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US4682194A Expired / Lapsed US ⏱️ 0.0 years remaining

Heat-sensitive recording material

Assignee: Fujifilm Holdings Corp
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Filing: 1986-11-17
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Granted: 1987-07-21
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Expires: 2006-11-17
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Abstract

Abstract A heat-sensitive recording material is described, comprising a support comprising thereon a layer containing microcapsules containing a leuco dye and an organic solvent in a core thereof and a color developer outside of said microcapsules capable of reacting with said leuco dye to develop a color, wherein a glass transition point of said microcapsule wall is from about 60° C. to 200° C.

Inventors

  • 👤 Toshimasa Usami
  • 👤 Toshiharu Tanaka
  • 👤 Shohei Yoshida

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 14:21
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/26; B41M5/30; B41M2205/00; B41M2205/04; B41M5/124; B41M5/165; B41M5/28; B41M5/287; B41M5/323; B41M5/333; B41M5/3333; B41M5/3335; B41M5/337; B41M5/3375; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2982; Y10T428/2984; Y10T428/2985; Y10T428/2987

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 65 words
A heat-sensitive recording material comprising a support and a recording layer comprising microcapsules containing a leuco dye and an organic solvent in a core thereof and a color developer outside of said microcapsules capable of reacting with said leuco dye to produce a color, said microcapsules having walls being of a polymer having a glass transition point of from about 60° C. to 200° C.
Claim 2
Dependent Claim 65 words
A heat-sensitive recording material comprising a support and a recording layer comprising microcapsules containing a leuco dye and an organic solvent in a core thereof and a color developer outside of said microcapsules capable of reacting with said leuco dye to produce a color, said microcapsules having walls being of a polymer having a glass transition point of from about 60° C. to 200° C.
Claim 3
Dependent Claim 21 words
A heat-sensitive recording material as in claim 1, wherein said glass transition point is from about 70° C. to 150° C.
Claim 4
Dependent Claim 18 words
A heat-sensitive recording material as in claim 1, wherein said microcapsule further contains a glass transition point modifier.
Claim 5
Dependent Claim 27 words
A heat-sensitive recording material as in claim 3, wherein a glass transition modifier is a carbamic acid ester, an aromatic methoxy compound or an organic sulfonamide compound.
Claim 6
Dependent Claim 18 words
A heat-sensitive recording material as in claim 3, wherein said glass transition point modifier is a phenol compound.
Claim 7
Dependent Claim 16 words
A heat-sensitive recording material as in claim 5, wherein said glass transition point modifier is p-benzyloxyphenol.
Claim 8
Dependent Claim 23 words
A heat-sensitive recording material as in claim 6, wherein said microcapsule wall being of a polymer is polyurethane, polyurea or a mixuture thereof.
Claim 9
Dependent Claim 28 words
A heat-sensitive recording material as in claim 1, wherein said leuco dye has a partial skeletal structure, which undergoes cleavage or fission on contact with a color developer.
Claim 10
Dependent Claim 31 words
A heat-sensitive recording material as in claim 8, wherein said leuco dye has a partial skeletal structure of a lactone, a lactam, a sultone, a spiropyran, an ester or an amide.
Claim 11
Dependent Claim 28 words
A heat-sensitive recording material as in claim 1, wherein said color developer is a phenol compound, an organic acid or metal salts thereof, or a hydroxybenzoic acid ester.
Claim 12
Dependent Claim 25 words
A heat-sensitive recording material as in claim 10, wherein said phenol compound and an organic acid is melt at about 50° C. to 250° C.
Claim 13
Dependent Claim 22 words
A heat-sensitive recording material as in claim 1, wherein said organic solvent has a boiling point of at least about 180° C.
Claim 14
Dependent Claim 26 words
A heat-sensitive recording material as in claim 1, wherein said recording layer has a non-volatile matter content of from about 2.5 to 25 g/m 2 .
Claim 15
Dependent Claim 27 words
A heat-sensitive recording material as in claim 1, wherein said microcapsule wall being of a polymer is polyurethane, polyurea, polyamide, polyester, ureaformaldehyde resin or a mixture thereof.
Claim 16
Dependent Claim 23 words
A heat-sensitive recording material as in claim 1, wherein said microcapsule wall being of a polymer is polyurethane, polyurea or a mixture thereof.

References Cited (Backward Citations)

JPS5845090A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-07-20 1991-01-19 1991-07-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-07-20 1995-01-19 1995-07-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-07-20 1999-01-19 1999-07-21 $7700.00 Window Closed / Lapsed

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