US4661440A
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Process for stabilizing photographic material containing magenta coupler
Assignee: Ha Whitten & Co
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Filing: 1985-11-07
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Granted: 1987-04-28
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Expires: 2005-11-07
Abstract
Abstract Photographic material containing magenta coupler is stabilized by incorporating a dibenzoxaphosphorin of the formula ##STR1## into the emulsion layer containing the coupler or into an adjoining colloid layer. The yellowing on dark storage of such material is substantially reduced as a result. The symbols A and n are defined in claim 1.
Inventors
- 👤 Paul Tschopp
- 👤 David G. Leppard
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 14:16
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/30; G03C7/392; G03C7/39208; G03C7/39288; C; C07; C07F; C07F9/00; C07F9/02; C07F9/547; C07F9/6564; C07F9/6571; C07F9/657163; C07F9/65719; Y; Y10; Y10S; Y10S430/00; Y10S430/132
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
354 words
A process for stabilising photographic silver halide material containing magenta coupler, which comprises incorporating into the silver halide emulsion layer containing the magenta coupler or into an adjoining colloid layer at least one compound of the formula I ##STR41## in which n is the number 1 or 2 and A, if n is 1, is a group of the formula II ##STR42## in which R 1 is C 1 -C 18 -alkyl, C 5 -C 6 -cycloalkyl, Cl, Br, CN, C 7 -C 21 -aralkyl or a group of the formula III ##STR43## in which X is C 2 -C 8 -alkylene and Y is a --OR 4 , --N(R 5 )(R 6 ), C 1 -C 4 -alkyl, the residue ##STR44## wherein B is C 1 -C 18 -alkylene which is uninterrupted or interrupted one or more times by --O-- or --S-- or is a group of the formula ##STR45## R 2 is hydrogen, R 1 or a --OR 7 group, R 3 is hydrogen or R 1 , R 4 is C 1 -C 18 -alkyl which is uninterrupted or interrupted one or more times by --O-- or is a polyethylene glycol radical, phenyl, substituted phenyl or benzyl, R 5 and R 6 , independently of each other, are hydrogen, C 1 -C 18 -alkyl, phenyl, benzyl, or a --(CH 2 ) m --O--R 8 group, R 7 is hydrogen or C 1 -C 4 -alkyl, R 8 is C 1 -C 18 -alkyl and m is a number between 1 and 4, or R 2 and R 3 together are C 3 -C 8 -alkylene or a group ##STR46## in which R 9 , R 10 , R 11 independently of one another are each C 1 -C 4 -alkyl, or A, if n is 2, is a group of the formula IV ##STR47## in which R 12 and R 13 , independently of one another, are each C 1 -C 18 -alkyl or a group of the formula III or A is a group of the formula V ##STR48## in which R 8 and R 9 are as defined above.
Claim 2
Dependent Claim
354 words
A process for stabilising photographic silver halide material containing magenta coupler, which comprises incorporating into the silver halide emulsion layer containing the magenta coupler or into an adjoining colloid layer at least one compound of the formula I ##STR41## in which n is the number 1 or 2 and A, if n is 1, is a group of the formula II ##STR42## in which R 1 is C 1 -C 18 -alkyl, C 5 -C 6 -cycloalkyl, Cl, Br, CN, C 7 -C 21 -aralkyl or a group of the formula III ##STR43## in which X is C 2 -C 8 -alkylene and Y is a --OR 4 , --N(R 5 )(R 6 ), C 1 -C 4 -alkyl, the residue ##STR44## wherein B is C 1 -C 18 -alkylene which is uninterrupted or interrupted one or more times by --O-- or --S-- or is a group of the formula ##STR45## R 2 is hydrogen, R 1 or a --OR 7 group, R 3 is hydrogen or R 1 , R 4 is C 1 -C 18 -alkyl which is uninterrupted or interrupted one or more times by --O-- or is a polyethylene glycol radical, phenyl, substituted phenyl or benzyl, R 5 and R 6 , independently of each other, are hydrogen, C 1 -C 18 -alkyl, phenyl, benzyl, or a --(CH 2 ) m --O--R 8 group, R 7 is hydrogen or C 1 -C 4 -alkyl, R 8 is C 1 -C 18 -alkyl and m is a number between 1 and 4, or R 2 and R 3 together are C 3 -C 8 -alkylene or a group ##STR46## in which R 9 , R 10 , R 11 independently of one another are each C 1 -C 4 -alkyl, or A, if n is 2, is a group of the formula IV ##STR47## in which R 12 and R 13 , independently of one another, are each C 1 -C 18 -alkyl or a group of the formula III or A is a group of the formula V ##STR48## in which R 8 and R 9 are as defined above.
