Cyclohexanedimethanol/diamine mixtures as RIM extenders

Claim 2

In a polyurethane polyurea polymer prepared by the catalyzed reaction injection molding of an organic polyisocyanate, an optional high molecular weight compound having at least two active hydrogen containing groups, and an extender mixture comprising (i) an aromatic diamine wherein at least one of the positions ortho to each amine group of said diamine is substituted by a lower alkyl group and (ii) a low molecular weight diol, the improvement which comprises employing as said diol a bis (hydroxyalkyl)cycloalkane.

Claim 3

A polymer according to claim 1 wherein said extender mixture comprises (i) from about 20 to about 95 percent by weight of said diamine and complementally (ii) from 80 to 5 percent of said bis(hydroxyalkyl)cycloalkane.

Claim 4

A polymer according to claim 1 wherein said aromatic diamine is selected from the group consisting of 1-methyl-3,5-diethyl-2,4-diaminobenzene, 1-methyl-3,5-diethyl-2,6-diaminobenzene, and mixtures thereof.

Claim 5

A polymer according to claim 1 wherein said diol comprises a bis(hydroxyalkyl)cyclohexane.

Claim 6

A polymer according to claim 1 wherein the ratio of isocyanate equivalents to the total active hydrogen equivalents of said optional active hydrogen containing compound and said extender mixture is from about 0.85 to about 1.2.

Claim 7

A polymer according to claim 1 wherein said optional active hydrogen containing compound is present such that its equivalent proportions to the total active hydrogen equivalents of said extender mixture falls within the range of from about 1:4 to about 1:100.

Claim 8

A polymer according to claim 6 wherein said equivalent proportions fall within a range of from about 1:10 to about 1:80.

Claim 9

A polymer according to claim 1 wherein said optional active hydrogen containing compound comprises a polyol.

Claim 10

A polymer according to claim 8 wherein said polyol has a molecular weight of from about 1500 to about 7000 and a primary hydroxyl functionality of from about 2 to about 4.

Claim 11

A polymer according to claim 1 wherein said polyisocyanate comprises an aromatic polyisocyanate.

Claim 12

A polymer according to claim 10 wherein said polyisocyanate is selected from the group consisting of (a) an isocyanate terminated prepolymer prepared from methylenebis(phenyl isocyanate); (b) a liquefied form of 4,4'-methylenebis(phenyl isocyanate); and mixtures of (a) and (b).

Claim 13

A high flexural-modulus polyurethane polyurea polymer prepared by the reaction injection molding of A a polyisocyanate selected from the group consisting of (a) an isocyanate terminated prepolymer prepared from methylenebis (phenyl isocyanate); (b) a liquefied form of 4,4'-methylenebis(phenyl isocyanate); and mixtures of (a) and (b); B. a polyol having a molecular weight of from about 1500 to about 7000 and a primary hydroxyl functionality of from about 2 to about 4; C. an extender mixture comprising (i) from about 20 to about 95 percent by weight of an aromatic diamine selected from the group consisting of 1-methyl-3.5-diethyl-2,4-diaminobenzene, 1-methyl-3,5-diethyl-2,6-diaminobenzene, and mixtures thereof; and (ii) from about 80 to about 5 percent of a bis(hydroxyalkyl)cyclohexane, and D. a urethane catalyst wherein the equivalent proportions of said polyol (B) to the total active hydrogen equivalents of said extender mixture (C) falls within the range of from about 1:10 to about 1:80 and the ratio of isocyanate equivalents to the total active hydrogen equivalents of (B) and (C) is from about 0.85 to about 1.2

Claim 14

A high flexural-modulus polyurethane polyurea polymer prepared by the reaction injection molding of A a polyisocyanate selected from the group consisting of (a) an isocyanate terminated prepolymer prepared from methylenebis (phenyl isocyanate); (b) a liquefied form of 4,4'-methylenebis(phenyl isocyanate); and mixtures of (a) and (b); B. a polyol having a molecular weight of from about 1500 to about 7000 and a primary hydroxyl functionality of from about 2 to about 4; C. an extender mixture comprising (i) from about 20 to about 95 percent by weight of an aromatic diamine selected from the group consisting of 1-methyl-3.5-diethyl-2,4-diaminobenzene, 1-methyl-3,5-diethyl-2,6-diaminobenzene, and mixtures thereof; and (ii) from about 80 to about 5 percent of a bis(hydroxyalkyl)cyclohexane, and D. a urethane catalyst wherein the equivalent proportions of said polyol (B) to the total active hydrogen equivalents of said extender mixture (C) falls within the range of from about 1:10 to about 1:80 and the ratio of isocyanate equivalents to the total active hydrogen equivalents of (B) and (C) is from about 0.85 to about 1.2

Claim 15

A polyurethane-polyurea according to claim 12 wherein said extender (i) comprises a mixture of 1-methyl-3,5-diethyl-2,4-,and 2,6-diaminobenzene and said extender (ii) comprises bis(hydroxymethyl) cyclohexane.

Claim 16

A polyurethane-polyurea according to claim 13 wherein said (i) is from about 45 to about 85 percent by weight and said (ii) from about 55 to about 15 percent.

Claim 17

A polyurethane-polyurea according to claim 14 wherein said polyisocyanate comprises a liquefied form of 4,4'-methylenebis(phenyl isocyanate).

Claim 18

A polyurethane-polyurea according to claim 14 wherein said polyisocyanate comprises a mixture of an isocyanate terminated prepolymer prepared from methylenebis(phenyl isocyanate) and a liquefied form of 4,4'-methylenebis(phenyl isocyanate).

Claim 19

A miscible blend comprising (i) an aromatic diamine wherein at least one of the positions ortho to each amine group is substituted by a lower alkyl group and (ii) a bis(hydroxyalkyl) cycloalkane.

Claim 20

A miscible blend comprising (i) an aromatic diamine wherein at least one of the positions ortho to each amine group is substituted by a lower alkyl group and (ii) a bis(hydroxyalkyl) cycloalkane.

Claim 21

A blend according to claim 17 wherein (i) comprises an aromatic diamine selected from the group consisting of 1-methyl-3,5-diethyl-2,4-diaminobenzene, 1-methyl-3,5-diethyl-2,6,-diaminobenzene, and mixtures thereof.

Claim 22

A blend according to claim 17 wherein (ii) comprises a bis(hydroxyalkyl)cyclohexane.

Claim 23

A blend according to claim 17 comprising from about 20 to about 95 percent by weight of (i) and from about 80 to about 5 percent of (ii).

Claim 24

A blend according to claim 17 comprising (i) from about 45 to about 85 percent by weight of a mixture of 1-methyl-3,5-diethyl-2,4-diaminobenzene and 1-methyl-3,5-diethyl-2,6-diaminobenzene and (ii) from about 55 to about 15 percent of bis(hydroxymethyl) cyclohexane.

Claim 25

A miscible blend comprising a blend according to claim 17 and a high molecular weight compound having at least two active hydrogen containing groups.