US4676953A
Expired / Lapsed
US
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Continous production of sodium silicate solutions
Assignee: Henkel AG and Co KGaA
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Filing: 1985-06-24
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Granted: 1987-06-30
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Expires: 2005-06-24
Abstract
Abstract An apparatus for the continuous production of clear sodium silicate solution with an SiO 2 :Na 2 O weight ratio of 1-2.8:1 by fusing sand in aqueous sodium hydroxide using a pressure-sealed circulating suspension reactor having an upper portion comprising a partially tapered gravity thickener and a lower portion comprising a cylindrical jet loop mixer. The jet loop mixer has a concentric cylindrical insertion tube suspended therein, and a recirculating power jet nozzle is upwardly directed through the bottom of the jet loop mixer so that its stream is directed into the lower end of the insertion tube, causing a continuous circulation flow.
Inventors
- 👤 Lutz Jeromin
- 👤 Heinrich Krings
- 👤 Dieter Legel
- 👤 Rudolf Novotny
- 👤 Harald Skrobek
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 08:29
CPC Classifications
B; B01; B01J; B01J8/00; B01J8/18; B01J8/20; C; C01; C01B; C01B33/00; C01B33/20; C01B33/32
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
285 words
An apparatus for the continuous production of clear sodium silicate solution with an SiO 2 :Na 2 O weight ratio of about 1-2.8:1 by fusing sand in aqueous sodium hydroxide solution at a temperature of about 150°-250° C. and a pressure of about 5-40 bar, comprising: (a) a vertical pressure-sealed circulating suspension reactor having an upper portion comprising a gravity thickener which is partially tapered at its bottom connecting end, connected to a top of a lower portion comprising a cylindrical jet loop mixer having a bottom end, said lower portion having a cylindrical insertion tube open at its top and bottom ends suspended concentrically therein; (b) continuous circulation flow generation means comprising at least one first power jet nozzle, which nozzle is positioned below said jet loop mixer at a point capable of directing a stream upward through the bottom end of said jet loop mixer and through said insertion tube; (c) means for introducing a sand suspension directly into an upper half of said jet loop mixer; (d) means for introducing an aqueous sodium hydroxide solution into a lower third of said jet loop mixer; (e) means for introducing deionized water into a lower third of said jet loop mixer; (f) means for introducing steam directly into an upper half of said jet loop mixer; (g) means for removing a partial reaction product from a middle section of said gravity thickener and recirculating said partial reaction product back into said reactor through said at least one first jet nozzle; and (h) means for removing a completed reaction product comprising clear sodium silicate solution having an SiO 2 :Na 2 O weight ratio of about 1-2.8:1, from an upper section of said gravity thickener.
Claim 2
Independent Claim
285 words
An apparatus for the continuous production of clear sodium silicate solution with an SiO 2 :Na 2 O weight ratio of about 1-2.8:1 by fusing sand in aqueous sodium hydroxide solution at a temperature of about 150°-250° C. and a pressure of about 5-40 bar, comprising: (a) a vertical pressure-sealed circulating suspension reactor having an upper portion comprising a gravity thickener which is partially tapered at its bottom connecting end, connected to a top of a lower portion comprising a cylindrical jet loop mixer having a bottom end, said lower portion having a cylindrical insertion tube open at its top and bottom ends suspended concentrically therein; (b) continuous circulation flow generation means comprising at least one first power jet nozzle, which nozzle is positioned below said jet loop mixer at a point capable of directing a stream upward through the bottom end of said jet loop mixer and through said insertion tube; (c) means for introducing a sand suspension directly into an upper half of said jet loop mixer; (d) means for introducing an aqueous sodium hydroxide solution into a lower third of said jet loop mixer; (e) means for introducing deionized water into a lower third of said jet loop mixer; (f) means for introducing steam directly into an upper half of said jet loop mixer; (g) means for removing a partial reaction product from a middle section of said gravity thickener and recirculating said partial reaction product back into said reactor through said at least one first jet nozzle; and (h) means for removing a completed reaction product comprising clear sodium silicate solution having an SiO 2 :Na 2 O weight ratio of about 1-2.8:1, from an upper section of said gravity thickener.
Claim 3
Dependent Claim
55 words
The apparatus of claim 1 wherein said means for introducing a sand suspension comprises: a suspending unit having stirring means, a sand introduction inlet, a suspending liquid introduction inlet and a sand suspension outlet; and a sand suspension conduit with a sand suspension pump operatively connected thereto connecting said outlet to said jet loop mixer.
Claim 4
Dependent Claim
53 words
The apparatus of claim 1 wherein said means for introducing steam comprises: a steam conduit, a steam regulator valve through which said steam conduit passes, a temperature sensor located within a middle section of said gravity thickner, and a temperature regulator operatively connected to both said temperature sensor and said steam regulator valve.
Claim 5
Dependent Claim
36 words
The apparatus of claim 1 wherein said means for introducing steam comprises: a steam conduit, a manometer located within an upper section of said gravity thickener, and a pressure release valve operatively connected to said manometer.
Claim 6
Dependent Claim
43 words
The apparatus of claim 1 wherein said means for introducing an aqueous sodium hydroxide solution comprises a sodium hydroxide conduit whose outlet is directly connected to a side of said jet loop mixer, and which has a sodium hydroxide pump operatively connected therewith.
