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US4693960A Expired / Lapsed US ⏱️ 0.0 years remaining

Photolithographic etching process using organosilicon polymer composition

Assignee: International Business Machines Corp
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Filing: 1986-11-07
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Granted: 1987-09-15
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Expires: 2006-11-07
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Abstract

Abstract A composition containing a polysiloxane having a polymerizable ethylenically unsaturated group, and 2,2-dimethoxy-2-phenyl acetophenone as an ultraviolet light sensitizer; and use thereof in lithography.

Inventors

  • 👤 Edward D. Babich
  • 👤 Michael Hatzakis
  • 👤 John J. Liutkis
  • 👤 Juri R. Parasczak
  • 👤 Jane M. Shaw

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 03:54
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/075; G03F7/0757; C; C08; C08K; C08K5/00; C08K5/04; C08K5/07; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/118; Y10S430/119

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 148 words
A process for producing an image which comprises providing on a substrate a layer of an ultraviolet light-sensitive negative resist composition consisting essentially of: (a) polysiloxane having polymerizable ethylenically unsaturated groups wherein said polysiloxane contains about 0.1% to about 20% by weight of ethylenically unsaturated groups per molecule and wherein said polysiloxane also contains phenyl or substituted phenyl groups, and (b) 2,2-dimethoxy-2-phenyl acetophenone in an amount sufficient to improve the sensitivity to ultraviolet light radiation, and being at least about 0.1% by weight based upon the polysiloxane. imagewise exposing the layer of light-sensitive composition to imaging ultraviolet radiation in a desired pattern and developing the exposed layer, thereby leaving the desired pattern of the layer of light-sensitive negative resist composition remaining on the substrate, and then etching the substrate by a dry etching process using the pattern of the layer of light-sensitive negative resist composition as the mask.
Claim 2
Dependent Claim 148 words
A process for producing an image which comprises providing on a substrate a layer of an ultraviolet light-sensitive negative resist composition consisting essentially of: (a) polysiloxane having polymerizable ethylenically unsaturated groups wherein said polysiloxane contains about 0.1% to about 20% by weight of ethylenically unsaturated groups per molecule and wherein said polysiloxane also contains phenyl or substituted phenyl groups, and (b) 2,2-dimethoxy-2-phenyl acetophenone in an amount sufficient to improve the sensitivity to ultraviolet light radiation, and being at least about 0.1% by weight based upon the polysiloxane. imagewise exposing the layer of light-sensitive composition to imaging ultraviolet radiation in a desired pattern and developing the exposed layer, thereby leaving the desired pattern of the layer of light-sensitive negative resist composition remaining on the substrate, and then etching the substrate by a dry etching process using the pattern of the layer of light-sensitive negative resist composition as the mask.
Claim 3
Dependent Claim 19 words
The process of claim 1 wherein said composition is the top imaging layer in a double layer imaging process.
Claim 4
Dependent Claim 22 words
The process of claim 2 wherein the bottom layer in the double layer imaging process is etched using a dry etching process.
Claim 5
Dependent Claim 18 words
The process of claim 3 wherein said dry etching process is a reactive ion etching in oxygen plasma.
Claim 6
Dependent Claim 11 words
The process of claim 1 wherein said polysiloxane is a gum.
Claim 7
Dependent Claim 13 words
The process of claim 1 wherein said polysiloxane is a polydimethyl-diphenyl vinyl siloxane.
Claim 8
Dependent Claim 24 words
The process of claim 1 wherein said acetophenone is present in amounts of about 1% to about 20% by weight based upon the polysiloxane.
Claim 9
Dependent Claim 23 words
The process of claim 1 wherein said acetophenone is present in amounts of about 5% to 15% by weight based upon the polysiloxane.
Claim 10
Dependent Claim 22 words
The process of claim 1 wherein said polysiloxane contains about 0.1% to about 0.5% by weight of ethylenically unsaturated groups per molecule.
Claim 11
Dependent Claim 18 words
The process of claim 1 wherein said dry etching process is a reactive ion etching in oxygen plasma.

References Cited (Backward Citations)

US3696068A Cited
US4052529A Cited
US4208471A Cited
US4491508A Cited
US4539357A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-09-14 1991-03-16 1991-09-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-09-14 1995-03-16 1995-09-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-09-14 1999-03-16 1999-09-15 $7700.00 Window Closed / Lapsed

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