Patent EP0569030A1 successfully refreshed from Google Patents.
US4666983A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Absorbent article
Assignee: Nippon Shokubai Co Ltd
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Filing: 1983-04-19
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Granted: 1987-05-19
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Expires: 2003-04-19
Abstract
Abstract An absorbent article obtained by mixing 100 parts by weight of an absorbent resin powder having a carboxyl group with 0.001 to 10 parts by weight of a crosslinking agent having at least two functional groups capable of reacting with the carboxyl group per molecule and reacting the absorbent resin powder with the crosslinking agent to crosslink the molecular chains existing at least in the vicinity of the surface of the absorbent resin powder.
Inventors
- 👤 Tsuneo Tsubakimoto
- 👤 Tadao Shimomura
- 👤 Yoshio Irie
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 13:08
CPC Classifications
C; C09; C09K; C09K3/00; C09K3/32; A; A61; A61L; A61L15/00; A61L15/16; A61L15/42; A61L15/60; B; B01; B01J; B01J20/00; B01J20/22; B01J20/26; C08; C08F; C08F8/00
Claims Analysis
Total Claims: 30
Claim 1
Independent Claim
132 words
An absorbent article obtained by mixing 100 parts by weight of a powder of an absorbent resin having a carboxyl group selected from the group consisting of hydrolyzate of starch/acrylonitrile graft copolymer; partial neutralization product of starch/acrylic acid graft copolymer; saponification product of vinyl acetate/acrylic ester copolymer; hydrolyzate of acrylonitrile copolymers; hydrolyzate of acrylamide copolymer; crosslinked product of any of the foregoing copolymers; partial neutralization product of polyacrylic acid; and crosslinked partial neutralization product of polyacrylic acid; with 0.001 to 10 parts by weight of a crosslinking agent having at least two functional groups capable of reacting with the carboxyl group per molecule and reacting the absorbent resin powder with the crosslinking agent to crosslink the molecular chains existing at least in the vicinity of the surface of the absorbent resin powder.
Claim 2
Dependent Claim
132 words
An absorbent article obtained by mixing 100 parts by weight of a powder of an absorbent resin having a carboxyl group selected from the group consisting of hydrolyzate of starch/acrylonitrile graft copolymer; partial neutralization product of starch/acrylic acid graft copolymer; saponification product of vinyl acetate/acrylic ester copolymer; hydrolyzate of acrylonitrile copolymers; hydrolyzate of acrylamide copolymer; crosslinked product of any of the foregoing copolymers; partial neutralization product of polyacrylic acid; and crosslinked partial neutralization product of polyacrylic acid; with 0.001 to 10 parts by weight of a crosslinking agent having at least two functional groups capable of reacting with the carboxyl group per molecule and reacting the absorbent resin powder with the crosslinking agent to crosslink the molecular chains existing at least in the vicinity of the surface of the absorbent resin powder.
Claim 3
Dependent Claim
155 words
An absorbent article obtained by mixing 100 parts by weight of a powder of an absorbent resin having a carboxyl group with 0.001 to 10 parts by weight of a crosslinking agent having at least two functional groups capable of reacting with the carboxyl groups per molecule and reacting the absorbent resin powder with the crosslinking agent to crosslink the molecular chains existing at least in the vicinity of the surface of the absorbent resin powder; wherein the absorbent resin having a carboxyl group is an alkali metal acrylate-type polymer obtained by copolymerizing 100 parts by weight of an acrylic acid salt-type monomer composed of 1 to 50 mole% of acrylic acid and 50 to 99 mole% of an alkali metal acrylate and 0 to 5 parts by weight of a crosslinkable monomer in aqueous solution in a monomer concentration of at least 20% by weight, and drying the resulting gel-like hydrous polymer under heat.
Claim 4
Dependent Claim
155 words
An absorbent article obtained by mixing 100 parts by weight of a powder of an absorbent resin having a carboxyl group with 0.001 to 10 parts by weight of a crosslinking agent having at least two functional groups capable of reacting with the carboxyl groups per molecule and reacting the absorbent resin powder with the crosslinking agent to crosslink the molecular chains existing at least in the vicinity of the surface of the absorbent resin powder; wherein the absorbent resin having a carboxyl group is an alkali metal acrylate-type polymer obtained by copolymerizing 100 parts by weight of an acrylic acid salt-type monomer composed of 1 to 50 mole% of acrylic acid and 50 to 99 mole% of an alkali metal acrylate and 0 to 5 parts by weight of a crosslinkable monomer in aqueous solution in a monomer concentration of at least 20% by weight, and drying the resulting gel-like hydrous polymer under heat.
Claim 5
Dependent Claim
25 words
The absorbent article of claim 1 wherein the absorbent resin powder contains at least 70% by weight of particles which pass through a 60-mesh sieve.
Claim 6
Dependent Claim
15 words
The absorbent article of claim 1 wherein the crosslinking agent is a polyhydric alcohol compound.
Claim 7
Dependent Claim
25 words
The absorbent article of claim 4 which is obtained by reacting the absorbent resin powder with the polyhydric alcohol compound at 90° to 300° C.
Claim 8
Dependent Claim
15 words
The absorbent article of claim 1 wherein the crosslinking agent is a polyglycidyl ether compound.
Claim 9
Dependent Claim
25 words
The absorbent article of claim 6 which is obtained by reacting the absorbent resin powder with the polyglycidyl ether compound at 50° to 300° C.
Claim 10
Dependent Claim
15 words
The absorbent article of claim 1 wherein the crosslinking agent is a polyfunctional aziridine compound.
Claim 11
Dependent Claim
25 words
The absorbent article of claim 8 which is obtained by reacting the absorbent resin powder with the polyfunctional aziridine compound at 10° to 300° C.
