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US4697011A Expired / Lapsed US ⏱️ 0.0 years remaining

N-fluoro-N-perfluoromethyl sulfonamides

Assignee: Research Corp
•
Filing: 1986-07-18
•
Granted: 1987-09-29
•
Expires: 2006-07-18
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Abstract

Abstract N-fluoro-N-perfluoromethyl sulfonamide compounds are provided as fluorinating agents for the fluorination of organic compounds by either the direct electrophilic fluorination of organic compounds or by the fluorination of organic compound carbanions.

Inventors

  • 👤 Darryl D. DesMarteau

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 14:09
CPC Classifications
C; C07; C07D; C07D285/00; C07D285/01; C07B; C07B39/00; C07C; C07C17/00; C07C17/093; C07C17/10; C07C17/12; C07C37/00; C07C37/62; C07C41/00; C07C41/01; C07C41/18; C07C41/22; C07D285/15; C07J; C07J1/00; C07J1/0051; C07J1/0059

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 117 words
##STR11## wherein R is a hydrocarbon radical which is substituted or is unsubstituted and which is a C 1-30 branched or straight chain alkyl, C 3-30 cycloalkyl, or aryl (C 1-10 alkyl) or aryl group wherein aryl and aryl are C 6-14 arylene, R f is a perfluorinated radical which is C 2-30 branched or straight chain alkyl, C 3-30 cycloalkyl, or aryl (C 1-10 alkyl) or aryl group wherein aryl and aryl are C 6-14 arylene, R' f is a perfluorinated radical which is (CF 2 ) n' wherein n'is 1 to 4, a is 0 or 1 and m is 1 or 2, n is 0 or 1, p is 0 or 1 and m+n+p=2.
Claim 2
Dependent Claim 117 words
##STR11## wherein R is a hydrocarbon radical which is substituted or is unsubstituted and which is a C 1-30 branched or straight chain alkyl, C 3-30 cycloalkyl, or aryl (C 1-10 alkyl) or aryl group wherein aryl and aryl are C 6-14 arylene, R f is a perfluorinated radical which is C 2-30 branched or straight chain alkyl, C 3-30 cycloalkyl, or aryl (C 1-10 alkyl) or aryl group wherein aryl and aryl are C 6-14 arylene, R' f is a perfluorinated radical which is (CF 2 ) n' wherein n'is 1 to 4, a is 0 or 1 and m is 1 or 2, n is 0 or 1, p is 0 or 1 and m+n+p=2.
Claim 3
Dependent Claim 10 words
A compound as in claim 1 which has formula I.
Claim 4
Dependent Claim 10 words
A compound as in claim 1 which has formula II.
Claim 5
Dependent Claim 10 words
A compound as in claim 1 which has formula III.
Claim 6
Dependent Claim 10 words
A compound as in claim 1 which has formula IV.
Claim 7
Dependent Claim 19 words
A compound as in claim 2 which has the formula (CF 3 SO 2 ) m NF(R) n .
Claim 8
Dependent Claim 17 words
A compound as in claim 6 which has the formula (CF 3 SO 2 ) 2 NF).
Claim 9
Dependent Claim 15 words
A compound as in claim 6 which has the formula (CF 3 SO 2 )N(F)R.
Claim 10
Dependent Claim 15 words
A compound as in claim 8 in which R is a C 1-30 alkyl group.
Claim 11
Dependent Claim 12 words
A compound as in claim 9 which has the formula (CF.sub.3 SO.sub.2)N(F)(CH.sub.3).
Claim 12
Dependent Claim 13 words
A compound as in claim 2 which has the formula (CF.sub.3 SO.sub.2)NF(R.sub.f SO.sub.2).
Claim 13
Dependent Claim 16 words
A compound as in claim 11 in which R f is a C 1-30 alkyl group.
Claim 14
Dependent Claim 16 words
A compound as in claim 12 in which R f is C 4 F 9 .
Claim 15
Dependent Claim 16 words
A compound as in claim 12 in which R f is C 6 F 13 .
Claim 16
Dependent Claim 11 words
A compound as in claim 5 in which n' is 2.
Claim 17
Dependent Claim 11 words
A compound as in claim 5 in which n' is 3.

References Cited (Backward Citations)

US3917688A Cited
GB1437074A Cited
US4387222A Cited
US4429093A Cited
US4479901A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-09-28 1991-03-30 1991-09-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-09-28 1995-03-30 1995-09-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-09-28 1999-03-30 1999-09-29 $7700.00 Window Closed / Lapsed

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