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US4684685A Expired / Lapsed US ⏱️ 0.0 years remaining

Readhering and removable adhesive

Assignee: Dennison Manufacturing Co
•
Filing: 1986-08-25
•
Granted: 1987-08-04
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Expires: 2006-08-25
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Abstract

Abstract A gelled solid adhesive for coating substrates, typically paper. The adhesive can be made available in stick form and is easily applied in even coats to any surface area of the substrate. The adhesive has sufficient tack enabling the coated substrate to instantly adhere to essentially any free contact surface upon gently pressing the substrate to the free surface. The adhesive coated substrate is easily removable from the contact surface by manually lifting it therefrom. The adhesive permits readherence of the adhesive coated substrate to the same or different free contact surfaces. An adhesive coated paper substrate will readhere many times to free paper contact surface. The preferred gelled adhesive product is formed of an aqueous dispersion of components which include a rubber such as natural rubber latex component, a friction reducing agent, a tackifier, an antioxidant, a gelling agent and surfactant. Preferred classes of tackifiers are anionic aqueous dispersion of hydrogenated esters of rosin and anionic aqueous dispersion of esters of hydrogenated rosin.

Inventors

  • 👤 Ralph J. Shuman
  • 👤 Barbara Burns

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 23:45
CPC Classifications
C; C09; C09J; C09J9/00; C09J9/005; C09J107/00; C09J107/02; C08; C08L; C08L2666/00; C08L2666/02; C08L2666/26; Y; Y10; Y10S; Y10S524/00; Y10S524/925

