US4686255A
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Stabilized polyvinyl chloride molding compositions
Assignee: Henkel AG and Co KGaA
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Filing: 1984-08-30
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Granted: 1987-08-11
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Expires: 2004-08-30
Abstract
Abstract Stabilized polyvinyl chloride molding compositions contain, per 100 parts by weight of polymer, 0.02 to 5 parts by weight compounds of Formula I, ##STR1## in which R represents an alkyl group with 1 to 19 carbon atoms, a cycloalkyl group with 5 or 6 carbon atoms, a phenyl group, an alkylphenyl group with 7 to 11 carbon atoms or an MOOC--CH 2 group, n represents the numbers 0 and 1, and M represents sodium or potassium. Heat stabilizers which are metal soaps, aromatic metal carboxylates, metal phenolates and organotin compounds as well as crystalline sodium aluminosilicate are also incorporated.
Inventors
- 👤 Werner Erwied
- 👤 Horst Upadek
- 👤 Bernd Wegemund
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 10:50
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/09; C08K5/098
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
173 words
Stabilized polyvinyl chloride molding compositions containing a stabilizer combination consisting of (1) a primary stabilizer selected from the group consisting of metal soaps, aromatic metal carboxylates, metal phenolates, and organotin compounds, (2) a co-stabilizer having the structural formula: ##STR4## wherein R represents an alkyl group with 1 to 19 carbon atoms, a cycloalkyl group with 5 or 6 carbon atoms, a phenyl group, an alkylphenyl group with 7 to 11 carbon atoms, or an MOOC--CH 2 group; n represents the numbers 0 or 1; and M represents lithium, sodium or potassium; said co-stabilizer being present in an amount of from about 0.02 to about 5 parts by weight, based on 100 parts by weight of said polyvinyl choride, and (3) from about 0.2 to about 5 parts by weight, based on 100 parts by weight of said polyvinyl chloride, of a synthetic, crystalline, finely-divided sodium aluminosilicate containing 13 to 25% by weight of bound water which, based on the anhydrous form, has the composition 0.7-1.1Na 2 .Al 2 O 3 .1.3-2.4SiO 2 .
Claim 2
Dependent Claim
173 words
Stabilized polyvinyl chloride molding compositions containing a stabilizer combination consisting of (1) a primary stabilizer selected from the group consisting of metal soaps, aromatic metal carboxylates, metal phenolates, and organotin compounds, (2) a co-stabilizer having the structural formula: ##STR4## wherein R represents an alkyl group with 1 to 19 carbon atoms, a cycloalkyl group with 5 or 6 carbon atoms, a phenyl group, an alkylphenyl group with 7 to 11 carbon atoms, or an MOOC--CH 2 group; n represents the numbers 0 or 1; and M represents lithium, sodium or potassium; said co-stabilizer being present in an amount of from about 0.02 to about 5 parts by weight, based on 100 parts by weight of said polyvinyl choride, and (3) from about 0.2 to about 5 parts by weight, based on 100 parts by weight of said polyvinyl chloride, of a synthetic, crystalline, finely-divided sodium aluminosilicate containing 13 to 25% by weight of bound water which, based on the anhydrous form, has the composition 0.7-1.1Na 2 .Al 2 O 3 .1.3-2.4SiO 2 .
Claim 3
Dependent Claim
56 words
Stabilized polyvinyl chloride molding compositions in accordance with claim 1, wherein said primary stabilizer is a metal soap selected from the group consisting of calcium soap, barium soap, and zinc soap, and is present in an amount of from about 0.1 to 3 parts by weight, based on 100 parts by weight of said polyvinyl chloride.
Claim 4
Dependent Claim
25 words
Stabilized polyvinyl chloride molding compositions in accordance with claim 2 wherein said metal soap is derived from fatty acids containing 8 to 22 carbon atoms.
