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US4659783A Expired / Lapsed US ⏱️ 0.0 years remaining

Acrylic star polymers containing multifunctional monomers in the core

Assignee: EIDP Inc
•
Filing: 1985-09-03
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Granted: 1987-04-21
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Expires: 2005-09-03
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Abstract

Abstract Large acrylic star polymers, having a low polydispersity of polymer molecular weight and of arm molecular weight and containing multifunctional monomers in the core.

Inventors

  • 👤 Harry J. Spinelli

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 00:19
CPC Classifications
C; C08; C08F; C08F290/00; C08F290/02; C08F290/04; C08F290/046; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31855

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 173 words
A soluble acrylic star polymer comprising (a) a crosslinked core consisting essentially of a polymer derived from one or more monomers, each having at least two groups, ##STR33## and (b) attached to the core, at least 5 arms comprising polymer chains derived from one or more monomers, each having one group. ##STR34## in each of which R is the same or different and is H, CH 3 , CH 3 CH 2 , CN or CO 2 R' and Z' is O or NR', wherein R' is C 1-4 alkyl, wherein: at least 50% of the molecules of such star polymers have at least from 5 to 2,000,000 arms, wherein the ratio of the number of arms to the number of difunctional acrylic repeat units in the core is less than or equal to 1:1, and (c) wherein the soluble is defined as that nothing separates out from a solution of 1% weight of the star polymer in 99% solvent of toluene, glyme or tetrahydrofuran upon centrifuging at 17,000 rpm for 30 minutes.
Claim 2
Dependent Claim 173 words
A soluble acrylic star polymer comprising (a) a crosslinked core consisting essentially of a polymer derived from one or more monomers, each having at least two groups, ##STR33## and (b) attached to the core, at least 5 arms comprising polymer chains derived from one or more monomers, each having one group. ##STR34## in each of which R is the same or different and is H, CH 3 , CH 3 CH 2 , CN or CO 2 R' and Z' is O or NR', wherein R' is C 1-4 alkyl, wherein: at least 50% of the molecules of such star polymers have at least from 5 to 2,000,000 arms, wherein the ratio of the number of arms to the number of difunctional acrylic repeat units in the core is less than or equal to 1:1, and (c) wherein the soluble is defined as that nothing separates out from a solution of 1% weight of the star polymer in 99% solvent of toluene, glyme or tetrahydrofuran upon centrifuging at 17,000 rpm for 30 minutes.
Claim 3
Dependent Claim 35 words
A soluble acrylic star polymer of claim 1 made by polymerization in the presence of a polymerization initiator wherein the molar ratio of initiator to difunctional acrylic monomer is less than or equal to 1:1.
Claim 4
Dependent Claim 10 words
A coating composition containing a star polymer of claim 1.
Claim 5
Dependent Claim 14 words
A substrate coated with a coating composition containing a star polymer of claim 1.
Claim 6
Dependent Claim 10 words
A molding composition containing a star polymer of claim 1.
Claim 7
Dependent Claim 10 words
A molded article containing a star polymer of claim 1.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-04-20 1990-10-20 1991-04-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-04-20 1994-10-20 1995-04-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-04-20 1998-10-20 1999-04-21 $7700.00 Window Closed / Lapsed

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