US4670481A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Organotin acrylate and organotin polysiloxane antifouling coating composition
Assignee: Ameron Inc
•
Filing: 1986-02-14
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Granted: 1987-06-02
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Expires: 2006-02-14
Abstract
Abstract The invention provides a marine antifouling coating composition comprising a tributyltin acrylate coresin in the range of from about 10% to about 25% by weight, a tributyltin polysiloxane coresin in the range of from about 2% to about 20% by weight, at least one filler in the range of from about 10% to about 50% by weight and a solvent in an amount of from about 20% to about 50% by weight. Preferred tributyltin acrylate coresins comprise copolymers of tributyltin methacrylate monomers and methyl methacrylate monomers.
Inventors
- 👤 Raymond E. Foscante
- 👤 Charles D. Stevens
- 👤 Lee M. Parson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 11:21
CPC Classifications
A; A01; A01N; A01N55/00; A01N55/02; A01N55/04; C; C09; C09D; C09D183/00; C09D183/02; C09D5/00; C09D5/16; C09D5/1606; C09D5/1637; C09D5/1643; C09D5/1656; C09D5/1662; C09D5/1675
Claims Analysis
Total Claims: 38
Claim 1
Independent Claim
284 words
A marine antifouling coating composition comprising: an organotin acrylate coresin comprising at least one polymeric precursor having the formula ##STR4## where R 1 , R 2 and R 3 are independently selected from the group consisting of alkyl, cycloalkyl and aryl radicals and R 1 , R 2 and R 3 collectively contain up to 18 carbon atoms and where R 4 is a polymerizable radical selected from the group consisting of vinyl, α-methylvinyl and vinylphenyl radicals, the organotin acrylate coresin being in the range of from about 10 to about 25% by weight; an organotin polysiloxane coresin comprising at least one polymeric precursor having the formula ##STR5## where m is an average of up to about ten, each X is independently selected from the group consisting of R 5 and Y; where each R 5 is selected from the group consisting of hydrogen and alkyl and alkoxyalkyl radicals containing less than six carbon atoms; where each Y is a trisubstituted tin radical having the formula ##STR6## where R 6 , R 7 and R 8 are independently selected from the group consisting of alkyl, cycloalkyl and aryl radicals and R 6 , R 7 and R 8 contain collectively up to 18 carbon atoms; the organotin polysiloxane coresin being in the range of from about 2 to about 20% by weight; solvent for the organotin acrylate and organotin polysiloxane coresin in the range of from about 20% to about 50% by weight; and the balance in the range of from about 10% to about 50% by weight comprising marine paint and toxicant agents selected from the group consisting of pigment powders, fillers, plasticizers, antisettling agents, copper powder, cuprous salts, zinc oxide and algicides.
Claim 2
Dependent Claim
284 words
A marine antifouling coating composition comprising: an organotin acrylate coresin comprising at least one polymeric precursor having the formula ##STR4## where R 1 , R 2 and R 3 are independently selected from the group consisting of alkyl, cycloalkyl and aryl radicals and R 1 , R 2 and R 3 collectively contain up to 18 carbon atoms and where R 4 is a polymerizable radical selected from the group consisting of vinyl, α-methylvinyl and vinylphenyl radicals, the organotin acrylate coresin being in the range of from about 10 to about 25% by weight; an organotin polysiloxane coresin comprising at least one polymeric precursor having the formula ##STR5## where m is an average of up to about ten, each X is independently selected from the group consisting of R 5 and Y; where each R 5 is selected from the group consisting of hydrogen and alkyl and alkoxyalkyl radicals containing less than six carbon atoms; where each Y is a trisubstituted tin radical having the formula ##STR6## where R 6 , R 7 and R 8 are independently selected from the group consisting of alkyl, cycloalkyl and aryl radicals and R 6 , R 7 and R 8 contain collectively up to 18 carbon atoms; the organotin polysiloxane coresin being in the range of from about 2 to about 20% by weight; solvent for the organotin acrylate and organotin polysiloxane coresin in the range of from about 20% to about 50% by weight; and the balance in the range of from about 10% to about 50% by weight comprising marine paint and toxicant agents selected from the group consisting of pigment powders, fillers, plasticizers, antisettling agents, copper powder, cuprous salts, zinc oxide and algicides.
Claim 3
Dependent Claim
22 words
A marine antifouling coating composition as claimed in claim 1 wherein R 1 , R 2 and R 3 are each butyl.
Claim 4
Dependent Claim
22 words
A marine antifouling coating composition as claimed in claim 1 wherein R 6 , R 7 and R 8 are each butyl.
Claim 5
Dependent Claim
24 words
A marine antifouling coating composition as claimed in claim 1 wherein R 5 is selected from the group consisting of hydrogen and ethyl radicals.
