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US4690883A Expired / Lapsed US ⏱️ 0.0 years remaining

Image forming process

Assignee: Fujifilm Holdings Corp
•
Filing: 1985-12-13
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Granted: 1987-09-01
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Expires: 2005-12-13
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Abstract

Abstract A process for forming an image is provided, comprising imagewise exposing a photosensitive material comprising on a support a photosensitive silver halide, a sensitizing dye having general formula (I) and/or (II), and a compound which forms or releases a mobile dye in proportion or counter-proportion to the reduction of the photosensitive silver halide into silver by heating, and transferring the resulting mobile dye to a dye-fixing element in the presence of a hydrophilic solvent, wherein formulas (I) and (II) are: ##STR1## wherein Z 1 and Z 2 represent a group of non-metallic atoms necessary to form a 5- or 6-membered heterocyclic ring; R 1 and R 2 represent a substituted or unsubstituted alkyl group; L 1 , L 2 , and L 3 represent a substituted or unsubstituted methine group; p and q are equal to 0 or 1; m is equal to 0, 1, 2, or 3; X1.sup.⊖ represents an anion; k is equal to 0 or 1, with the proviso that the number of organic acid groups contained in the molecule except X1.sup.⊖ is up to 1, and Z 3 has the same meaning as Z 1 and Z 2 ; R 3 has the same meaning as R 1 and R 2 except an alkyl group having an acid group; L 4 and L 5 have the same meaning as L 1 , L 2 , and L 3 ; Z 4 represents a group of non-metallic atoms necessary to form a 5- or 6-membered heterocyclic ring; R 4 represents a hydrogen atom, or a substituted or unsubstituted alkyl, aryl or heterocyclic group; r has the same meaning as p and q; and n has the same meaning as m.

Inventors

  • 👤 Seiiti Kubodera
  • 👤 Masaki Okazaki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 03:59
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/08; G03C1/10; G03C1/12; G03C8/00; G03C8/40; G03C8/4013; G03C8/404

