US4676964A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for purifying silica
Assignee: JFE Mineral Co Ltd
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Filing: 1986-04-30
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Granted: 1987-06-30
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Expires: 2006-04-30
Abstract
Abstract This invention concerns a process for purifying silica produced from an alkali silicate aqueous solution, which usually contains more than 200 ppm of impurities, to silica containing less than 30 ppm of impurities. Concretely, the purification process of silica comprises: dispersing silica gel, containing a lot of impurities, in water and filtering the solution; dispersing the filtered out silica gel again in an aqueous solution of pH 2 or less and filtering the aqueous solution; putting the silica gel to heat-treatment and acid-treatment with continuous stirring in order to break the inside siloxane link and dissolve out impurities therefrom and filtering the acid solution; rinsing a produced cake with pure water to wash away the inside residual solution and drying the cake.
Inventors
- 👤 Akira Seki
- 👤 Yuuki Narita
- 👤 Yoshio Aso
- 👤 Shunro Nagata
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 19:27
CPC Classifications
C; C01; C01B; C01B33/00; C01B33/113; C01B33/12; C01B33/14; C01B33/157; C01B33/158
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
169 words
A process for producing high purity silica from silica gel obtained from an aqueous solution of alkali silicate, said starting silica gel including at least 200 ppm of metallic impurities, said process comprises (a) dispersing the silica gel in water; (b) filtering the resulting dispersion from step (a); (c) redispersing the silica gel filtered out in step (b) in an aqueous solution at a pH of 2 or less; (d) filtering the resulting dispersion from step (c); (e) heat-treating and acid-treating the silica gel filtered out in step (d) with stirring whereby siloxane links inside the silica gel are broken and metallic impurities in the silica gel are dissolved in the acid treating medium; (f) filtering the heat-treated and acid-treated silica gel from step (e) to filter out said dissolved impurities and form a cake; (g) rinsing said cake with pure water to remove residual acid treating medium; and (h) drying the rinsed cake; whereby silica gel containing less than about 30 ppm of said metallic impurities is obtained.
Claim 2
Dependent Claim
169 words
A process for producing high purity silica from silica gel obtained from an aqueous solution of alkali silicate, said starting silica gel including at least 200 ppm of metallic impurities, said process comprises (a) dispersing the silica gel in water; (b) filtering the resulting dispersion from step (a); (c) redispersing the silica gel filtered out in step (b) in an aqueous solution at a pH of 2 or less; (d) filtering the resulting dispersion from step (c); (e) heat-treating and acid-treating the silica gel filtered out in step (d) with stirring whereby siloxane links inside the silica gel are broken and metallic impurities in the silica gel are dissolved in the acid treating medium; (f) filtering the heat-treated and acid-treated silica gel from step (e) to filter out said dissolved impurities and form a cake; (g) rinsing said cake with pure water to remove residual acid treating medium; and (h) drying the rinsed cake; whereby silica gel containing less than about 30 ppm of said metallic impurities is obtained.
Claim 3
Dependent Claim
24 words
The process of claim 1 wherein in step (c) silica gel is dispersed in an aqueous medium at a pH not higher than 1.2.
Claim 4
Dependent Claim
20 words
The process of claim 1 wherein the heat-treatment in step (e) is at a temperature up to about 1100° C.
Claim 5
Dependent Claim
16 words
The process of claim 3 wherein the acid treatment in step (e) is with mineral acid.
Claim 6
Dependent Claim
40 words
The process of claim 1 wherein the starting aqueous solution of alkali silicate is prepared by adding an alkali metal salt to silicon dioxide having a purity of not less than 99%, heating the resulting mixture and adding water thereto.
Claim 7
Dependent Claim
32 words
The process of claim 5 wherein the silicon dioxide is produced by refining a lower grade silicon dioxide having a purity of about 80% by the steps of rinsing, flotation and acid-treatment.
Claim 8
Dependent Claim
115 words
A process for producing silica gel containing less than about 30 ppm of metallic impurities from silica gel containing more than about 200 ppm of metallic impurities which comprises forming an acid gel slurry of silica by stirring wet silica gel obtained from water glass and containing more than about 200 ppm of impurities in water at a pH of no more than 2, rinsing the acid gel slurry with water to remove some of said impurities; drying the rinsed gel; and dissolving and rinsing the dried gel in an acidic medium at an elevated temperature to remove additional impurities to thereby obtain silica gel containing no more than about 30 ppm of metallic impurities.
Claim 9
Dependent Claim
115 words
A process for producing silica gel containing less than about 30 ppm of metallic impurities from silica gel containing more than about 200 ppm of metallic impurities which comprises forming an acid gel slurry of silica by stirring wet silica gel obtained from water glass and containing more than about 200 ppm of impurities in water at a pH of no more than 2, rinsing the acid gel slurry with water to remove some of said impurities; drying the rinsed gel; and dissolving and rinsing the dried gel in an acidic medium at an elevated temperature to remove additional impurities to thereby obtain silica gel containing no more than about 30 ppm of metallic impurities.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1990-06-29 | 1990-12-29 | 1991-06-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-06-29 | 1994-12-29 | 1995-06-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-06-29 | 1998-12-29 | 1999-06-30 | $7700.00 | Window Closed / Lapsed |