US4668430A
Expired / Lapsed
US
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Roll-on perfume compositions containing polyoxybutylene-polyoxyethylene copolymers
Assignee: BASF Corp
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Filing: 1985-04-02
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Granted: 1987-05-26
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Expires: 2005-04-02
Abstract
Abstract The subject invention relates to roll-on perfume compositions containing polyoxybutylene-polyoxyethylene block copolymers having an internal polyoxybutylene hydrophobe and external polyoxyethylene hydrophiles.
Inventors
- 👤 Irving R. Schmolka
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 07:26
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/72; A61K8/90; A61Q; A61Q13/00
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
178 words
In a liquid roll-on composition containing, in weight percent based upon the total composition weight, from 5 percent to 15 percent of a perfume oil, from 25 percent to 40 percent of a volatile alcohol, from 10 percent to 60 percent water, and from 10 percent to 30 percent of a nonionic polyether surfactant, the improvement comprising, employing as the nonionic polyether surfactant a cogeneric polyoxybutylene-polyoxyethylene block copolymer corresponding to the formula Y[(C.sub.4 H.sub.8 O).sub.n (C.sub.2 H.sub.4 O).sub.m H].sub.x where Y is an organic radical derived from an organic initiator molecule having x active hydrogens, and where the values of n and x are integers such that an internal polyoxybutylene hydrophobe, corresponding to that portion of the molecule represented by the formula Y[(C.sub.4 H.sub.8 O).sub.n ].sub.x has a molecular weight of at least 500, and wherein the value of m in the external polyoxyethylene hydrophiles corresponding to those portions of the molecule represented by the formula [(C.sub.2 H.sub.4 O).sub.m ].sub.x is such that the hydrophiles comprise from 50 percent to about 90 percent by weight of the polyether.
Claim 2
Dependent Claim
178 words
In a liquid roll-on composition containing, in weight percent based upon the total composition weight, from 5 percent to 15 percent of a perfume oil, from 25 percent to 40 percent of a volatile alcohol, from 10 percent to 60 percent water, and from 10 percent to 30 percent of a nonionic polyether surfactant, the improvement comprising, employing as the nonionic polyether surfactant a cogeneric polyoxybutylene-polyoxyethylene block copolymer corresponding to the formula Y[(C.sub.4 H.sub.8 O).sub.n (C.sub.2 H.sub.4 O).sub.m H].sub.x where Y is an organic radical derived from an organic initiator molecule having x active hydrogens, and where the values of n and x are integers such that an internal polyoxybutylene hydrophobe, corresponding to that portion of the molecule represented by the formula Y[(C.sub.4 H.sub.8 O).sub.n ].sub.x has a molecular weight of at least 500, and wherein the value of m in the external polyoxyethylene hydrophiles corresponding to those portions of the molecule represented by the formula [(C.sub.2 H.sub.4 O).sub.m ].sub.x is such that the hydrophiles comprise from 50 percent to about 90 percent by weight of the polyether.
Claim 3
Dependent Claim
25 words
The composition of claim 1 wherein said polyether contains polyoxyethylene hydrophiles which comprise from about 70 percent to 85 percent by weight of the polyether.
Claim 4
Dependent Claim
17 words
The composition of claim 1 wherein said internal polyoxybutylene hydrophobe has a molecular weight greater than 2000.
Claim 5
Dependent Claim
18 words
The composition of claim 1 wherein said polyoxybutylene hydrophobe has a molecular weight of from 3000 to 5000.
Claim 6
Dependent Claim
23 words
The composition of claim 1 wherein said volatile alcohol is selected from the group consisting of ethanol, propanol, isopropanol, t-butanol, sec-butanol, and n-butanol.
Claim 7
Dependent Claim
23 words
The composition of claim 2 wherein said volatile alcohol is selected from the group consisting of ethanol, propanol, isopropanol, t-butanol, sec-butanol, and n-butanol.
Claim 8
Dependent Claim
23 words
The composition of claim 3 wherein said volatile alcohol is selected from the group consisting of ethanol, propanol, isopropanol, t-butanol, sec-butanol, and n-butanol.
