US4666742A
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Polymer composition containing an organic metal complex and method for producing a metallized polymer from the polymer composition
Assignee: Nissan Chemical Corp
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Filing: 1985-10-02
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Granted: 1987-05-19
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Expires: 2005-10-02
Abstract
Abstract A polymer composition comprising a polymer and an organic metal complex uniformly dispersed or dissolved therein.
Inventors
- 👤 Makoto Takakura
- 👤 Susumu Kondo
- 👤 Tatsuya Nogami
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 11:40
CPC Classifications
C; C08; C08K; C08K3/00; C08K3/02; C08K3/08; C08K5/00; C08K5/0091; H; H05; H05K; H05K3/00; H05K3/10; H05K3/105; H05K2203/00; H05K2203/11; H05K2203/1105; H05K2203/12; H05K2203/121; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
94 words
A method for producing a metallized polymer, which comprises: (a) contacting a polymer film comprising a polymer and an organic metal complex, wherein the weight ratio of the polymer to the metal of said organic metal complex ranges from 99.9:0.1 to 80:20, with a metallizing board made of copper or a copper alloy; (b) forming metal layer on the surface of said film from the liberated metal from said organic metal complex by heating the polymer film and metallizing board of step (a); and (c) recovering a polymer film with a metallized surface thereon.
Claim 2
Independent Claim
94 words
A method for producing a metallized polymer, which comprises: (a) contacting a polymer film comprising a polymer and an organic metal complex, wherein the weight ratio of the polymer to the metal of said organic metal complex ranges from 99.9:0.1 to 80:20, with a metallizing board made of copper or a copper alloy; (b) forming metal layer on the surface of said film from the liberated metal from said organic metal complex by heating the polymer film and metallizing board of step (a); and (c) recovering a polymer film with a metallized surface thereon.
Claim 3
Dependent Claim
40 words
The method according to claim 1, wherein the central metal of the organic metal complex is at least one metal selected from the group consisting of metals of Groups IV-A, V-A, VII-A, VIII and I-B of the Periodic Law Table.
Claim 4
Dependent Claim
41 words
The method acccrding to claim 1, wherein the central metal is at least one metal selected from the group consisting of titanium, zirconium, vanadium, chromium, molybdenum, tungsten, manganese, iron, cobalt, nickel, ruthenium, rhodium, iridium, palladium, osmium, platinum, copper, silver and gold.
Claim 5
Dependent Claim
83 words
The method according to claim 1, wherein the ligand of the organic metal complex is at least one ligand selected from the group consisting of a tertiary phosphine, a tertiary phosphite, carbon monoxide, an aliphatic or alicyclic olefin, a conjugated olefin, an aryl compound, a heterocyclic compound, an organic cyano compound, an organic isonitrile compound, an organic mercapto compound, a compound having an alkyl group, a vinyl group, an allyl group, an ethynyl group or an acyl group, halogen, oxygen, hydrogen and nitrogen.
Claim 6
Dependent Claim
85 words
The method according to claim 1, wherein the ligand of the organic metal complex is at least one ligand selected from the group consisting of triphenylphosphine, tributylphosphine, triethylphosphine, triphenylphosphite, tributylphosphite, triethylphosphite, carbon monoxide, cyclooctadiene, a substituted or unsubstituted cyclopentadiene, cyclooctatetraene, butadiene, pentadiene, a substituted or unsubstituted benzene, acetonitrile, benzonitrile, a compound having a lower alkyl group or a benzyl group, ethylene, propylene, isobutylene, t-butyl-isonitrile, vinyl-isonitrile, benzo-isonitrile, a substituted or unsubstituted acetylene, acetylacetone, ethyl acetyl acetonate, pyridine, thiophene, quinoline, furan, 2,2'-dipyridyl, ethylenedithiol, toluene-3,4-dithiol, chlorine and bromine.
Claim 7
Dependent Claim
135 words
The method according to claim 1, wherein the polymer is at least one polymer selected from the group consisting of an ionomer resin, an acrylonitrile-acrylic-styrene resin, an acrylonitrile-styrene resin, an acrylonitrile-butadienestyrene resin, a methylmethacrylate-butadiene-styrene resin, a phenoxy resin, an ethylene-vinylchloride copolymer, an ethylene-vinylacetate copolymer, a polystyrene, a polyvinylidene chloride, a vinyl acetate, a polyethylene, a polypropylene, a polybutadiene, a polyvinylidene fluoride, a polytetrafluoroethylene, a polyacetal, a polyamide, a polyamide-imide, a polyarylate, a polyether-imide, a polyether-ether ketone, a polyethyleneterephthalate, a polybutyleneterephthalate, a polycarbonate, a polysulphone, a polyethersulphone, a polyphenylene oxide, a polyphenylene sulfide, a polymethylmethacrylate, a guanamine resin, a diallylphthalate resin, a vinyl ester resin, a phenol resin, an unsaturated polyester resin, a furan resin, a polyimide resin, a poly-p-hydroxybenzoate, a urethane resin, a melamine-formaldehyde resin, a urea-formaldehyde resin, an epoxy resin and a xylene-formaldehyde resin.
Claim 8
Dependent Claim
83 words
The method according to claim 1, wherein the polymer is at least one rubber-like polymer selected from the group consisting of a styrene-butadiene rubber, a polybutadiene rubber, a polyisoprene rubber, an acrylonitrile-butadiene rubber, a polychloroprene rubber, a butyl rubber, a urethane rubber, an acrylate rubber, a silicone rubber, a fluorinated rubber, a styrene-block copolymer, a thermoplastic elastomer polyolefin, a thermoplastic elastomer polyvinylchloride, a thermoplastic elastomer polyurethane, a thermoplastic elastomer polyester, a thermopolastic elastomer polyamide, a thermoplastic elastomer fluorinated resin and a natural rubber.
Claim 9
Dependent Claim
20 words
The method of claim 19 wherein said metallizing board is partially coated with a resin not capable of inducing metallization.
Claim 10
Dependent Claim
16 words
The method of claim 8, wherein the surface of the recovered metallized polymer contains a pattern.
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