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US4700208A Expired / Lapsed US ⏱️ 0.0 years remaining

Dye-barrier/subbing layer for dye-donor element used in thermal dye transfer

Assignee: Eastman Kodak Co
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Filing: 1986-11-25
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Granted: 1987-10-13
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Expires: 2006-11-25
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Abstract

Abstract A dye-donor element for thermal dye transfer comprises a support, a hydrophilic dye-barrier/subbing layer comprising poly(butyl acrylate-co-2-aminoethyl methacrylate-co-2-hydroxyethyl methacrylate), poly(N-isopropylacrylamide-co-2-aminoethyl)-methacrylate-co-(2-hydroxyethyl methacrylate), poly[(2-chloroethyl)acrylamide-co-ethacrylic acid],or gelatin nitrate and a dye layer. The dye-barrier/subbing layer provides improved dye transfer densities.

Inventors

  • 👤 Noel R. Vanier
  • 👤 Kin K. Lum
  • 👤 Wayne A. Bowman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 07:01
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/26; B41M5/40; B41M5/42; B41M5/44; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10S428/914; Y10T; Y10T428/00; Y10T428/27; Y10T428/273; Y10T428/31504; Y10T428/31725; Y10T428/31768; Y10T428/31786; Y10T428/31797; Y10T428/31855; Y10T428/31935

