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US4684475A Expired / Lapsed US ⏱️ 0.0 years remaining

Organophosphate and silicate containing antifreeze

Assignee: Prestone Products Corp USA
•
Filing: 1984-07-23
•
Granted: 1987-08-04
•
Expires: 2004-07-23
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Abstract

Abstract Antifreeze composition and composition concentrate containing at least one organophosphate and at least one silicate in buffer/alcohol, together with method of making and using the composition and composition concentrate.

Inventors

  • 👤 William N. Matulewicz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 13:01
CPC Classifications
C; C09; C09K; C09K5/00; C09K5/20

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 177 words
An antifreeze composition concentrate comprising: (a) alcohol, (b) at least one buffer selected from the group consisting of salts of boric, phosphoric benzoic, substituted benzoic, dibasic acids having 6 to 20 carbon atoms, and mixtures thereof, (c) at least one alkylene oxide-containing organophosphate, in a corrosion inhibiting-effective amount, wherein said organophosphate has a molecular weight below about 10,000 and is selected from the group defined by the following structural formulae I, II and III: ##STR4## wherein R'=[RO(PO) x (EO) y ] wherein R=H or alkyl, aryl, alkylaryl, arylalkyl, alkenyl or alkynyl having up to 24 carbon atoms, PO=Propylene oxide radical, EO=Ethylene oxide radical, x=1 to 100, y=0 to 100, k=1 to 3, with the proviso that when k=3, at least one R' group is removed from the phosphate ester by hydrolysis prior to or during use, n=1 to 100, w=0 to 100, with the proviso that when w≧1, x can be zero, z=0 to 100 m=1 to 10, and (d) at least one silicate selected from the group consisting of organic and inorganic silicates, and mixtures thereof.
Claim 2
Dependent Claim 177 words
An antifreeze composition concentrate comprising: (a) alcohol, (b) at least one buffer selected from the group consisting of salts of boric, phosphoric benzoic, substituted benzoic, dibasic acids having 6 to 20 carbon atoms, and mixtures thereof, (c) at least one alkylene oxide-containing organophosphate, in a corrosion inhibiting-effective amount, wherein said organophosphate has a molecular weight below about 10,000 and is selected from the group defined by the following structural formulae I, II and III: ##STR4## wherein R'=[RO(PO) x (EO) y ] wherein R=H or alkyl, aryl, alkylaryl, arylalkyl, alkenyl or alkynyl having up to 24 carbon atoms, PO=Propylene oxide radical, EO=Ethylene oxide radical, x=1 to 100, y=0 to 100, k=1 to 3, with the proviso that when k=3, at least one R' group is removed from the phosphate ester by hydrolysis prior to or during use, n=1 to 100, w=0 to 100, with the proviso that when w≧1, x can be zero, z=0 to 100 m=1 to 10, and (d) at least one silicate selected from the group consisting of organic and inorganic silicates, and mixtures thereof.
Claim 3
Dependent Claim 15 words
The concentrate of claim 1 having a pH of between about 5.5 and about 11.
Claim 4
Dependent Claim 24 words
The concentrate of claim 1 wherein said silicate is selected from the group consisting of potassium silicate, sodium silicate, tetraethylorthosilicate, tetramethylorthosilicate, and mixtures thereof.
Claim 5
Dependent Claim 30 words
The concentrate of claim 1 wherein component (c) is present in an amount of between about 0.001 and about 30 weight percent based on the total weight of the concentrate.
Claim 6
Dependent Claim 30 words
The concentrate of claim 1 wherein component (c) is present in an amount of between about 0.005 and about 1 weight percent based on the total weight of the concentrate.
Claim 7
Dependent Claim 30 words
The concentrate of claim 1 wherein component (c) is present in an amount of between about 0.005 and about 0.1 weight percent based on the total weight of the concentrate.
Claim 8
Dependent Claim 30 words
The concentrate of claim 1 wherein component (b) is present in an amount of between about 0.1 and about 10 weight percent based on the total weight of the concentrate.
Claim 9
Dependent Claim 30 words
The concentrate of claim 1 wherein component (b) is present in an amount of between about 0.1 and about 5 weight percent based on the total weight of the concentrate.
Claim 10
Dependent Claim 22 words
The concentrate of claim 1 wherein component (d) is present in an amount not exceeding 1000 ppm as Si in the concentrate.
Claim 11
Dependent Claim 22 words
The concentrate of claim 1 wherein component (d) is present in an amount not exceeding 750 ppm as Si in the concentrate.
Claim 12
Dependent Claim 26 words
The concentrate of claim 1 wherein said alcohol is selected from the group consisting of ethylene glycol, diethylene glycol, propylene glycol, dipropylene glycol and mixtures thereof.
Claim 13
Dependent Claim 49 words
A method of cooling an automobile engine which comprises without regard to sequence, the steps of: (a) diluting the concentrate of claim 1 with water or a mixture of water and alcohol to produce a working antifreeze, and (b) adding the working antifreeze to an automobile engine coolant system.
Claim 14
Dependent Claim 16 words
An antifreeze composition comprising the concentrate of claim 1 and additionally containing water or aqueous alcohol.

References Cited (Backward Citations)

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US3510436A Cited
EP0002530A1 Cited
DE2756747A1 Cited
US4210548A Cited
US4360474A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-08-03 1991-02-02 1991-08-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-08-03 1995-02-02 1995-08-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-08-03 1999-02-02 1999-08-04 $7700.00 Window Closed / Lapsed

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