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US4686169A Expired / Lapsed US ⏱️ 0.0 years remaining

Optical recording medium and production of the same

Assignee: Panasonic Holdings Corp
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Filing: 1985-11-08
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Granted: 1987-08-11
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Expires: 2005-11-08
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Abstract

Abstract An optical recording medium comprising a substrate and an information recording layer which consists of monolayer assemblies comprising a photochromic compound of which is based on cis-trans isomerization such as an amphipathic derivative of azobenzene, indigo or thioindigo having a long chain substituent, which monolayers are formed on the substrate by the Langmuir-Blodgett method and oriented in a two-dimensional plain. When the recording medium is irradiated by light, light absorption spectrum of the recording layer changes so that information is recorded. Since the photochromic compound is oriented in a monolayer, its photochromism lasts long.

Inventors

  • 👤 Kimiaki Yoshino
  • 👤 Eiji Ando
  • 👤 Jinsei Miyazaki
  • 👤 Kazuhisa Morimoto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 18:29
CPC Classifications
G; G11; G11B; G11B7/00; G11B7/24; G11B7/241; G11B7/242; G11B7/244; B; B82; B82Y; B82Y30/00; Y; Y10; Y10S; Y10S430/00; Y10S430/136; Y10S430/146; Y10S430/162; Y10S430/163

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 48 words
An optical recording medium comprising a substrate and an information recording layer which consists of monomolecular layer assemblies comprising a photochromic dye which exhibits photochromism based on cis-trans isomerization and is stable in both cis and trans forms, which monomolecular layer assemblies are oriented in a two-dimensional plane.
Claim 2
Dependent Claim 48 words
An optical recording medium comprising a substrate and an information recording layer which consists of monomolecular layer assemblies comprising a photochromic dye which exhibits photochromism based on cis-trans isomerization and is stable in both cis and trans forms, which monomolecular layer assemblies are oriented in a two-dimensional plane.
Claim 3
Dependent Claim 16 words
An optical recording medium according to claim 1, wherein the photochromic dye has an amphipathic property.
Claim 4
Dependent Claim 19 words
An optical recording medium according to claim 1, wherein the monomolecular assemblies further comprises an amphipathic monomolecular film-forming compound.
Claim 5
Dependent Claim 22 words
An optical recording medium according to claim 1, wherein the photochromic compound is an amphipathic azobenzene derivative having a nitrogen-nitrogen double bond.
Claim 6
Dependent Claim 59 words
An optical recording medium according to claim 4, wherein the azobenzene derivative has a hydrophobic substituent on its chromophore ring selected from an alkyl group having at least 10 carbon atoms, an alkoxy group having at least 10 carbon atoms, an alkylacyl group having at least 10 carbon atoms and an alkylamino group having at least 10 carbon atoms.
Claim 7
Dependent Claim 14 words
An optical recording medium according to claim 5, wherein the azobenzene derivative is 4-monostearoylazobenzene.
Claim 8
Dependent Claim 27 words
An optical recording medium according to claim 2, wherein the amphipathic dye is one selected from the group consisting of an indigo derivative and a thioindigo derivative.
Claim 9
Dependent Claim 61 words
An optical recording medium according to claim 7, wherein the indigo or thioindigo derivative has a hydrophobic substituent on its chromophore ring selected from an alkyl group having at least 10 carbon atoms, an alkoxy group having at least 10 carbon atoms, an alkylacyl group having at least 10 carbon atoms and an alkylamino group having at least 10 carbon atoms.
Claim 10
Dependent Claim 14 words
An optical recording medium according to claim 8, wherein the indigo derivative is N,N'-diacylindigo.
Claim 11
Dependent Claim 12 words
An optical recording medium according to claim 9, wherein N,N'-diacylindigo is N,N'-distearoylindigo.
Claim 12
Dependent Claim 14 words
An optical recording medium according to claim 8, wherein the thioindigo derivative is 5-octadecylthioindigo.
Claim 13
Dependent Claim 14 words
An optical recording medium according to claim 8, wherein the thioindigo derivative is 5-octadecyl-5'-t-butylthioindigo.
Claim 14
Dependent Claim 14 words
An optical recording medium according to claim 8, wherein the thioindigo derivative is 5-octadecyl-1,8-naphtylthioindigo.

References Cited (Backward Citations)

US3715212A Cited
US4458004A Cited
US4539061A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-08-10 1991-02-09 1991-08-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-08-10 1995-02-09 1995-08-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-08-10 1999-02-09 1999-08-11 $7700.00 Window Closed / Lapsed

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