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US4659336A Expired / Lapsed US ⏱️ 0.0 years remaining

Motor fuel composition

Assignee: Texaco Inc
•
Filing: 1986-03-28
•
Granted: 1987-04-21
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Expires: 2006-03-28
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Abstract

Abstract A motor fuel composition comprising a mixture of hydrocarbons in the gasoline boiling range containing in combination a reaction product component and a polyolefin polymer/copolymer component is described. The reaction product component is the reaction product of maleic anhydride, a polyether polyamine, and a hydrocarbyl polyamine. The polyolefin polymer/copolymer component is the polymer, copolymer, or corresponding hydrogenated polymer or copolymer of a C 2 -C 6 unsaturated hydrocarbon, said polymer or copolymer having a molecular weight in the range of 500-3500, preferably 650-2600.

Inventors

  • 👤 Rodney L. Sung
  • 👤 Michael A. Caggiano
  • 👤 Milton D. Behrens

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 21:45
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/146; C10L1/16; C10L1/1625; C10L1/22; C10L1/234; C10L1/238; C10L1/2383; C10L1/2387

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 288 words
A motor fuel composition comprising a mixture of hydrocarbons boiling in the gasoline boiling range containing: (I) from about 0.0005-0.5 weight percent of the reaction product of: (a) 1 mole of maleic anhydride; (b) 1-2 moles of a polyether polyamine represented by the formula: ##STR17## where b has a value from about 5-150, a+c has a value from about 2-20, and Z is selected from the group consisting of (i) a hydrogen atom; (ii) an alkyl radical having from 1-6 carbon atoms; (iii) a polyether radical of the formula ##STR18## where b has a value from about 5-150, and a+c has a value from about 2-20; (iv) an alkylene polyether radical of the formula ##STR19## where R 1 is an alkylene radical having from about 1-6 carbon atoms, b has a value from about 5-150, and a+c has a value from about 2-20; and (v) a radical of the formula R.sub.2 (NH--R.sub.3).sub.x -- where R 2 is an alkyl radical having from about 1-24 carbon atoms, R 3 is an alkylene radical having from about 1-6 carbon atoms, and x has a value from about 1-10; and (c) 1-2 moles of a hydrocarbyl polyamine of the formula R.sub.2 (NH--R.sub.3).sub.x --NH.sub.2 where R 2 is a alkyl radical having from about 1-24 carbon atoms, R 3 is an alkylene radical having from about 1-6 carbon atoms, and x has a value from about 1-10; and (II) from about 0.01-1.0 volume percent, based on the total volume of the motor fuel composition, of a polyolefin polymer, copolymer, or the corresponding hydrogenated polymer or copolymer, or mixtures thereof, of a C 2 -C 6 unsaturated hydrocarbon, said polyolefin polymer or copolymer having a molecular weight in the range from about 500-3500.
Claim 2
Dependent Claim 288 words
A motor fuel composition comprising a mixture of hydrocarbons boiling in the gasoline boiling range containing: (I) from about 0.0005-0.5 weight percent of the reaction product of: (a) 1 mole of maleic anhydride; (b) 1-2 moles of a polyether polyamine represented by the formula: ##STR17## where b has a value from about 5-150, a+c has a value from about 2-20, and Z is selected from the group consisting of (i) a hydrogen atom; (ii) an alkyl radical having from 1-6 carbon atoms; (iii) a polyether radical of the formula ##STR18## where b has a value from about 5-150, and a+c has a value from about 2-20; (iv) an alkylene polyether radical of the formula ##STR19## where R 1 is an alkylene radical having from about 1-6 carbon atoms, b has a value from about 5-150, and a+c has a value from about 2-20; and (v) a radical of the formula R.sub.2 (NH--R.sub.3).sub.x -- where R 2 is an alkyl radical having from about 1-24 carbon atoms, R 3 is an alkylene radical having from about 1-6 carbon atoms, and x has a value from about 1-10; and (c) 1-2 moles of a hydrocarbyl polyamine of the formula R.sub.2 (NH--R.sub.3).sub.x --NH.sub.2 where R 2 is a alkyl radical having from about 1-24 carbon atoms, R 3 is an alkylene radical having from about 1-6 carbon atoms, and x has a value from about 1-10; and (II) from about 0.01-1.0 volume percent, based on the total volume of the motor fuel composition, of a polyolefin polymer, copolymer, or the corresponding hydrogenated polymer or copolymer, or mixtures thereof, of a C 2 -C 6 unsaturated hydrocarbon, said polyolefin polymer or copolymer having a molecular weight in the range from about 500-3500.
Claim 3
Dependent Claim 226 words
