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US4686255A Expired / Lapsed US ⏱️ 0.0 years remaining

Stabilized polyvinyl chloride molding compositions

Assignee: Henkel AG and Co KGaA
•
Filing: 1984-08-30
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Granted: 1987-08-11
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Expires: 2004-08-30
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Abstract

Abstract Stabilized polyvinyl chloride molding compositions contain, per 100 parts by weight of polymer, 0.02 to 5 parts by weight compounds of Formula I, ##STR1## in which R represents an alkyl group with 1 to 19 carbon atoms, a cycloalkyl group with 5 or 6 carbon atoms, a phenyl group, an alkylphenyl group with 7 to 11 carbon atoms or an MOOC--CH 2 group, n represents the numbers 0 and 1, and M represents sodium or potassium. Heat stabilizers which are metal soaps, aromatic metal carboxylates, metal phenolates and organotin compounds as well as crystalline sodium aluminosilicate are also incorporated.

Inventors

  • 👤 Werner Erwied
  • 👤 Horst Upadek
  • 👤 Bernd Wegemund

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 10:50
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/09; C08K5/098

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 173 words
Stabilized polyvinyl chloride molding compositions containing a stabilizer combination consisting of (1) a primary stabilizer selected from the group consisting of metal soaps, aromatic metal carboxylates, metal phenolates, and organotin compounds, (2) a co-stabilizer having the structural formula: ##STR4## wherein R represents an alkyl group with 1 to 19 carbon atoms, a cycloalkyl group with 5 or 6 carbon atoms, a phenyl group, an alkylphenyl group with 7 to 11 carbon atoms, or an MOOC--CH 2 group; n represents the numbers 0 or 1; and M represents lithium, sodium or potassium; said co-stabilizer being present in an amount of from about 0.02 to about 5 parts by weight, based on 100 parts by weight of said polyvinyl choride, and (3) from about 0.2 to about 5 parts by weight, based on 100 parts by weight of said polyvinyl chloride, of a synthetic, crystalline, finely-divided sodium aluminosilicate containing 13 to 25% by weight of bound water which, based on the anhydrous form, has the composition 0.7-1.1Na 2 .Al 2 O 3 .1.3-2.4SiO 2 .
Claim 2
Dependent Claim 173 words
Stabilized polyvinyl chloride molding compositions containing a stabilizer combination consisting of (1) a primary stabilizer selected from the group consisting of metal soaps, aromatic metal carboxylates, metal phenolates, and organotin compounds, (2) a co-stabilizer having the structural formula: ##STR4## wherein R represents an alkyl group with 1 to 19 carbon atoms, a cycloalkyl group with 5 or 6 carbon atoms, a phenyl group, an alkylphenyl group with 7 to 11 carbon atoms, or an MOOC--CH 2 group; n represents the numbers 0 or 1; and M represents lithium, sodium or potassium; said co-stabilizer being present in an amount of from about 0.02 to about 5 parts by weight, based on 100 parts by weight of said polyvinyl choride, and (3) from about 0.2 to about 5 parts by weight, based on 100 parts by weight of said polyvinyl chloride, of a synthetic, crystalline, finely-divided sodium aluminosilicate containing 13 to 25% by weight of bound water which, based on the anhydrous form, has the composition 0.7-1.1Na 2 .Al 2 O 3 .1.3-2.4SiO 2 .
Claim 3
Dependent Claim 56 words
Stabilized polyvinyl chloride molding compositions in accordance with claim 1, wherein said primary stabilizer is a metal soap selected from the group consisting of calcium soap, barium soap, and zinc soap, and is present in an amount of from about 0.1 to 3 parts by weight, based on 100 parts by weight of said polyvinyl chloride.
Claim 4
Dependent Claim 25 words
Stabilized polyvinyl chloride molding compositions in accordance with claim 2 wherein said metal soap is derived from fatty acids containing 8 to 22 carbon atoms.
Claim 5
Dependent Claim 98 words