Claim 3
Dependent Claim
283 words
A process according to claim 1, wherein the compound used has the formula I in which A, if n is 1, is a group of the formula II ##STR49## in which R 1 is C 1 -C 18 -alkyl, C 5 -C 6 -cycloalkyl, Cl, Br, CN, C 7 -C 21 -aralkyl or a group of the formula III ##STR50## in which X is C 2 -C 8 -alkylene and Y is a --OR 4 or --N(R 5 )(R 6 ) group, R 2 is hydrogen, R 1 or a --OR 7 group, R 3 is hydrogen or R 1 , R 4 is C 1 -C 18 -alkyl which is uninterrupted or interrupted one or more times by --O-- or is a polyethylene glycol radical, phenyl or benzyl, R 5 and R 6 , independently of each other, are hydrogen, C 1 -C 18 -alkyl, phenyl, benzyl, or a --(CH 2 ) m --O--R 8 group, R 7 is hydrogen or C 1 -C 4 -alkyl, R 8 is C 1 -C 18 -alkyl and m is a number between 1 and 4, or R 2 and R 3 together are C 3 -C 8 -alkylene or a group ##STR51## in which R 9 , R 10 , R 11 independently of one another are each C 1 -C 4 -alkyl, or A, if n is 2, is a group of the formula IV ##STR52## in which R 12 and R 13 , independently of one another, are each C 1 -C 18 -alkyl or a group of the formula III or A is a group of the formula V ##STR53## in which R 8 and R 9 are as defined above.
Claim 4
Dependent Claim
116 words
A process according to claim 1, wherein the compound used has the formula I in which A, if n is 1, is a group of the formula II in which R 1 and R 2 , independently of each other, are each hydrogen, C 1 -C 18 -alkyl or C 7 -C 21 -aralkyl, and R 3 is hydrogen, or R 2 and R 3 together are C 2 -C 8 -alkylene, or A, if n is 2, is a group of the formula IV in which R 12 and R 13 are each C 1 -C 18 -alkyl or a --X--C(O)OR 4 group in which X and R 4 are as defined in claim 1.
Claim 5
Dependent Claim
119 words
A process according to claim 1, wherein the compound used has the formula I in which A, if n is 1, is a group of the formula VI ##STR54## in which R 1 and R 2 are each branched C 4 -C 8 -alkyl or α,α-dimethylbenzyl and R 3 is hydrogen, or R 2 and R 3 together are the --C(CH 3 ) 2 --CH 2 --C(CH 3 ) 2 -- group, or A, if n is 2, is a group of the formula VII ##STR55## in which R 12 and R 13 are each branched alkyl or a group of the formula VIII --C(CH.sub.3).sub.2 --(CH.sub.2).sub.3 --COOR.sub.4 (VIII) in which R 4 is straight-chain C 1 -C 18 -alkyl.
Claim 6
Dependent Claim
108 words
A process according to claim 1, wherein the compound used has the formula I in which A, if n is 1, is a group of the formula VI in which R 1 and R 2 are each tert.-butyl, 1,1,3,3-tetramethylbutyl or α,α-dimethylbenzyl and R 3 is hydrogen or R 2 and R 3 together are a --C(CH 3 ) 2 --CH 2 --C(CH 3 ) 2 -- group, or A, if n is 2, is a group of the formula VII in which R 12 and R 13 are each tert.-butyl, 1,1,3,3-tetramethylbutyl or a group of the formula VIII in which R 4 is C 1 -C 10 -alkyl.
Claim 7
Dependent Claim
18 words
A process according to claim 1, wherein the compound of the formula I used has the formula ##STR56##
Claim 8
Dependent Claim
18 words
A process according to claim 1, wherein the compound of the formula I used has the formula ##STR57##
Claim 9
Dependent Claim
18 words
A process according to claim 1, wherein the compound of the formula I used has the formula ##STR58##
Claim 10
Dependent Claim
27 words
A process according to claim 1, wherein the compound of the formula I is used in an amount of 1-400 mol %, based on the magenta coupler.
Claim 11
Dependent Claim
26 words
A process according to claim 1, where the photographic material contains at least one further organic stabiliser, UV absorber, fluorescent brightening agents, anti-fogging agent and/or plasticiser.
Claim 12
Dependent Claim
17 words
A process according to claim 1, wherein the photographic material contains at least one further colour coupler.
References Cited (Backward Citations)
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1990-04-27 | 1990-10-27 | 1991-04-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-04-27 | 1994-10-27 | 1995-04-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-04-27 | 1998-10-27 | 1999-04-28 | $7700.00 | Window Closed / Lapsed |