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US4683248A Expired / Lapsed US ⏱️ 0.0 years remaining

Crosslinking of styrene polymers

Assignee: Luperox GmbH
•
Filing: 1985-10-02
•
Granted: 1987-07-28
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Expires: 2005-10-02
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Abstract

Abstract Optionally nucleo-substituted styrene polymers are crosslinked at temperatures above 110° C. with combinations of crosslinkage promoters containing at least two polymerizable C--C double or C--C triple bonds in the molecule, and organic peroxides (with the exception of hydroperoxides, peracids, and ketone peroxides) having a 10 hour halflife temperature below 106° C.

Inventors

  • 👤 Kurt Rauer
  • 👤 Angelika Orner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 06:58
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/04; C08J9/06; C08J9/10; C08J9/102; C08F; C08F257/00; C08F257/02; C08J2325/00

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 123 words
A process of crosslinking and foaming a homopolymer or copolymer selected from the group of polystyrenes, nucleo-substituted polystyrenes, impact-resistant polystyrenes, or mixtures thereof with the exception of p-methylstyrene homopolymers containing a chemically decomposing blowing agent free of amino or hydrazine groups comprising heating said homo- or copolymer at a temperature above 110° C. in the presence of 0.5 to 15% of at least one crosslinking promoter containing at least two active C--C double or C--C triple bonds in the molecule, 0.5 to 15% of at least one organic peroxide having a 10 hour halflife temperature below 106° C. (as determined in benzene) selected from the group of peresters, percarbonate esters, perketals, ether peroxides, diacyl peroxides, and ketone peroxide esters, and optionally foaming agents.
Claim 2
Dependent Claim 123 words
A process of crosslinking and foaming a homopolymer or copolymer selected from the group of polystyrenes, nucleo-substituted polystyrenes, impact-resistant polystyrenes, or mixtures thereof with the exception of p-methylstyrene homopolymers containing a chemically decomposing blowing agent free of amino or hydrazine groups comprising heating said homo- or copolymer at a temperature above 110° C. in the presence of 0.5 to 15% of at least one crosslinking promoter containing at least two active C--C double or C--C triple bonds in the molecule, 0.5 to 15% of at least one organic peroxide having a 10 hour halflife temperature below 106° C. (as determined in benzene) selected from the group of peresters, percarbonate esters, perketals, ether peroxides, diacyl peroxides, and ketone peroxide esters, and optionally foaming agents.
Claim 3
Dependent Claim 14 words
Process according to claim 1, characterized by the use of aromatic peresters as peroxides.
Claim 4
Dependent Claim 15 words
Process according to claim 1, characterized by the use of aromatic diacyl peroxides as peroxides.
Claim 5
Dependent Claim 14 words
Process according to claim 1, characterized by the use of percarbonate esters as peroxides.

References Cited (Backward Citations)

US3058928A Cited
FR1259094A Cited
US3432447A Cited
US3743611A Cited
US3965054A Cited
US4272583A Cited
US4433029A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-07-27 1991-01-26 1991-07-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-07-27 1995-01-26 1995-07-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-07-27 1999-01-26 1999-07-28 $7700.00 Window Closed / Lapsed

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