Stabilized polyvinyl chloride molding compositions in accordance with claim 1, including from about 0.2 to about 5 parts by weight, based on 100 parts by weight of said polyvinyl chloride, of a compound having the formula selected from the group consisting of: ##STR5## wherein X 1 and X 2 independently of one another represent hydrogen or the SH group, wherein at least one of the substitutents X 1 and X 2 represents an SH group and in which R 1 , R 2 and R 3 represent straight-chain and branched alkyl groups with 5 to 22 carbon atoms.
Claim 6
Dependent Claim 171 words
A stabilizer combination for polyvinyl chloride molding compositions consisting of (1) a primary stabilizer selected from the group consisting of metal soaps, aromatic metal carboxylates, metal phenolates, and organotin compounds, (2) a co-stabilizer having the structural formula: ##STR6## wherein R represents an alkyl group with 1 to 19 carbon atoms, a cycloalkyl group with 5 or 6 carbon atoms, a phenyl group, an alkylphenyl group with 7 to 11 carbon atoms, or an MOOC--CH 2 group; n represents the numbers 0 or 1; and M represents lithium, sodium or potassium; said co-stabilizer being present in an amount of from about 0.02 to about 5 parts by weight, based on 100 parts by weight of said polyvinyl chloride, and (3) about 0.2 to about 5 parts by weight, based on 100 parts by weight of said polyvinyl chloride, of a synthetic, crystalline, finely-divided sodium aluminosilicate containing 13 to 25% by weight of bound water which, based on the anhydrous form, has the composition 0.7-1.1Na 2 O.Al 2 O 3 .1.3-2.4SiO 2 .
Claim 7
Dependent Claim 171 words
A stabilizer combination for polyvinyl chloride molding compositions consisting of (1) a primary stabilizer selected from the group consisting of metal soaps, aromatic metal carboxylates, metal phenolates, and organotin compounds, (2) a co-stabilizer having the structural formula: ##STR6## wherein R represents an alkyl group with 1 to 19 carbon atoms, a cycloalkyl group with 5 or 6 carbon atoms, a phenyl group, an alkylphenyl group with 7 to 11 carbon atoms, or an MOOC--CH 2 group; n represents the numbers 0 or 1; and M represents lithium, sodium or potassium; said co-stabilizer being present in an amount of from about 0.02 to about 5 parts by weight, based on 100 parts by weight of said polyvinyl chloride, and (3) about 0.2 to about 5 parts by weight, based on 100 parts by weight of said polyvinyl chloride, of a synthetic, crystalline, finely-divided sodium aluminosilicate containing 13 to 25% by weight of bound water which, based on the anhydrous form, has the composition 0.7-1.1Na 2 O.Al 2 O 3 .1.3-2.4SiO 2 .
Claim 8
Dependent Claim 59 words
A stabilizer combination for polyvinyl chloride molding compositions in accordance with claim 5 wherein said primary stabilizer is a metal soap selected from the group consisting of calcium soap, barium soap, and zinc soap, and is present in an amount of from about 0.1 to 3 parts by weight, based on 100 parts by weight of said polyvinyl chloride.
Claim 9
Dependent Claim 28 words
A stabilizer combination for polyvinyl chloride molding compositions in accordance with claim 6 wherein said metal soap is derived from fatty acids containing 8 to 22 carbon atoms.
Claim 10
Dependent Claim 101 words
A stabilizer combination for polyvinyl chloride molding compositions in accordance with claim 5 including from about 0.2 to about 5 parts by weight, based on 100 parts by weight of said polyvinyl chloride, of a compound having the formula selected from the group consisting of: ##STR7## wherein X 1 and X 2 independently of one another represent hydrogen or the SH group, wherein at least one of the substituents X 1 and X 2 represents an SH group and in which R 1 , R 2 and R 3 represent straight-chain and branched alkyl groups with 5 to 22 carbon atoms.

References Cited (Backward Citations)

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GB771857A Cited
US2954362A Cited
US3398114A Cited
US3346536A Cited
US4000100A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-08-10 1991-02-09 1991-08-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-08-10 1995-02-09 1995-08-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-08-10 1999-02-09 1999-08-11 $7700.00 Window Closed / Lapsed

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