Claim 9
Dependent Claim
23 words
The composition of claim 4 wherein said volatile alcohol is selected from the group consisting of ethanol, propanol, isopropanol, t-butanol, sec-butanol, and n-butanol.
Claim 10
Dependent Claim
28 words
The composition of claim 1 wherein said organic initiator molecule is selected from the group consisting of ethylene glycol, propylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, and 1,4-butylene glycol.
Claim 11
Dependent Claim
28 words
The composition of claim 3 wherein said organic initiator molecule is selected from the group consisting of ethylene glycol, propylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, and 1,4-butylene glycol.
Claim 12
Dependent Claim
28 words
The composition of claim 5 wherein said organic initiator molecule is selected from the group consisting of ethylene glycol, propylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, and 1,4-butylene glycol.
Claim 13
Dependent Claim
13 words
The composition of claim 9 wherein said organic initiator molecule is 1,4-butylene glycol.
Claim 14
Dependent Claim
148 words
In a liquid roll-on composition containing, in weight percent based upon the total composition weight, from 5 percent to 15 percent of a perfume oil, from 25 percent to 40 percent of a volatile alcohol, from 10 percent to 60 percent water, and from 10 percent to 30 percent of a nonionic polyether surfactant, the improvement comprising, employing as the nonionic polyether surfactant a cogeneric polyoxybutylene-polyoxyethylene block copolymer corresponding to the formula HO(C.sub.2 H.sub.O).sub.m (C.sub.4 H.sub.8 O).sub.n (C.sub.2 H.sub.4 O).sub.m H wherein m is an integer such that the molecular weight of the polyoxybutylene hydrophobe which is that portion of the molecule represented by the formula (C.sub.4 H.sub.8 O).sub.n is greater than 500, and wherein m is an integer such that the polyoxyethylene hydrophiles which are those portions of the molecule represented by (C.sub.2 H.sub.4 O).sub.m comprise from 50 percent to 90 percent by weight of the polyether.
Claim 15
Dependent Claim
148 words
In a liquid roll-on composition containing, in weight percent based upon the total composition weight, from 5 percent to 15 percent of a perfume oil, from 25 percent to 40 percent of a volatile alcohol, from 10 percent to 60 percent water, and from 10 percent to 30 percent of a nonionic polyether surfactant, the improvement comprising, employing as the nonionic polyether surfactant a cogeneric polyoxybutylene-polyoxyethylene block copolymer corresponding to the formula HO(C.sub.2 H.sub.O).sub.m (C.sub.4 H.sub.8 O).sub.n (C.sub.2 H.sub.4 O).sub.m H wherein m is an integer such that the molecular weight of the polyoxybutylene hydrophobe which is that portion of the molecule represented by the formula (C.sub.4 H.sub.8 O).sub.n is greater than 500, and wherein m is an integer such that the polyoxyethylene hydrophiles which are those portions of the molecule represented by (C.sub.2 H.sub.4 O).sub.m comprise from 50 percent to 90 percent by weight of the polyether.
Claim 16
Dependent Claim
35 words
The composition of claim 13 wherein said polyoxybutylene hydrophobe is prepared by oxyalkylating an organic initiator molecule which is 1,4-butylene glycol with a cyclic ether selected from the group consisting of 1,2-butylene oxide and tetrahydrofuran.
Claim 17
Dependent Claim
17 words
The composition of claim 13 wherein said polyoxybutylene hydrophobe has a molecular weight of greater than 2400.
Claim 18
Dependent Claim
18 words
The composition of claim 13 wherein said polyoxybutylene hydrophobe has a molecular weight of from 3000 to 5000.
Claim 19
Dependent Claim
20 words
The composition of claim 16 wherein said oxyethylene hydrophiles comprise from 70 to 85 percent by weight of the polyether.
Claim 20
Dependent Claim
18 words
The composition of claim 16 wherein said oxyethylene hydrophiles comprise about 80 percent by weight of the polyether.
Claim 21
Dependent Claim
11 words
The composition of claim 18 wherein said volatile alcohol is ethanol.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1990-05-25 | 1990-11-24 | 1991-05-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-05-25 | 1994-11-24 | 1995-05-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-05-25 | 1998-11-24 | 1999-05-26 | $7700.00 | Window Closed / Lapsed |