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US4695509A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyamide fiber reinforcement in thermoset polyurethane composites

Assignee: Honeywell International Inc
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Filing: 1985-12-23
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Granted: 1987-09-22
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Expires: 2005-12-23
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Abstract

Abstract Fiber-reinforced thermoset polyurethane composites display enhanced impact strength when sufficient amounts of a high tenacity aliphatic polyamide fiber characterized by a drawn denier of 4 to 8 denier per filament; a thermal shrinkage of up to about 14 percent; an elongation of from less than 28 percent; and a tenacity of at least 5.5, preferably at least 7 grams per denier, are incorporated into the composite. The process of producing such composites, including reinforced reaction injection molding processes, resin transfer molding processes, and casting process are improved by a reduction in equipment wear resulting from the incorporation of the specified polyamide fiber.

Inventors

  • 👤 Colleen W. Cordova
  • 👤 Hugh H. Rowan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 10:02
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/04; C08J5/046; C08J2375/00; C08J2375/04; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31562; Y10T442/00; Y10T442/20; Y10T442/2008; Y10T442/2861; Y10T442/2893

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 76 words
A fiber-reinforced thermoset polyurethane molded composite characterized by improved impact strength comprising molded thermoset polyurethane matrix reinforced with high tenacity polyamide fiber in an amount sufficient to provide said composite with said improved impact strength, said polyamide fiber characterized by a drawn denier of 4 to 8 denier per filament; a thermal shrinkage of up to about 14 percent; an elongation of less than 28 percent; and a tenacity of at least 5.5 grams per denier.
Claim 2
Dependent Claim 76 words
A fiber-reinforced thermoset polyurethane molded composite characterized by improved impact strength comprising molded thermoset polyurethane matrix reinforced with high tenacity polyamide fiber in an amount sufficient to provide said composite with said improved impact strength, said polyamide fiber characterized by a drawn denier of 4 to 8 denier per filament; a thermal shrinkage of up to about 14 percent; an elongation of less than 28 percent; and a tenacity of at least 5.5 grams per denier.
Claim 3
Dependent Claim 19 words
The composite of claim 1 wherein said polyamide fiber has a tenacity of at least 7 grams per denier.
Claim 4
Dependent Claim 20 words
The composite of claim 2 wherein said polyamide fiber is cut fiber having a length of at least 0.125 inch.
Claim 5
Dependent Claim 16 words
The composite of claim 2 wherein said polyamide fiber is in the form of nonwoven matt.
Claim 6
Dependent Claim 15 words
The composite of claim 2 wherein said polyamide fiber is in the form of fabric.
Claim 7
Dependent Claim 47 words
A process for the production of the composite of claim 1 comprising placing said polyamide fiber in the form of nonwoven mat or fabric into a mold; introducing a charge into the mold comprising a polymeric isocyanate, polyol, and curing agent; and curing to form said composite.
Claim 8
Dependent Claim 69 words
A process for the production of the composite of claim 1 comprising: (a) mixing said polyamide fiber in the form of cut fiber with at least one starting component for the production of thermoset polyurethane; (b) blending starting components for the production of thermoset polyurethane including the fiber-containing component of (a); (c) introducing said blend of starting components into a closed mold; (d) and curing to form said composite.
Claim 9
Dependent Claim 17 words
The process of claim 7 wherein said cut fiber has a length of at last 0.125 inch.

References Cited (Backward Citations)

US4233359A Cited
US4302493A Cited
US4501790A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-09-21 1991-03-23 1991-09-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-09-21 1995-03-23 1995-09-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-09-21 1999-03-23 1999-09-22 $7700.00 Window Closed / Lapsed

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