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 343 words
A process for forming an image, comprising imagewise exposing a photosensitive material comprising on a support a photosensitive silver halide, a sensitizing dye having general formula (I) and/or (II) as defined below, and a compound which forms or releases a mobile dye in proportion or counterproportion to the reduction of the photosensitive silver halide into silver by heating, and transferring the resulting mobile dye to a dye-fixing element in the presence of a hydrophilic solvent as a dye transfer assistant, said hydrophilic solvent consisting essentially of water, wherein formula (I) is: ##STR31## wherein Z 1 and Z 2 individually represent a group of non-metallic atoms necessary to form a 5- or 6-membered heterocyclic ring, Z 1 and Z 2 may be the same or different, R 1 and R 2 individually represent a substituted or unsubstituted alkyl group, R 1 and R 2 may be the same or different, L 1 , L 2 and L 3 individually represent a substituted or unsubstituted methine group, p and q are individually equal to 0 or 1, m is equal to 0, 1, 2, or 3, X 1 .sup.⊖ represents an anion, k is equal to 0 or 1, with the proviso that the number of organic acid groups contained in the molecular except X 1 .sup.⊖ is up to 1, and formula (II) is: ##STR32## wherein Z 3 has the same meaning as Z 1 and Z 2 , R 3 has the same meaning as R 1 and R 2 except an alkyl group having an acid group, L 4 and L 5 have the same meaning as L 1 , L 2 , and L 3 , Z 4 represents a group of non-metallic atoms necessary to form a 5- or 6-membered heterocyclic ring, R 4 represents a hydrogen atom, or a substituted or unsubstituted alkyl, aryl or heterocyclic group, r has the same meaning as p and q, and n has the same meaning as m, wherein the imagewise exposed photosensitive material is heated to develop the imagewise exposed photosensitive material.
Claim 2
Dependent Claim 343 words
A process for forming an image, comprising imagewise exposing a photosensitive material comprising on a support a photosensitive silver halide, a sensitizing dye having general formula (I) and/or (II) as defined below, and a compound which forms or releases a mobile dye in proportion or counterproportion to the reduction of the photosensitive silver halide into silver by heating, and transferring the resulting mobile dye to a dye-fixing element in the presence of a hydrophilic solvent as a dye transfer assistant, said hydrophilic solvent consisting essentially of water, wherein formula (I) is: ##STR31## wherein Z 1 and Z 2 individually represent a group of non-metallic atoms necessary to form a 5- or 6-membered heterocyclic ring, Z 1 and Z 2 may be the same or different, R 1 and R 2 individually represent a substituted or unsubstituted alkyl group, R 1 and R 2 may be the same or different, L 1 , L 2 and L 3 individually represent a substituted or unsubstituted methine group, p and q are individually equal to 0 or 1, m is equal to 0, 1, 2, or 3, X 1 .sup.⊖ represents an anion, k is equal to 0 or 1, with the proviso that the number of organic acid groups contained in the molecular except X 1 .sup.⊖ is up to 1, and formula (II) is: ##STR32## wherein Z 3 has the same meaning as Z 1 and Z 2 , R 3 has the same meaning as R 1 and R 2 except an alkyl group having an acid group, L 4 and L 5 have the same meaning as L 1 , L 2 , and L 3 , Z 4 represents a group of non-metallic atoms necessary to form a 5- or 6-membered heterocyclic ring, R 4 represents a hydrogen atom, or a substituted or unsubstituted alkyl, aryl or heterocyclic group, r has the same meaning as p and q, and n has the same meaning as m, wherein the imagewise exposed photosensitive material is heated to develop the imagewise exposed photosensitive material.
Claim 3
Dependent Claim 61 words
The process of claim 1 wherein the heterocyclic ring formed by each of Z 1 and Z 2 has a thiazole nucleus, benzothiazole nucleus, naphthothiazole nucleus, thiazoline nucleus, oxazole nucleus, benzoxazole nucleus, naphthoxazole nucleus, oxazoline nucleus, selenazole nucleus, benzoselenazole nucleus, naphthoselenazole nucleus, 3,3-dialkylindolenine nucleus, imidazole nucleus, pyridine nucleus, quinoline nucleus, imidazo[4,5-b]quinoxaline nucleus, oxadiazole nucleus, thiadiazole nucleus, tetrazole nucleus, or pyrimidine nucleus.
Claim 4
Dependent Claim 25 words
The process of claim 1 wherein R 1 and R 2 independently represent a substituted or unsubstituted alkyl group having 1 to 18 carbon atoms.
Claim 5
Dependent Claim 17 words
The process of claim 1 wherein X1.sup.⊖ represents a halogen ion, substituted arylsulfonate ion, or alkoxysulfonate ion.
Claim 6
Dependent Claim 56 words
The process of claim 1 wherein the heterocyclic ring formed by Z 3 has a thiazole nucleus, benzothiazole nucleus, naphthothiazole nucleus, thiazoline nucleus, oxazole nucleus, benzoxazole nucleus, naphthoxazole nucleus, oxazoline nucleus, selenazole nucleus, benzoselenazole nucleus, naphthoselenazole nucleus, 3,3-dialkylindolenine nucleus, imidazole nucleus, pyridine nucleus, quinoline nucleus, imidazo[4,5-b]quinoxaline nucleus, oxadiazole nucleus, thiadiazole nucleus, tetrazole nucleus, or pyrimidine nucleus.
Claim 7
Dependent Claim 29 words
The process of claim 1 wherein R 3 represents a substituted or unsubstituted alkyl group having 1 to 18 carbon atoms except the alkyl groups having an acid group.
Claim 8
Dependent Claim 40 words
The process of claim 1 wherein the heterocyclic ring formed by Z 4 has a rhodanine nucleus, 2-thiohydantoin nucleus, 2-thioxoxazolidin-4-one nucleus, 2-pyrazolin-5-one nucleus, barbituric acid nucleus, 2-thiobarbituric acid nucleus, thiazolidin-2,4-dione nucleus, thiazolidin-4-one nucleus, isooxazolone nucleus, hydantoin nucleus, or indanedione nucleus.
Claim 9
Dependent Claim 54 words
The process of claim 1 wherein R 4 represents a hydrogen atom, unsubstituted alkyl group having 1 to 18 carbon atoms, substituted alkyl group having 1 to 20 carbon atoms, unsubstituted aryl group having 6 to 20 carbon atoms, substituted aryl group having 6 to 24 carbon atoms, or substituted or unsubstituted heterocyclic group.
Claim 10
Dependent Claim 13 words
The process of claim 1, wherein the hydrophilic solvent is water per se.
Claim 11
Dependent Claim 13 words
The process of claim 1, wherein the sensitizing dye has general formula (I).
Claim 12
Dependent Claim 13 words
The process of claim 10, wherein the sensitizing dye has general formula (II).

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-08-31 1991-03-02 1991-09-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-08-31 1995-03-02 1995-09-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-08-31 1999-03-02 1999-09-01 $7700.00 Window Closed / Lapsed

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