US4693960A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Photolithographic etching process using organosilicon polymer composition
Assignee: International Business Machines Corp
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Filing: 1986-11-07
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Granted: 1987-09-15
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Expires: 2006-11-07
Abstract
Abstract A composition containing a polysiloxane having a polymerizable ethylenically unsaturated group, and 2,2-dimethoxy-2-phenyl acetophenone as an ultraviolet light sensitizer; and use thereof in lithography.
Inventors
- 👤 Edward D. Babich
- 👤 Michael Hatzakis
- 👤 John J. Liutkis
- 👤 Juri R. Parasczak
- 👤 Jane M. Shaw
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 03:54
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/075; G03F7/0757; C; C08; C08K; C08K5/00; C08K5/04; C08K5/07; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/118; Y10S430/119
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
148 words
A process for producing an image which comprises providing on a substrate a layer of an ultraviolet light-sensitive negative resist composition consisting essentially of: (a) polysiloxane having polymerizable ethylenically unsaturated groups wherein said polysiloxane contains about 0.1% to about 20% by weight of ethylenically unsaturated groups per molecule and wherein said polysiloxane also contains phenyl or substituted phenyl groups, and (b) 2,2-dimethoxy-2-phenyl acetophenone in an amount sufficient to improve the sensitivity to ultraviolet light radiation, and being at least about 0.1% by weight based upon the polysiloxane. imagewise exposing the layer of light-sensitive composition to imaging ultraviolet radiation in a desired pattern and developing the exposed layer, thereby leaving the desired pattern of the layer of light-sensitive negative resist composition remaining on the substrate, and then etching the substrate by a dry etching process using the pattern of the layer of light-sensitive negative resist composition as the mask.
Claim 2
Dependent Claim
148 words
A process for producing an image which comprises providing on a substrate a layer of an ultraviolet light-sensitive negative resist composition consisting essentially of: (a) polysiloxane having polymerizable ethylenically unsaturated groups wherein said polysiloxane contains about 0.1% to about 20% by weight of ethylenically unsaturated groups per molecule and wherein said polysiloxane also contains phenyl or substituted phenyl groups, and (b) 2,2-dimethoxy-2-phenyl acetophenone in an amount sufficient to improve the sensitivity to ultraviolet light radiation, and being at least about 0.1% by weight based upon the polysiloxane. imagewise exposing the layer of light-sensitive composition to imaging ultraviolet radiation in a desired pattern and developing the exposed layer, thereby leaving the desired pattern of the layer of light-sensitive negative resist composition remaining on the substrate, and then etching the substrate by a dry etching process using the pattern of the layer of light-sensitive negative resist composition as the mask.
Claim 3
Dependent Claim
19 words
The process of claim 1 wherein said composition is the top imaging layer in a double layer imaging process.
Claim 4
Dependent Claim
22 words
The process of claim 2 wherein the bottom layer in the double layer imaging process is etched using a dry etching process.
Claim 5
Dependent Claim
18 words
The process of claim 3 wherein said dry etching process is a reactive ion etching in oxygen plasma.
Claim 6
Dependent Claim
11 words
The process of claim 1 wherein said polysiloxane is a gum.
Claim 7
Dependent Claim
13 words
The process of claim 1 wherein said polysiloxane is a polydimethyl-diphenyl vinyl siloxane.
Claim 8
Dependent Claim
24 words
The process of claim 1 wherein said acetophenone is present in amounts of about 1% to about 20% by weight based upon the polysiloxane.
Claim 9
Dependent Claim
23 words
The process of claim 1 wherein said acetophenone is present in amounts of about 5% to 15% by weight based upon the polysiloxane.
Claim 10
Dependent Claim
22 words
The process of claim 1 wherein said polysiloxane contains about 0.1% to about 0.5% by weight of ethylenically unsaturated groups per molecule.
Claim 11
Dependent Claim
18 words
The process of claim 1 wherein said dry etching process is a reactive ion etching in oxygen plasma.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-09-14 | 1991-03-16 | 1991-09-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-09-14 | 1995-03-16 | 1995-09-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-09-14 | 1999-03-16 | 1999-09-15 | $7700.00 | Window Closed / Lapsed |