Claim 6
Dependent Claim
29 words
A marine antifouling coating composition as claimed in claim 1 wherein the organotin acrylate coresin is present in an amount of from about 17% to about 25% by weight.
Claim 7
Dependent Claim
28 words
A marine antifouling coating composition as claimed in claim 1 wherein the organotin polysiloxane is present in an amount of from about 5% to about 15% by weight.
Claim 8
Dependent Claim
32 words
A marine antifouling coating composition as claimed in claim 1 wherein the ratio of tin atoms to silicon atoms in the organotin polysiloxane polymeric precursor is from about 1.7:5 to about 5:5.
Claim 9
Dependent Claim
28 words
A marine antifouling coating composition as claimed in claim 7 wherein the ratio of tin atoms to silicon atoms in the organotin polysiloxane polymeric precursor is about 2.5:5.
Claim 10
Dependent Claim
27 words
A marine antifouling coating composition as claimed in claim 1 wherein the solvent is present in an amount of from about 25% to about 45% by weight.
Claim 11
Dependent Claim
37 words
A marine antifouling coating composition as claimed in claim 1 wherein the composition comprises a toxicant selected from the group consisting of copper salts and mixtures thereof in an amount of up to about 50% by weight.
Claim 12
Dependent Claim
26 words
A marine antifouling coating composition as claimed in claim 1 wherein the composition comprises a plasticizer in an amount of up to about 5% by weight.
Claim 13
Dependent Claim
25 words
A marine antifouling coating composition as claimed in claim 1 wherein the composition comprises zinc oxide in an amount up to about 15% by weight.
Claim 14
Dependent Claim
27 words
A marine antifouling coating composition as claimed in claim 1 wherein the composition comprises an antisettling agent in an amount of up to about 3% by weight.
Claim 15
Dependent Claim
26 words
A marine antifouling coating composition as claimed in claim 1 wherein the composition comprises an algicide in an amount of up to about 16% by weight.
Claim 16
Dependent Claim
38 words
A marine antifouling coating composition as claimed in claim 1 wherein the composition comprises a filler or pigment powder selected from the group consisting of iron oxide, talc, titanium dioxide, silicon dioxide, and chrome dioxide and mixtures thereof.
Claim 17
Dependent Claim
30 words
A marine antifouling coating composition as claimed in claim 1 wherein the filler or pigment powder is present in the range of from about 10% to about 50% by weight.
Claim 18
Dependent Claim
18 words
A marine antifouling coating composition as claimed in claim 1 wherein the organotin polysiloxane is hydrolizable in situ.
Claim 19
Dependent Claim
17 words
A marine antifouling coating composition as claimed in claim 1 wherein the organotin polysiloxane is partially prehydrolized.
Claim 20
Dependent Claim
25 words
A marine antifouling coating composition as claimed in claim 1 wherein the organotin acrylate coresin comprises copolymers of tributyltin methacrylate monomers and methyl methacrylate monomers.
Claim 21
Dependent Claim
210 words
A marine antifouling coating composition comprising: an organotin acrylate coresin comprising at least one polymeric precursor having the formula: ##STR7## where R 1 , R 2 and R 3 are each butyl and where R 4 is a polymerizable radical selected from the group consisting of vinyl, α-methylvinyl and vinylphenyl radicals, the organotin acrylate coresin being in the range of from about 10 to about 25% by weight; an organotin polysiloxane coresin comprising at least one polymeric precursor having the formula: ##STR8## where m is an average of up to about 10, each X is independently selected from the group consisting of hydrogen and ethyl radical, where each Y is a tributyltin radical and the X's are selected so that the ratio of tin atoms to silicon atoms is in the range from 1.7:5 to 5:5, the organotin polysiloxane being present in the range of from about 2 to about 20% by weight; a solvent for the organotin acrylate and organotin polysiloxane in an amount of from about 20% to about 50% by weight; and a filler or pigment powder selected from the group consisting of iron oxide, talc, silicon dioxide, titanium dioxide, chronium oxide and mixtures thereof in an amount of from about 10% to about 50% by weight.
Claim 22
Dependent Claim
210 words
A marine antifouling coating composition comprising: an organotin acrylate coresin comprising at least one polymeric precursor having the formula: ##STR7## where R 1 , R 2 and R 3 are each butyl and where R 4 is a polymerizable radical selected from the group consisting of vinyl, α-methylvinyl and vinylphenyl radicals, the organotin acrylate coresin being in the range of from about 10 to about 25% by weight; an organotin polysiloxane coresin comprising at least one polymeric precursor having the formula: ##STR8## where m is an average of up to about 10, each X is independently selected from the group consisting of hydrogen and ethyl radical, where each Y is a tributyltin radical and the X's are selected so that the ratio of tin atoms to silicon atoms is in the range from 1.7:5 to 5:5, the organotin polysiloxane being present in the range of from about 2 to about 20% by weight; a solvent for the organotin acrylate and organotin polysiloxane in an amount of from about 20% to about 50% by weight; and a filler or pigment powder selected from the group consisting of iron oxide, talc, silicon dioxide, titanium dioxide, chronium oxide and mixtures thereof in an amount of from about 10% to about 50% by weight.