Claims Analysis

Total Claims: 30
Claim 1
Independent Claim 140 words
A gelled adhesive product in solid form comprising: a rubber component; a water soluble or water dispersible tackifying agent; and a gelling agent; said gelled adhesive product having the combination of properties resulting in an adhesive coatable onto a substrate surface area by gliding the adhesive product over the substrate surface, the adhesive having sufficient tack permitting the adhesive coated area on said substrate to immediately adhere to a solid contact surface as said adhesive coated substrate is pressed against the contact surface, the adhesive also having sufficient release property permitting removal of said adhesive coated substrate from said contact surface upon lifting the coated substrate from the contact surface, said adhesive having the additional property permitting said same adhesive coated substrate to readhere to a solid contact surface upon pressing said same coated substrate thereto without applying additional adhesive.
Claim 2
Dependent Claim 140 words
A gelled adhesive product in solid form comprising: a rubber component; a water soluble or water dispersible tackifying agent; and a gelling agent; said gelled adhesive product having the combination of properties resulting in an adhesive coatable onto a substrate surface area by gliding the adhesive product over the substrate surface, the adhesive having sufficient tack permitting the adhesive coated area on said substrate to immediately adhere to a solid contact surface as said adhesive coated substrate is pressed against the contact surface, the adhesive also having sufficient release property permitting removal of said adhesive coated substrate from said contact surface upon lifting the coated substrate from the contact surface, said adhesive having the additional property permitting said same adhesive coated substrate to readhere to a solid contact surface upon pressing said same coated substrate thereto without applying additional adhesive.
Claim 3
Dependent Claim 29 words
An adhesive product as in claim 1 wherein the tackifying agent is selected from the group consisting of the hydrogenated ester of rosin and the ester of hydrogenated rosin.
Claim 4
Dependent Claim 17 words
An adhesive product as in claim 2 wherein the tackifying agent comprises hydrogenated methyl ester of rosin.
Claim 5
Dependent Claim 18 words
An adhesive product as in claim 2 wherein the tackifying agent comprises the glycerol ester of hydrogenated rosin.
Claim 6
Dependent Claim 18 words
An adhesive product as in claim 1 further comprising a friction reducing agent comprising a polyhydric aliphatic alcohol.
Claim 7
Dependent Claim 14 words
An adhesive product as in claim 5 wherein the friction reducing agent is glycerine.
Claim 8
Dependent Claim 15 words
An adhesive product as in claim 5 wherein the friction reducing agent is propylene glycol.
Claim 9
Dependent Claim 11 words
An adhesive product as in claim 1 further comprising an antioxidant.
Claim 10
Dependent Claim 20 words
An adhesive product as in claim 1 wherein the gelling agent is a gel-forming salt of an aliphatic carboxylic acid.
Claim 11
Dependent Claim 21 words
An adhesive product as in claim 9 wherein the gel-forming salt of the aliphatic carboxylic acid has an alkali metal cation.
Claim 12
Dependent Claim 14 words
An adhesive product as in claim 1 wherein the gelling agent is sodium stearate.
Claim 13
Dependent Claim 18 words
An adhesive product as in claim 1 wherein the natural rubber latex component has a low ammonia content.
Claim 14
Dependent Claim 28 words
An adhesive product as in claim 1 wherein the rubber component comprises between about 5 to 20 percent by weight of the product on a water free basis.
Claim 15
Dependent Claim 28 words
An adhesive product as in claim 13 wherein the tackifying agent comprises between about 15 to 70 percent by weight of the product on a water free basis.
Claim 16
Dependent Claim 12 words
An adhesive product as in claim 1 having a substantially cylindrical shape.
Claim 17
Dependent Claim 13 words
A gelled adhesive product as in claim 1 wherein the substrate is paper.
Claim 18
Dependent Claim 44 words
A gelled adhesive product as in claim 16 wherein the substrate is paper and the contact surface is paper and the adhesive coated substrate has the property that it is removable from and will readhere at least eight times to a paper contact surface.
Claim 19
Dependent Claim 16 words
An adhesive product as in claim 1 further comprising an surfactant comprising an alkylaryl polyether alcohol.
Claim 20
Dependent Claim 24 words
An adhesive product as in claim 18 wherein the alkylaryl polyether alcohol is formed of the reaction product of an octylphenol and ethylene oxide.
Claim 21
Dependent Claim 24 words
An adhesive product as in claim 19 wherein the alkylaryl polyether alcohol comprises octylphenoxypolyethoxyethanol having an average of five ethylene oxide units per molecule.
Claim 22
Dependent Claim 148 words
In a gelled adhesive product in solid form comprising a water soluble or water dispersible tackifying agent and a gelling agent, the improvement comprising: the adhesive product further comprising a rubber component, said adhesive product having the combination of properties resulting in an adhesive coatable onto a substrate surface area by gliding the adhesive product over the substrate surface, the adhesive having sufficient tack permitting the adhesive coated area on said substrate to immediately adhere to a solid contact surface as said adhesive coated substrate is pressed against the contact surface, the adhesive also having sufficient release property permitting removal of said adhesive coated substrate from said contact surface upon lifting the coated substrate from the contact surface, said adhesive having the additional property permitting said same adhesive coated substrate to readhere to a solid contact surface upon pressing said same coated substrate thereto without applying additional adhesive.
Claim 23
Dependent Claim 148 words
In a gelled adhesive product in solid form comprising a water soluble or water dispersible tackifying agent and a gelling agent, the improvement comprising: the adhesive product further comprising a rubber component, said adhesive product having the combination of properties resulting in an adhesive coatable onto a substrate surface area by gliding the adhesive product over the substrate surface, the adhesive having sufficient tack permitting the adhesive coated area on said substrate to immediately adhere to a solid contact surface as said adhesive coated substrate is pressed against the contact surface, the adhesive also having sufficient release property permitting removal of said adhesive coated substrate from said contact surface upon lifting the coated substrate from the contact surface, said adhesive having the additional property permitting said same adhesive coated substrate to readhere to a solid contact surface upon pressing said same coated substrate thereto without applying additional adhesive.
Claim 24
Dependent Claim 29 words
An adhesive product as in claim 21 wherein the tackifying agent is selected from the group consisting of the hydrogenated ester of rosin and the ester of hydrogenated rosin.
Claim 25
Dependent Claim 18 words
An adhesive product as in claim 21 further comprising a friction reducing agent comprising a polyhydric aliphatic alcohol.
Claim 26
Dependent Claim 27 words
An adhesive product as in claim 21 further comprising a surfactant comprising an alkylaryl polyether alcohol formed of the reaction product of an octylphenol and ethylene oxide.
Claim 27
Dependent Claim 20 words
A gelled adhesive product as in claim 1 wherein the rubber component is capable of dispersion in water based emulsion.
Claim 28
Dependent Claim 29 words
A gelled adhesive product as in claim 1 wherein the rubber component is selected from the group consisting of natural rubber latex, styrene butadiene, butyl rubber and nitrile rubber.
Claim 29
Dependent Claim 20 words
A gelled adhesive product as in claim 21 wherein the rubber component is capable of dispersion in water based emulsion.
Claim 30
Dependent Claim 29 words
A gelled adhesive product as in claim 21 wherein the rubber component is selected from the group consisting of natural rubber latex, styrene butadiene, butyl rubber and nitrile rubber.

References Cited (Backward Citations)

US1932624A Cited
US1958745A Cited
US2325562A Cited
US2358761A Cited
US2382731A Cited
US3576776A Cited
US3681190A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-08-03 1991-02-02 1991-08-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-08-03 1995-02-02 1995-08-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-08-03 1999-02-02 1999-08-04 $7700.00 Window Closed / Lapsed

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