A motor fuel composition according to claim 1, in which said reaction product component is obtained by reacting: (a) 1 mole of maleic anhydride; (b) about 1.5 moles of a polyether polyamine represented by the formula: ##STR20## where b has a value from about 8-50, a+c has a value from about 2.5-10, and Z is selected from the group consisting of (i) a hydrogen atom; (ii) an alkyl radical having from 1-6 carbon atoms; (iii) a polyether radical of the formula ##STR21## where b has a value from about 8-50, and a+c has a value from about 2.5-10; (iv) an alkylene polyether radical of the formula ##STR22## where R 1 is an alkylene radical having from about 1-3 carbon atoms, b has a value from about 8-50, and a+c has a value from about 2.5-10; and (v) a radical of the formula R.sub.2 (NH--R.sub.3).sub.x -- where R 2 is an alkyl radical having from about 12-20 carbon atoms, R 3 is an alkylene radical having from about 1-6 carbon atoms, and x has a value from about 1-5; and (c) about 1 mole of a hydrocarbyl polyamine of the formula R.sub.2 (NH--R.sub.3).sub.x --NH.sub.2 where R 2 is a alkyl radical having from about 12-20 carbon atoms, R 3 is an alkylene radical having from about 1-6 carbon atoms, and x has a value from about 1-5.
Claim 4
Dependent Claim 101 words
A motor fuel composition according to claim 1, in which said reaction product component is obtained by reacting: (a) 1 mole of maleic anhydride; (b) 1-2 moles of a polyether polyamine, where said polyether polyamine is a polyether diamine of the formula ##STR23## where b has a value from about 5-150 and a+c has a value from about 2-20; and (c) 1-2 moles of a hydrocarbyl polyamine, where said hydrocarbyl polyamine is a n-alkyl-alkylene diamine of the formula R--NH--(CH.sub.2).sub.n --NH.sub.2 where R is an aliphatic hydrocarbon radical having from about 8-24 carbon atoms and n has a value from about 1-5.
Claim 5
Dependent Claim 40 words
A motor fuel composition according to claim 3, in which said reaction product component is obtained by reacting 1 mole of said maleic anhydride with about 1.5 moles of said polyether diamine and about 1 mole of said n-alkyl-alkylene diamine.
Claim 6
Dependent Claim 47 words
A motor fuel composition according to claim 3, where b has a value from about 8 to 50, a+c has a value from about 2.5 to 10, n is equal to 3, and R is an aliphatic hydrocarbon radical having from about 12 to 20 carbon atoms.
Claim 7
Dependent Claim 24 words
A motor fuel composition according to claim 3, where said n-alkyl-alkylene diamine is selected from the group consisting of: n-coco-1,3-diaminopropane; n-soya-1,3-diaminopropane; n-tallow-1,3-diaminopropane; and n-oleyl-1,3-diaminopropane.
Claim 8
Dependent Claim 38 words
A motor fuel composition according to claim 1, in which said polyolefin polymer or copolymer component is derived from an unsaturated hydrocarbon selected from the group consisting of ethylene, propylene, isopropylene, butylene, isobutylene, amylene, hexylene, isoprene, and butadiene.
Claim 9
Dependent Claim 31 words
A motor fuel composition according to claim 1, in which said polyolefin polymer, copolymer, or corresponding hydrogenated polymer or copolymer component has a molecular weight in the range of about 650-2600.
Claim 10
Dependent Claim 27 words
A motor fuel composition according to claim 8, in which said polyolefin polymer component is a polypropylene having a molecular weight in the range of about 750-1000.
Claim 11
Dependent Claim 24 words
A motor fuel composition according to claim 9, where said polyolefin polymer component is a polypropylene with an average molecular weight of about 800.
Claim 12
Dependent Claim 27 words
A motor fuel composition according to claim 8, in which said polyolefin polymer component is a polyisobutylene having a molecular weight in the range of about 1000-1500.
Claim 13
Dependent Claim 23 words
A composition according to claim 11, in which said polyolefin polymer component is a polyisobutylene having an average molcular weight of about 1300.
Claim 14
Dependent Claim 21 words
A motor fuel composition according to claim 1, containing from about 0.001 to 0.10 weight percent of said reaction product component.
Claim 15
Dependent Claim 21 words
A motor fuel composition according to claim 1, containing from about 0.01 to 0.05 weight percent of said reaction product component.
Claim 16
Dependent Claim 23 words
A motor fuel composition according to claim 1, containing from about 0.05 to 0.15 volume percent of said polyolefin polymer or copolymer component.
Claim 17
Dependent Claim 23 words
A motor fuel composition according to claim 1, containing from about 0.05 to 0.10 volume percent of said polyolefin polymer or copolymer component.
Claim 18
Dependent Claim 24 words
A concentrate composition comprising 1.0-75.0 total weight percent of a mixture of the reaction product and polyolefin polymer or copolymer components of claim 1.
Claim 19
Dependent Claim 30 words
A concentrate composition according to claim 17, where said mixture of reaction product and polyolefin polymer or copolymer components is present in a concentration range of 5.0-35.0 total weight percent.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-04-20 1990-10-20 1991-04-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-04-20 1994-10-20 1995-04-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-04-20 1998-10-20 1999-04-21 $7700.00 Window Closed / Lapsed

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