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 47 words
In a dye-donor element for thermal dye transfer comprising a support having thereon a dye layer, the improvement wherein a hydrophilic dye-barrier/subbing layer is located between said dye layer and said support, said dye-barrier/subbing layer comprising poly(butyl acrylate-co-2-aminoethyl methacrylate-co-2-hydroxyethyl methacrylate), poly(N-isopropylacrylamide-co-2-aminoethyl)methacrylate-co-(2-hydroxyethyl methacrylate), poly[(2-chloroethyl)acrylamide-co-methacrylic acid], or gelatin nitrate.
Claim 2
Dependent Claim 47 words
In a dye-donor element for thermal dye transfer comprising a support having thereon a dye layer, the improvement wherein a hydrophilic dye-barrier/subbing layer is located between said dye layer and said support, said dye-barrier/subbing layer comprising poly(butyl acrylate-co-2-aminoethyl methacrylate-co-2-hydroxyethyl methacrylate), poly(N-isopropylacrylamide-co-2-aminoethyl)methacrylate-co-(2-hydroxyethyl methacrylate), poly[(2-chloroethyl)acrylamide-co-methacrylic acid], or gelatin nitrate.
Claim 3
Dependent Claim 22 words
The element of claim 1 wherein said dye-barrier/subbing layer is present in an amount of up to about 1.8 g/m 2 .
Claim 4
Dependent Claim 12 words
The element of claim 1 wherein said dye-barrier/subbing layer is gelatin nitrate.
Claim 5
Dependent Claim 16 words
The element of claim 1 wherein said dye layer comprises a sublimable dye in a binder.
Claim 6
Dependent Claim 29 words
The element of claim 1 wherein the side of the support opposite the side having thereon said dye layer is coated with a slipping layer comprising a lubricating material.
Claim 7
Dependent Claim 11 words
The element of claim 1 wherein said support comprises poly(ethylene terephthalate).
Claim 8
Dependent Claim 19 words
The element of claim 6 wherein said dye layer comprises sequential repeating areas of cyan, magenta and yellow dye.
Claim 9
Dependent Claim 68 words
In a process of forming a dye transfer image comprising imagewise-heating a dye-donor element comprising a support having thereon a dye layer and transferring a dye image to a dye-receiving element to form said dye transfer image, the improvement wherein a hydrophilic dye-barrier/subbing layer is located between said dye layer and said support, said dye-barrier/subbing layer comprising poly(butyl acrylate-co-2-aminoethyl methacrylate-co-2-hydroxyethyl methacrylate), poly(N-isopropylacrylamide-co-2-aminoethyl)-methacrylate-co-(2-hydroxyethyl methacrylate), poly[(2-chloroethyl)acrylamide-co-methacrylic acid], or gelatin nitrate.
Claim 10
Dependent Claim 68 words
In a process of forming a dye transfer image comprising imagewise-heating a dye-donor element comprising a support having thereon a dye layer and transferring a dye image to a dye-receiving element to form said dye transfer image, the improvement wherein a hydrophilic dye-barrier/subbing layer is located between said dye layer and said support, said dye-barrier/subbing layer comprising poly(butyl acrylate-co-2-aminoethyl methacrylate-co-2-hydroxyethyl methacrylate), poly(N-isopropylacrylamide-co-2-aminoethyl)-methacrylate-co-(2-hydroxyethyl methacrylate), poly[(2-chloroethyl)acrylamide-co-methacrylic acid], or gelatin nitrate.
Claim 11
Dependent Claim 22 words
The process of claim 8 wherein said dye-barrier/subbing layer is present in an amount of up to about 1.8 g/m 2 .
Claim 12
Dependent Claim 41 words
The process of claim 8 wherein said support is poly(ethylene terephthalate) which is coated with sequential repeating areas of cyan, magenta and yellow dye, and said process steps are sequentially performed for each color to obtain a three-color dye transfer image.
Claim 13
Dependent Claim 89 words
In a thermal dye transfer assmeblage comprising: (a) a dye-donor element comprising a support having thereon a dye layer, and (b) a dye-receiving element comprising a support having thereon a dye image-receiving layer, said dye-receiving element being in a superposed relationship with said dye-donor element so that said dye layer is in contact with said dye image-receiving layer, the improvement wherein a hydrophilic dye-barrier/subbing layer is located between said dye layer and said support, said dye-barrier/subbing layer comprising poly(butyl acrylate-co-2-aminoethyl metacrylate-co-2-hydroxyethyl methacrylate), poly(N-isopropylacrylamide-co-2-aminoethyl)metacrylate-co-(2-hydroxyethyl methacrylate), poly[(2-chloroethyl)acrylamide-co-methacrylic acid], or gelatin nitrate.
Claim 14
Dependent Claim 89 words
In a thermal dye transfer assmeblage comprising: (a) a dye-donor element comprising a support having thereon a dye layer, and (b) a dye-receiving element comprising a support having thereon a dye image-receiving layer, said dye-receiving element being in a superposed relationship with said dye-donor element so that said dye layer is in contact with said dye image-receiving layer, the improvement wherein a hydrophilic dye-barrier/subbing layer is located between said dye layer and said support, said dye-barrier/subbing layer comprising poly(butyl acrylate-co-2-aminoethyl metacrylate-co-2-hydroxyethyl methacrylate), poly(N-isopropylacrylamide-co-2-aminoethyl)metacrylate-co-(2-hydroxyethyl methacrylate), poly[(2-chloroethyl)acrylamide-co-methacrylic acid], or gelatin nitrate.
Claim 15
Dependent Claim 22 words
The assemblage of claim 11 wherein said dye-barrier/subbing layer is present in an amount of up to about 1.8 g/m 2 .
Claim 16
Dependent Claim 12 words
The assmeblage of claim 11 wherein said dye-barrier/subbing layer is gelatin nitrate.
Claim 17
Dependent Claim 16 words
The assemblage of claim 11 wherein said dye layer comprises a sublimable dye in a binder.
Claim 18
Dependent Claim 29 words
The assemblage of claim 11 wherein the side of the support, opposite the side having thereon said dye layer, is coated with a slipping layer comprising a lubricating material.
Claim 19
Dependent Claim 15 words
The assemblage of claim 11 wherein said support of the dye-donor element comprises poly(ethylene terephthalate).
Claim 20
Dependent Claim 19 words
The assemblage of claim 16 wherein said dye layer comprises sequential repeating areas of cyan, magenta and yellow dye.

References Cited (Backward Citations)

US4253838A Cited
US4027345A Cited
US4021591A Cited
EP0109295A2 Cited
JPS6019138A Cited
EP0138483A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-10-12 1991-04-13 1991-10-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-10-12 1995-04-13 1995-10-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-10-12 1999-04-13 1999-10-13 $7700.00 Window Closed / Lapsed

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