Patent US2540984A successfully refreshed from Google Patents.
US4659783A
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Acrylic star polymers containing multifunctional monomers in the core
Assignee: EIDP Inc
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Filing: 1985-09-03
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Granted: 1987-04-21
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Expires: 2005-09-03
Abstract
Abstract Large acrylic star polymers, having a low polydispersity of polymer molecular weight and of arm molecular weight and containing multifunctional monomers in the core.
Inventors
- 👤 Harry J. Spinelli
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 00:19
CPC Classifications
C; C08; C08F; C08F290/00; C08F290/02; C08F290/04; C08F290/046; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31855
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
173 words
A soluble acrylic star polymer comprising (a) a crosslinked core consisting essentially of a polymer derived from one or more monomers, each having at least two groups, ##STR33## and (b) attached to the core, at least 5 arms comprising polymer chains derived from one or more monomers, each having one group. ##STR34## in each of which R is the same or different and is H, CH 3 , CH 3 CH 2 , CN or CO 2 R' and Z' is O or NR', wherein R' is C 1-4 alkyl, wherein: at least 50% of the molecules of such star polymers have at least from 5 to 2,000,000 arms, wherein the ratio of the number of arms to the number of difunctional acrylic repeat units in the core is less than or equal to 1:1, and (c) wherein the soluble is defined as that nothing separates out from a solution of 1% weight of the star polymer in 99% solvent of toluene, glyme or tetrahydrofuran upon centrifuging at 17,000 rpm for 30 minutes.
Claim 2
Dependent Claim
173 words
A soluble acrylic star polymer comprising (a) a crosslinked core consisting essentially of a polymer derived from one or more monomers, each having at least two groups, ##STR33## and (b) attached to the core, at least 5 arms comprising polymer chains derived from one or more monomers, each having one group. ##STR34## in each of which R is the same or different and is H, CH 3 , CH 3 CH 2 , CN or CO 2 R' and Z' is O or NR', wherein R' is C 1-4 alkyl, wherein: at least 50% of the molecules of such star polymers have at least from 5 to 2,000,000 arms, wherein the ratio of the number of arms to the number of difunctional acrylic repeat units in the core is less than or equal to 1:1, and (c) wherein the soluble is defined as that nothing separates out from a solution of 1% weight of the star polymer in 99% solvent of toluene, glyme or tetrahydrofuran upon centrifuging at 17,000 rpm for 30 minutes.
Claim 3
Dependent Claim
35 words
A soluble acrylic star polymer of claim 1 made by polymerization in the presence of a polymerization initiator wherein the molar ratio of initiator to difunctional acrylic monomer is less than or equal to 1:1.
Claim 4
Dependent Claim
10 words
A coating composition containing a star polymer of claim 1.
Claim 5
Dependent Claim
14 words
A substrate coated with a coating composition containing a star polymer of claim 1.
Claim 6
Dependent Claim
10 words
A molding composition containing a star polymer of claim 1.
Claim 7
Dependent Claim
10 words
A molded article containing a star polymer of claim 1.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-04-20 | 1990-10-20 | 1991-04-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-04-20 | 1994-10-20 | 1995-04-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-04-20 | 1998-10-20 | 1999-04-21 | $7700.00 | Window Closed / Lapsed |