Claim 5
Dependent Claim
98 words
Stabilized polyvinyl chloride molding compositions in accordance with claim 1, including from about 0.2 to about 5 parts by weight, based on 100 parts by weight of said polyvinyl chloride, of a compound having the formula selected from the group consisting of: ##STR5## wherein X 1 and X 2 independently of one another represent hydrogen or the SH group, wherein at least one of the substitutents X 1 and X 2 represents an SH group and in which R 1 , R 2 and R 3 represent straight-chain and branched alkyl groups with 5 to 22 carbon atoms.
Claim 6
Dependent Claim
171 words
A stabilizer combination for polyvinyl chloride molding compositions consisting of (1) a primary stabilizer selected from the group consisting of metal soaps, aromatic metal carboxylates, metal phenolates, and organotin compounds, (2) a co-stabilizer having the structural formula: ##STR6## wherein R represents an alkyl group with 1 to 19 carbon atoms, a cycloalkyl group with 5 or 6 carbon atoms, a phenyl group, an alkylphenyl group with 7 to 11 carbon atoms, or an MOOC--CH 2 group; n represents the numbers 0 or 1; and M represents lithium, sodium or potassium; said co-stabilizer being present in an amount of from about 0.02 to about 5 parts by weight, based on 100 parts by weight of said polyvinyl chloride, and (3) about 0.2 to about 5 parts by weight, based on 100 parts by weight of said polyvinyl chloride, of a synthetic, crystalline, finely-divided sodium aluminosilicate containing 13 to 25% by weight of bound water which, based on the anhydrous form, has the composition 0.7-1.1Na 2 O.Al 2 O 3 .1.3-2.4SiO 2 .
Claim 7
Dependent Claim
171 words
A stabilizer combination for polyvinyl chloride molding compositions consisting of (1) a primary stabilizer selected from the group consisting of metal soaps, aromatic metal carboxylates, metal phenolates, and organotin compounds, (2) a co-stabilizer having the structural formula: ##STR6## wherein R represents an alkyl group with 1 to 19 carbon atoms, a cycloalkyl group with 5 or 6 carbon atoms, a phenyl group, an alkylphenyl group with 7 to 11 carbon atoms, or an MOOC--CH 2 group; n represents the numbers 0 or 1; and M represents lithium, sodium or potassium; said co-stabilizer being present in an amount of from about 0.02 to about 5 parts by weight, based on 100 parts by weight of said polyvinyl chloride, and (3) about 0.2 to about 5 parts by weight, based on 100 parts by weight of said polyvinyl chloride, of a synthetic, crystalline, finely-divided sodium aluminosilicate containing 13 to 25% by weight of bound water which, based on the anhydrous form, has the composition 0.7-1.1Na 2 O.Al 2 O 3 .1.3-2.4SiO 2 .
Claim 8
Dependent Claim
59 words
A stabilizer combination for polyvinyl chloride molding compositions in accordance with claim 5 wherein said primary stabilizer is a metal soap selected from the group consisting of calcium soap, barium soap, and zinc soap, and is present in an amount of from about 0.1 to 3 parts by weight, based on 100 parts by weight of said polyvinyl chloride.
Claim 9
Dependent Claim
28 words
A stabilizer combination for polyvinyl chloride molding compositions in accordance with claim 6 wherein said metal soap is derived from fatty acids containing 8 to 22 carbon atoms.
Claim 10
Dependent Claim
101 words
A stabilizer combination for polyvinyl chloride molding compositions in accordance with claim 5 including from about 0.2 to about 5 parts by weight, based on 100 parts by weight of said polyvinyl chloride, of a compound having the formula selected from the group consisting of: ##STR7## wherein X 1 and X 2 independently of one another represent hydrogen or the SH group, wherein at least one of the substituents X 1 and X 2 represents an SH group and in which R 1 , R 2 and R 3 represent straight-chain and branched alkyl groups with 5 to 22 carbon atoms.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-08-10 | 1991-02-09 | 1991-08-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-08-10 | 1995-02-09 | 1995-08-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-08-10 | 1999-02-09 | 1999-08-11 | $7700.00 | Window Closed / Lapsed |