Claim 12
Dependent Claim
15 words
The absorbent article of claim 1 wherein the crosslinking agent is a polyfunctional amine compound.
Claim 13
Dependent Claim
25 words
The absorbent article of claim 10 which is obtained by reacting the absorbent resin powder with the polyfunctional amine compound at 90° to 300° C.
Claim 14
Dependent Claim
15 words
The absorbent article of claim 1 wherein the crosslinking agent is a polyfunctional isocyanate compound.
Claim 15
Dependent Claim
25 words
The absorbent article of claim 12 which is obtained by reacting the absorbent resin powder with the polyfunctional isocyanate compound at 10° to 300° C.
Claim 16
Dependent Claim
32 words
The absorbent article of claim 2 wherein the crosslinking agent is a compound selected from the group consisting of glycerol, polyethylene glycol, triethanolamine, sorbitan monolaurate, polyoxyethylene sorbitan monostearate, trimethylol propane, and sorbitol.
Claim 17
Dependent Claim
29 words
The absorbent article of claim 14 wherein the amount of the crosslinking agent is about 0.3 part by weight per 100 parts by weight of the absorbent resin powder.
Claim 18
Dependent Claim
27 words
The absorbent article of claim 2 wherein the crosslinking agent is selected from the group consisting of 2,2-bishydroxymethylbutanol-tris[3-(1-aziridinyl)propionate], ethylene glycol diglycidyl ether, 2,4-tolylene diisocyanate and triethylene tetraamine.
Claim 19
Dependent Claim
33 words
The absorbent article of claim 2 wherein the absorbent resin powder is crosslinked with 0.05 part by weight, per 100 parts of the absorbent resin powder of 2,2-bishydroxymethylbutanol-tri[3-(1-aziridinyl)propionate] or ethylene glycol diglycidyl ether.
Claim 20
Dependent Claim
34 words
The absorbent article of claim 2 wherein the absorbent resin powder is crosslinked with 1 part by weight, per 100 parts by weight of the absorbent resin powder, of 2,4-tolylene diisocyanate or triethylene tetraamine.
Claim 21
Dependent Claim
67 words
An absorbent article which is a reaction product of 100 parts by weight of a powder of an absorbent resin which is a saponified copolymer of vinyl acetate and methylacrylate with 0.001 to 10 parts by weight of a crosslinking agent which is trimethylol propane wherein at least the molecular chains existing at least in the vicinity of the surface of the absorbent resin powder are crosslinked.
Claim 22
Dependent Claim
67 words
An absorbent article which is a reaction product of 100 parts by weight of a powder of an absorbent resin which is a saponified copolymer of vinyl acetate and methylacrylate with 0.001 to 10 parts by weight of a crosslinking agent which is trimethylol propane wherein at least the molecular chains existing at least in the vicinity of the surface of the absorbent resin powder are crosslinked.
Claim 23
Dependent Claim
67 words
An absorbent article which is a reaction product of 100 parts by weight of a powder of an absorbent resin which is a crosslinked copolymer of isobutylene and maleic anhydride with 0.001 to 10 parts by weight of a crosslinking agent which is polyethylene glycol wherein at least the molecular chains existing at least in the vicinity of the surface of the absorbent resin powder are crosslinked.
Claim 24
Dependent Claim
67 words
An absorbent article which is a reaction product of 100 parts by weight of a powder of an absorbent resin which is a crosslinked copolymer of isobutylene and maleic anhydride with 0.001 to 10 parts by weight of a crosslinking agent which is polyethylene glycol wherein at least the molecular chains existing at least in the vicinity of the surface of the absorbent resin powder are crosslinked.
Claim 25
Dependent Claim
23 words
The absorbent article of claim 19 wherein 1 part of the crosslinking agent is used per 100 parts of the absorbent resin powder.
Claim 26
Dependent Claim
28 words
The absorbent article of claim 20 wherein the crosslinking agent is used in an amount of 0.5 part per 100 parts by weight of the absorbent resin powder.
Claim 27
Dependent Claim
78 words
The absorbent article of claim 1 wherein the absorbent resin is obtained by dispersing an aqueous solution of acrylic acid, an alkali metal acrylate containing a water-soluble radical, or mixtures thereof, and containing a water-soluble radical polymerization initiator in a hydrocarbon solvent selected from the group consisting of alicyclic hydrocarbon, aliphatic hydrocarbon, and mixtures thereof, in the presence of a surface-active agent having a hydrophile-lipophile (HLB) balance of 3 to 12, and subjecting the mixture to suspension polymerization.
Claim 28
Dependent Claim
30 words
The absorbent article of claim 1 wherein the absorbent resin is a saponification product of a copolymer of a vinyl ester and an ethylenically unsaturated carboxylic acid or derivative thereof.
Claim 29
Dependent Claim
54 words
The absorbent article of claim 1 wherein the absorbent resin is a polymer obtained by polymerizing starch, cellulose, or a mixture thereof in an aqueous medium with a monomer having a carboxyl group or a monomer capable of forming a carboxyl group upon hydrolysis and a crosslinking monomer or the hydrolyzate of said polymer.
Claim 30
Dependent Claim
51 words
The absorbent article of claim 1 wherein the absorbent resin is the reaction product of an alkaline substance with a maleic anhydride-type copolymer composed of maleic anhydride and at least one monomer selected from the group consisting of alpha-olefins and vinyl compounds or the reaction product thereof with a polyepoxy compound.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-05-18 | 1990-11-17 | 1991-05-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-05-18 | 1994-11-17 | 1995-05-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-05-18 | 1998-11-17 | 1999-05-19 | $7700.00 | Window Closed / Lapsed |