Claim 23
Dependent Claim
25 words
A marine antifouling coating composition as claimed in claim 20 wherein the organotin acrylate coresin comprises copolymers of tributyltin methacrylate monomers and methyl methacrylate monomers.
Claim 24
Dependent Claim
29 words
A marine antifouling coating composition as claimed in claim 20 wherein the organotin acrylate coresin is present in an amount of from about 17% to about 25% by weight.
Claim 25
Dependent Claim
29 words
A marine antifouling coating composition as claimed in claim 20 wherein the organotin polysiloxane coresin is present in an amount of from about 5% to about 15% by weight.
Claim 26
Dependent Claim
28 words
A marine antifouling coating composition as claimed in claim 20 wherein the ratio of tin atoms to silicon atoms in the organotin polysiloxane polymeric precursor is about 2.5:5.
Claim 27
Dependent Claim
27 words
A marine antifouling coating composition as claimed in claim 20 wherein the solvent is present in an amount of from about 25% to about 45% by weight.
Claim 28
Dependent Claim
38 words
A marine antifouling coating composition as claimed in claim 20 wherein the composition further comprises a toxicant selected from the group consisting of copper salts and mixtures thereof in an amount of up to about 50% by weight.
Claim 29
Dependent Claim
27 words
A marine antifouling coating composition as claimed in claim 20 wherein the composition further comprises a plasticizer in an amount of up to about 5% by weight.
Claim 30
Dependent Claim
26 words
A marine antifouling coating composition as claimed in claim 20 wherein the composition further comprises zinc oxide in an amount up to about 15% by weight.
Claim 31
Dependent Claim
28 words
A marine antifouling coating composition as claimed in claim 20 wherein the composition further comprises an antisettling agent in an amount of up to about 3% by weight.
Claim 32
Dependent Claim
27 words
A marine antifouling coating composition as claimed in claim 20 wherein the composition further comprises an algicide in an amount of up to about 16% by weight.
Claim 33
Dependent Claim
31 words
A marine antifouling coating composition as claimed in claim 20 wherein the composition further comprises a viscosity stabilizing agent in the range of from about 6 to about 20% by weight.
Claim 34
Dependent Claim
18 words
A marine antifouling coating composition as claimed in claim 20 wherein the organotin polysiloxane is hydrolizable in situ.
Claim 35
Dependent Claim
17 words
A marine antifouling coating composition as claimed in claim 20 wherein the organotin polysiloxane is partially prehydrolized.
Claim 36
Dependent Claim
135 words
A marine antifouling coating composition comprising: an organotin acrylate coresin comprising copolymers of tributyltin methacrylate monomers and methyl methacrylate monomers in the range from about 10% to about 25% by weight; an organotin polysiloxane coresin comprising an organotin polysiloxane having a ratio of tin atoms to silicon atoms of from about 1.7:5 to about 5:5, said organotin polysiloxane coresin being present in the range of from about 2% to about 20% by weight; a solvent for the organotin acrylate and organotin polysiloxane in an amount of from about 20% to about 50% by weight; and the balance in the range of from about 10% to about 50% by weight comprising marine paint and toxicant agents selected from the group consisting of pigment powders, fillers, plasticizers, antisettling agents, copper powder, cuprous salts, zinc oxide and algicides.
Claim 37
Dependent Claim
135 words
A marine antifouling coating composition comprising: an organotin acrylate coresin comprising copolymers of tributyltin methacrylate monomers and methyl methacrylate monomers in the range from about 10% to about 25% by weight; an organotin polysiloxane coresin comprising an organotin polysiloxane having a ratio of tin atoms to silicon atoms of from about 1.7:5 to about 5:5, said organotin polysiloxane coresin being present in the range of from about 2% to about 20% by weight; a solvent for the organotin acrylate and organotin polysiloxane in an amount of from about 20% to about 50% by weight; and the balance in the range of from about 10% to about 50% by weight comprising marine paint and toxicant agents selected from the group consisting of pigment powders, fillers, plasticizers, antisettling agents, copper powder, cuprous salts, zinc oxide and algicides.
Claim 38
Dependent Claim
32 words
A marine antifouling coating composition as claimed in claim 34 wherein the ratio of tributyltin methacrylate monomers to methyl methacrylate monomers is in the range of from about 1:2 to about 1:2.5.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-06-01 | 1990-12-01 | 1991-06-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-06-01 | 1994-12-01 | 1995-06-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-06-01 | 1998-12-01 | 1999-06-02 | $7700.00 | Window Closed / Lapsed |