim 1 , and (c) 0.001 to 5% by weight, based on the total weight of the composition, of the 4-(5-)-methyl-1-[di-(2-ethylhexyl)aminomethyl]-benzotriazole according to claim 1.
Claim 5
Dependent Claim 29 words
A composition according to claim 3 wherein, based on the total composition, 0.1 to 2% by weight of antioxidant; and 0.01 to 1% by weight of 4-(5-)-methyl-1-[di-((2-ethylhexyl)aminomethyl]-benzotriazole are present.
Claim 6
Dependent Claim 82 words
A lubricant composition according to claim 3 which additionally contains (d) 0.01 to 2% by weight, based on the total composition, of a compound of formula I ##STR3## in which R 1 , R 2 and R 3 are identical or different and R 1 , R 2 and R 3 are each hydrogen or C 1 -C 18 -alkyl, C 16 -C 18 -alkenyl methyl, phenyl, naphthyl or C 5 -C 6 -cycloalkyl and R is C 4 -C 12 -alkyl.
Claim 7
Dependent Claim 20 words
A method of stabilising lubricants by adding to them an effective amount of the stabiliser system according to claim 1.
Claim 8
Dependent Claim 20 words
A method of stabilising lubricants by adding to them an effective amount of the stabiliser system according to claim 2.

References Cited (Backward Citations)

US3914179A Cited
US3697427A Cited
US3931022A Cited
US4101431A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-10-19 1991-04-20 1991-10-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-10-19 1995-04-20 1995-10-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-10-19 1999-04-20 1999-10-20 $7700.00 Window Closed / Lapsed

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