Claim 7
Dependent Claim
40 words
The apparatus of claim 1 wherein said means for introducing deionized water comprises a deionized water conduit whose outlet is directly connected to a side of said jet loop mixer, and which has a deionized water pump operatively connected therewith.
Claim 8
Dependent Claim
56 words
The apparatus of claim 1 wherein said means for removing a completed reaction product comprises cooling means, an outlet pipe leading from said gravity thickener through said cooling means, means for conveying heat removed by said cooling means to at least one starting component, and means for filtering entrained solids, located downstream of said cooling means.
Claim 9
Dependent Claim
48 words
The apparatus of claim 7 wherein said means for removing a partial reaction product comprises a recirculation conduit whose inlet is connected to said gravity thickener below said outlet pipe, whose outlet is said at least one first nozzle, and which has a recirculation pump operatively connnected therewith.
Claim 10
Dependent Claim
43 words
The apparatus of claim 8 wherein said means for introducing an aqueous sodium hydroxide solution comprises a sodium hydroxide conduit whose outlet is connected to said recirculation conduit downstream of said recirculation pump, and which has a sodium hydroxide pump operatively connected therewith.
Claim 11
Dependent Claim
34 words
The apparatus of claim 7 wherein means for maintaining a constant reaction mass within said reactor are located within said gravity thickener, and comprise a lever governor operatively connected to said means for removing.
Claim 12
Dependent Claim
40 words
The apparatus of claim 8 wherein said means for introducing deionized water comprises a deionized water conduit whose outlet is connected to said recirculation conduit downstream of said recirculation pump, and which has a deionized water pump operatively connected therewith.
Claim 13
Dependent Claim
57 words
The apparatus of claim 1 further comprising at least one second power jet nozzle, which nozzle is positioned below said jet loop mixer at a point where its flow is directed tangentially through a lower side of said jet loop mixer parallel to its bottom end, to form a circular flow pattern within said jet loop mixer.
Claim 14
Dependent Claim
181 words
The apparatus of claim 12 wherein: (a) said means for introducing a sand suspension comprises: a suspending unit having stirring means, a sand introduction inlet, a suspending liquid introduction inlet and a sand suspension outlet; and a sand suspension conduit with a sand suspension pump operatively connected therewith joining said suspending unit to said jet loop mixer; (b) said means for removing a completed reaction product comprises cooling means, an outlet pipe leading from said gravity thickener through said cooling means, means for conveying heat removed by said cooling means to at least one starting component, and means for filtering entrained solids, located downstream of said cooling means; (c) means for maintaining a constant reaction mass within said reactor are located within said gravity thickener, and comprise a level governor operatively connected to said means for removing; and (d) said means for removing a partial reaction product comprises a recirculation conduit whose inlet is connected to said gravity thickener below said outlet pipe, whose outlet is said at least one first nozzle, and which has a recirculation pump operatively associated therewith.
Claim 15
Dependent Claim
43 words
The apparatus of claim 13 wherein said means for introducing an aqueous sodium hydroxide solution comprises a sodium hydroxide conduit whose outlet is directly connected to a side of said jet loop mixer, and which has a sodium hydroxide pump operatively associated therewith.
Claim 16
Dependent Claim
40 words
The apparatus of claim 14 wherein said means for introducing deionized water comprises a deionized water conduit whose outlet is directly connected to a side of said jet loop mixer, and which has a deionized water pump operatively connected therewith.
Claim 17
Dependent Claim
53 words
The apparatus of claim 15 wherein said means for introducing steam comprises: a steam conduit, a steam regulatory valve through which said steam conduit passes, a temperature sensor located within a middle section of said gravity thickener, and a temperature regulator operatively connected to both said temperature sensor and said steam regulatory valve.
Claim 18
Dependent Claim
36 words
The apparatus of claim 15 wherein said means for introducing steam comprises: a steam conduit, a manometer located within an upper section of said gravity thickener, and a pressure release valve operatively connected to said manometer.
Claim 19
Dependent Claim
43 words
The apparatus of claim 13 wherein said means for introducing an aqueous sodium hydroxide solution comprises a sodium hydroxide conduit whose outlet is connected to said recirculation conduit downstream of said recirculation pump; and which has a sodium hydroxide pump operatively connected therewith.
Claim 20
Dependent Claim
40 words
The apparatus of claim 18 wherein said means for introducing deionized water comprises a deionized water conduit whose outlet is connected to said recirculation conduit downstream of said recirculation pump, and which has a deionized water pump operatively connected therewith.
Claim 21
Dependent Claim
53 words
The apparatus of claim 19 wherein said means for introducing steam comprises: a steam conduit, a steam regulatory valve through which said steam conduit passes, a temperature sensor located within a middle section of said gravity thickener, and a temperature regulator operatively connected to both said temperature sensor and said steam regulatory valve.
Claim 22
Dependent Claim
36 words
The apparatus of claim 19 wherein said means for introducing steam comprises: a steam conduit, a manometer located within an upper section of said gravity thickener, and a pressure release valve operatively connected to said manometer.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-06-29 | 1990-12-29 | 1991-06-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-06-29 | 1994-12-29 | 1995-06-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-06-29 | 1998-12-29 | 1999-06-30 | $7700.00 | Window Closed / Lapsed |