US4666527A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Continuous crystallization of fructose anhydride
Assignee: Kato Kagaku Co Ltd
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Filing: 1984-11-06
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Granted: 1987-05-19
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Expires: 2004-11-06
Abstract
Abstract The present invention relates to a process for continuously crystallizing fructose anhydride using a seed crystallization tank and a crystallization tank separated from each other, comprising feeding an aqueous fructose solution containing at least 90% of fructose and containing at least 87 W/W % of solid and an aqueous solution containing a great deal of crystals in an amount of 0.5 to 5 times that of said fructose solution into a seed crystallization tank equipped with a high speed agitator, mixing the mixture at 40° to 50° C. at a high speed, introducing the obtained mixture into a crystallization tank and gradually cooling the mixture under condition under which new crystals do not form spontaneously to thereby grow the crystals. The present invention can realize the crystallization at a low temperature of 40° to 50° C. or below and prevents the decomposition and the polymerization of fructose which often occur above 50° C. by mixing an aqueous fructose solution and a great deal of crystals at a high speed, whereby large and uniform crystals of fructose anhydride can be obtained in an enhanced yield.
Inventors
- 👤 Yoshikuni Ito
- 👤 Jinshu Kanamoto
- 👤 Seiji Murayama
- 👤 Shinji Suzuki
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 01:39
CPC Classifications
C; C13; C13K; C13K11/00
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
294 words
A process for continuously crystallizing fructose anhydride which comprises: providing a cyrstallization tank comprising an upper crystallization chamber maintained at a temperature of 35°-45° C. and a lower crystallization chamber maintained at a temperature lower than said upper crystallization chamber of between 25°-35° C., a connecting passage being provided between said upper and lower crystallization chambers, whereby a first decreasing temperature gradient from said upper to said lower crystallization chambers is maintained; providing a seed crystallization tank having a high speed agitator; maintaining an upper portion of said seed crystallization tank at 40°-50° C.; maintaining a lower portion of said seed crystallization tank at 30°-40° C. so that a second gradient of decreasing temperature between said upper and lower portions of said seed crystallization tank is maintained; feeding a first aqueous solution containing at least 90% of fructose and containing at least 87 W/W % of solid and a second aqueous solution, containing 25-35 W/W % of crystals, from said upper crystallization chamber in an amount of 50-500% of the first aqueous solution into said upper portion of said seed crystallization tank, at 40°-50° C., with high speed agitation of said seed crystallization tank to obtain mixture; removing said mixture from said lower portion of said seed crystallization tank, whereby said mixture has been gradually cooled by said second gradient of decreasing temperature; feeding said removed mixture into said upper crystallization chamber and flowing said removed mixture through said upper crystallization chamber into said connecting passage and then into said lower cyrstallization chamber, whereby said mixture is subjected to said first temperature gradient and said mixture is thereby gradually cooled under conditions such that new crystals do not form spontaneously, to thereby grow said crystals in said lower cyrstallization chamber; and isolating said crystals.
Claim 2
Dependent Claim
294 words
A process for continuously crystallizing fructose anhydride which comprises: providing a cyrstallization tank comprising an upper crystallization chamber maintained at a temperature of 35°-45° C. and a lower crystallization chamber maintained at a temperature lower than said upper crystallization chamber of between 25°-35° C., a connecting passage being provided between said upper and lower crystallization chambers, whereby a first decreasing temperature gradient from said upper to said lower crystallization chambers is maintained; providing a seed crystallization tank having a high speed agitator; maintaining an upper portion of said seed crystallization tank at 40°-50° C.; maintaining a lower portion of said seed crystallization tank at 30°-40° C. so that a second gradient of decreasing temperature between said upper and lower portions of said seed crystallization tank is maintained; feeding a first aqueous solution containing at least 90% of fructose and containing at least 87 W/W % of solid and a second aqueous solution, containing 25-35 W/W % of crystals, from said upper crystallization chamber in an amount of 50-500% of the first aqueous solution into said upper portion of said seed crystallization tank, at 40°-50° C., with high speed agitation of said seed crystallization tank to obtain mixture; removing said mixture from said lower portion of said seed crystallization tank, whereby said mixture has been gradually cooled by said second gradient of decreasing temperature; feeding said removed mixture into said upper crystallization chamber and flowing said removed mixture through said upper crystallization chamber into said connecting passage and then into said lower cyrstallization chamber, whereby said mixture is subjected to said first temperature gradient and said mixture is thereby gradually cooled under conditions such that new crystals do not form spontaneously, to thereby grow said crystals in said lower cyrstallization chamber; and isolating said crystals.
Claim 3
Dependent Claim
36 words
A process according to claim 1, wherein said mixture removed from the lower portion of the seed crystallization tank and fed to the upper crystallization chamber is heated to dissolve fine crystals in said removed mixture.
Claim 4
Dependent Claim
29 words
A process according to claim 1, wherein a portion of the mixture separated from said grown crystals during said isolation step is continuously mixed with said first aqueous solution.
Claim 5
Dependent Claim
23 words
A process according to claim 1 which comprises providing said crystallization tank with a low speed agitator which prevents crystals from being damaged.
Claim 6
Dependent Claim
70 words
A process according to claim 1 wherein said seed crystallization tank and said crystallization tank are each in the form of a vertical cylinder with a ratio of diameter to height of 1:2 to 1:10 and provided with a temperture controller for controlling the temperature of the solution by heating or cooling and with a bottom inclined by 15 to 60 degrees to facilitate the discharge of the crystalline massecuite.
Claim 7
Dependent Claim
77 words
A process according to claim 1 wherein each of said tanks has a jacket thereabout and cooling of the seed crystallization tank and the crystallization tank is carried out by introducing cooling water into the lower part of each jacket and discharging it from the upper part of each jacket to produce a temperature gradient in such a way that the temperature of the tank is lower in the lower part and higher in the upper part.
Claim 8
Dependent Claim
15 words
A process according to claim 1, wherein the entire process is conducted at ambient pressure.
Claim 9
Dependent Claim
41 words
The process of claim 1, whereby said mixture removed from said lower portion of said seed cyrstallization tank is fed into said upper crystallization chamber at a point below where said second aqueous solution is removed from said upper crystallization chamber.
Claim 10
Dependent Claim
24 words
The process of claim 8, whereby said mixture in said lower portion of said seed crystallization chamber is pumped into said upper crystallization chamber.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-05-18 | 1990-11-17 | 1991-05-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-05-18 | 1994-11-17 | 1995-05-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-05-18 | 1998-11-17 | 1999-05-19 | $7700.00 | Window Closed / Lapsed |