Zirconium alloy fuel cladding resistant to PCI crack propagation

Claim 2

A nuclear fuel element cladding tube comprising: concentric tubular layers of zirconium base alloys; said concentric tubular layers including an inner layer and outer layer; said outer layer, metallurgically bonded to said inner layer; said outer layer composed of a first zirconium base alloy characterized by excellent resistance to corrosion caused by exposure to high temperature and pressure aqueous environments; said inner layer composed of a second zirconium base alloy consisting of: about 0.2 to 0.6 wt.% tin, about 0.03 to 0.11 wt.% iron, less than about 0.02 wt.% chromium, up to about 350 ppm oxygen and the remainder being zirconium and incidental impurities; and said inner layer characterized by improved resistance to crack propagation under reactor operating conditions compared to said first zirconium alloy.

Claim 3

The nuclear fuel element cladding tube according to claim 1 wherein said second zirconium base alloy contains about 0.4 to 0.6 wt.% tin.

Claim 4

The nuclear fuel element cladding tube according to claim 1 wherein said inner layer is characterized by a fully recrystallized microstructure.

Claim 5

The nuclear fuel element cladding tube according to claim 1 wherein said inner layer has a wall thickness of at least about 0.003 inches.

Claim 6

The nuclear fuel element cladding tube according to claim 1 wherein said first alloy is selected from the group consisting of Zircaloy-2, Zircaloy-4 and zirconium 1 to 3 wt.% niobium alloys.

Claim 7

The nuclear fuel element cladding tube according to claim 1 wherein the oxygen content of said second zirconium base alloy is limited to less than about 250 ppm.

Claim 8

The nuclear fuel element cladding tube according to claim 1 wherein said second zirconium base alloy contains about 0.03 to 0.06 wt.% iron.

Claim 9

The nuclear fuel element cladding tube according to claim 4 wherein said inner layer is further characterized by a fully recrystallized grain structure having a grain size between about 1/10 and 1/20 of said inner layer wall thickness.

Claim 10

The nuclear fuel element cladding tube in accordance with claim 1 produced by a process comprising the steps of: obtaining an intermediate size cladding tube; then surface beta treating said outer layer of said intermediate size cladding tube; then cold working said intermediate size cladding tube in one step to substantially final size; and then annealing the substantially final size cladding tube at a temperature below about 600° C. to produce a fine fully recrystallized grain size in said inner layer.

Claim 11

A water reactor nuclear fuel element comprising: an elongate cladding container; a nuclear fuel material sealed within said cladding container; said elongate cladding container having: an outer tubular layer; an inner tubular layer; said inner layer concentrically located between said nuclear fuel material and said outer layer; the outer circumferential surface of said inner layer bonded to the inner circumferential surface of said outer layer over essentially the entire outer circumferential surface of said inner layer; said outer layer composed of a first alloy selected from the group of zirconium alloys consisting of Zircaloy-2 and Zircaly-4 type alloys, and Zr--Nb alloys containing about 1 to 3 wt.% Nb; said inner layer composed of a second alloy consisting of: about 0.2 to 0.6 wt.% tin; about 0.03 to 0.11 wt.% of an element selected from the group consisting of chromium and iron with the sum of the chromium and iron contents being about 0.03 to 0.11 wt.%; the balance of said second alloy consisting essentially of zirconium and incidental impurities, and wherein the total amount of said incidental impurities is less than about 1500 ppm, of which oxygen comprises less than about 350 ppm; said inner layer having a recrystallized grain structure and a wall thickness of at least about 0.003 inch; substantially cylindrically shaped pellets comprising said nuclear fuel material; said pellets having an outside diameter smaller than the inside diameter of said inner layer forming a clearance space within said elongate composite cladding container; a pressurized inert gas filling said clearance space.

Claim 12

A water reactor nuclear fuel element comprising: an elongate cladding container; a nuclear fuel material sealed within said cladding container; said elongate cladding container having: an outer tubular layer; an inner tubular layer; said inner layer concentrically located between said nuclear fuel material and said outer layer; the outer circumferential surface of said inner layer bonded to the inner circumferential surface of said outer layer over essentially the entire outer circumferential surface of said inner layer; said outer layer composed of a first alloy selected from the group of zirconium alloys consisting of Zircaloy-2 and Zircaly-4 type alloys, and Zr--Nb alloys containing about 1 to 3 wt.% Nb; said inner layer composed of a second alloy consisting of: about 0.2 to 0.6 wt.% tin; about 0.03 to 0.11 wt.% of an element selected from the group consisting of chromium and iron with the sum of the chromium and iron contents being about 0.03 to 0.11 wt.%; the balance of said second alloy consisting essentially of zirconium and incidental impurities, and wherein the total amount of said incidental impurities is less than about 1500 ppm, of which oxygen comprises less than about 350 ppm; said inner layer having a recrystallized grain structure and a wall thickness of at least about 0.003 inch; substantially cylindrically shaped pellets comprising said nuclear fuel material; said pellets having an outside diameter smaller than the inside diameter of said inner layer forming a clearance space within said elongate composite cladding container; a pressurized inert gas filling said clearance space.

Claim 13

The fuel element according to claim 10 wherein said substantially cylindrically shaped pellets are stacked within said elongate cladding container forming a plenum space near one end of said elongate cladding container and wherein a spring means is located in said plenum exerting pressure on one end of said cylindrically shaped pellets; and said plenum also containing said pressurized inert gas.

Claim 14

The cladding tube according to claim 1 wherein said incidental impurities are limited to the following in weight percent: ______________________________________ Al ≦0.0075 B ≦0.00005 Cd ≦0.00005 C ≦0.027 Cr ≦0.020 Co ≦0.0020 Cu ≦0.0050 Hf ≦0.0100 H ≦0.0025 Mg ≦0.0020 Mn ≦0.0050 Mo ≦0.0050 N ≦0.0065 Si ≦0.0120 Ti ≦0.0050 W ≦0.010 U ≦0.00035. ______________________________________

Claim 15

The water reactor fuel element according to claim 10 wherein said incidental impurities are limited to the following in weight percent: ______________________________________ Al ≦0.0075 B ≦0.00005 Cd ≦0.00005 C ≦0.027 Co ≦0.0020 Cu ≦0.0050 Hf ≦0.0100 H ≦0.0025 Mg ≦0.0020 Mn ≦0.0050 Mo ≦0.0050 N ≦0.0065 Si ≦0.0120 Ti ≦0.0050 W ≦0.010 U ≦0.00035. ______________________________________

Claim 16

The cladding tube according to claim 1 wherein the total amount of said incidental impurities, including oxygen, is limited to less than 1500 ppm.

Claim 17

The cladding tube according to claim 1 wherein the first zirconium base alloy is Zircaloy-2.

Claim 18

The cladding tube according to claim 1 wherein said first zirconium base alloy is Zircaloy-4.