US4684475A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Organophosphate and silicate containing antifreeze
Assignee: Prestone Products Corp USA
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Filing: 1984-07-23
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Granted: 1987-08-04
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Expires: 2004-07-23
Abstract
Abstract Antifreeze composition and composition concentrate containing at least one organophosphate and at least one silicate in buffer/alcohol, together with method of making and using the composition and composition concentrate.
Inventors
- 👤 William N. Matulewicz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 13:01
CPC Classifications
C; C09; C09K; C09K5/00; C09K5/20
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
177 words
An antifreeze composition concentrate comprising: (a) alcohol, (b) at least one buffer selected from the group consisting of salts of boric, phosphoric benzoic, substituted benzoic, dibasic acids having 6 to 20 carbon atoms, and mixtures thereof, (c) at least one alkylene oxide-containing organophosphate, in a corrosion inhibiting-effective amount, wherein said organophosphate has a molecular weight below about 10,000 and is selected from the group defined by the following structural formulae I, II and III: ##STR4## wherein R'=[RO(PO) x (EO) y ] wherein R=H or alkyl, aryl, alkylaryl, arylalkyl, alkenyl or alkynyl having up to 24 carbon atoms, PO=Propylene oxide radical, EO=Ethylene oxide radical, x=1 to 100, y=0 to 100, k=1 to 3, with the proviso that when k=3, at least one R' group is removed from the phosphate ester by hydrolysis prior to or during use, n=1 to 100, w=0 to 100, with the proviso that when w≧1, x can be zero, z=0 to 100 m=1 to 10, and (d) at least one silicate selected from the group consisting of organic and inorganic silicates, and mixtures thereof.
Claim 2
Dependent Claim
177 words
An antifreeze composition concentrate comprising: (a) alcohol, (b) at least one buffer selected from the group consisting of salts of boric, phosphoric benzoic, substituted benzoic, dibasic acids having 6 to 20 carbon atoms, and mixtures thereof, (c) at least one alkylene oxide-containing organophosphate, in a corrosion inhibiting-effective amount, wherein said organophosphate has a molecular weight below about 10,000 and is selected from the group defined by the following structural formulae I, II and III: ##STR4## wherein R'=[RO(PO) x (EO) y ] wherein R=H or alkyl, aryl, alkylaryl, arylalkyl, alkenyl or alkynyl having up to 24 carbon atoms, PO=Propylene oxide radical, EO=Ethylene oxide radical, x=1 to 100, y=0 to 100, k=1 to 3, with the proviso that when k=3, at least one R' group is removed from the phosphate ester by hydrolysis prior to or during use, n=1 to 100, w=0 to 100, with the proviso that when w≧1, x can be zero, z=0 to 100 m=1 to 10, and (d) at least one silicate selected from the group consisting of organic and inorganic silicates, and mixtures thereof.
Claim 3
Dependent Claim
15 words
The concentrate of claim 1 having a pH of between about 5.5 and about 11.
Claim 4
Dependent Claim
24 words
The concentrate of claim 1 wherein said silicate is selected from the group consisting of potassium silicate, sodium silicate, tetraethylorthosilicate, tetramethylorthosilicate, and mixtures thereof.
Claim 5
Dependent Claim
30 words
The concentrate of claim 1 wherein component (c) is present in an amount of between about 0.001 and about 30 weight percent based on the total weight of the concentrate.
Claim 6
Dependent Claim
30 words
The concentrate of claim 1 wherein component (c) is present in an amount of between about 0.005 and about 1 weight percent based on the total weight of the concentrate.
Claim 7
Dependent Claim
30 words
The concentrate of claim 1 wherein component (c) is present in an amount of between about 0.005 and about 0.1 weight percent based on the total weight of the concentrate.
Claim 8
Dependent Claim
30 words
The concentrate of claim 1 wherein component (b) is present in an amount of between about 0.1 and about 10 weight percent based on the total weight of the concentrate.
Claim 9
Dependent Claim
30 words
The concentrate of claim 1 wherein component (b) is present in an amount of between about 0.1 and about 5 weight percent based on the total weight of the concentrate.
Claim 10
Dependent Claim
22 words
The concentrate of claim 1 wherein component (d) is present in an amount not exceeding 1000 ppm as Si in the concentrate.
Claim 11
Dependent Claim
22 words
The concentrate of claim 1 wherein component (d) is present in an amount not exceeding 750 ppm as Si in the concentrate.
Claim 12
Dependent Claim
26 words
The concentrate of claim 1 wherein said alcohol is selected from the group consisting of ethylene glycol, diethylene glycol, propylene glycol, dipropylene glycol and mixtures thereof.
Claim 13
Dependent Claim
49 words
A method of cooling an automobile engine which comprises without regard to sequence, the steps of: (a) diluting the concentrate of claim 1 with water or a mixture of water and alcohol to produce a working antifreeze, and (b) adding the working antifreeze to an automobile engine coolant system.
Claim 14
Dependent Claim
16 words
An antifreeze composition comprising the concentrate of claim 1 and additionally containing water or aqueous alcohol.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-08-03 | 1991-02-02 | 1991-08-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-08-03 | 1995-02-02 | 1995-08-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-08-03 | 1999-02-02 | 1999-08-04 | $7700.00 | Window Closed / Lapsed |