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US4657973A Expired / Lapsed US ⏱️ 0.0 years remaining

Polycarbonate resin composition

Assignee: Idemitsu Kosan Co Ltd
•
Filing: 1986-01-08
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Granted: 1987-04-14
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Expires: 2006-01-08
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Abstract

Abstract Polycarbonate resin compositions are disclosed, comprising: (1) (A) a polycarbonate resin and (B) polyesterether elastomer, said elastomer composing of a bifunctional carboxylic acid component and a glycol component comprising polyalkylene glycol and ethylene glycol, or (2) the components (A) and (B), and (C) a rubber-like elastomer, or (3) the components (A) and (B), and (D) a polyester resin, or (4) the components (A), (B), (C) and (D). These compositions are excellent in solvent resistance and so forth, and further possess excellent physical and thermal properties characteristic of a polycarbonate resin. Thus the compositions are useful for use in production of industrial and electrical articles, such as a car bumper in the field of car industry.

Inventors

  • 👤 Hideki Endo
  • 👤 Kazuto Hashimoto
  • 👤 Kenji Tanaka
  • 👤 Takeshi Matsumoto
  • 👤 Keishiro Igi
  • 👤 Takayuki Okamura
  • 👤 Shunro Taniguchi
  • 👤 Masao Ishii
  • 👤 Yoshifumi Murata
  • 👤 Shinichi Yokota

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 12:00
CPC Classifications
C; C08; C08L; C08L69/00; C08L67/00; C08L67/02; C08L67/025

Claims Analysis

Total Claims: 28
Claim 1
Independent Claim 74 words
A polycarbonate resin composition comprising: (A) 92 to 10 wt % of a polycarbonate resin; and (B) 8 to 90 wt % of a polyesterether elastomer, said polyesterether elastomer consisting essentially of 40 to 75 wt % of a bifunctional carboxylic acid component and 60 to 25 wt % of a glycol component, said glycol component comprising 1 to 65 wt % of polyethylene glycol and 99 to 35 wt % of ethylene glycol.
Claim 2
Dependent Claim 74 words
A polycarbonate resin composition comprising: (A) 92 to 10 wt % of a polycarbonate resin; and (B) 8 to 90 wt % of a polyesterether elastomer, said polyesterether elastomer consisting essentially of 40 to 75 wt % of a bifunctional carboxylic acid component and 60 to 25 wt % of a glycol component, said glycol component comprising 1 to 65 wt % of polyethylene glycol and 99 to 35 wt % of ethylene glycol.
Claim 3
Dependent Claim 23 words
The composition as claimed in claim 1, wherein the polycarbonate resin (A) has a viscosity average molecular weight of from 10,000 to 100,000.
Claim 4
Dependent Claim 22 words
The composition as claimed in claim 1, wherein the polyesterether elastomer (B) has an inherent viscosity of from 0.4 to 1.5 dl/g.
Claim 5
Dependent Claim 18 words
The composition as claimed in claim 1, wherein the bifunctional carboxylic acid component is an aromatic dicarboxylic acid.
Claim 6
Dependent Claim 84 words
A polycarbonate resin composition comprising: (A) 30 to 90 wt % of a polycarbonate resin; (B) 4 to 45 wt % of a polyesterether elastomer, said polyesterether elastomer consisting essentially of 40 to 75 wt % of a bifunctional carboxylic acid component and 60 to 25 wt % of a glycol component, said glycol component comprising 1 to 65 wt % of polyethylene glycol and 99 to 35 wt % of ethylene glycol; and (C) 1 to 25 wt % of a rubber-like elastomer.
Claim 7
Dependent Claim 84 words
A polycarbonate resin composition comprising: (A) 30 to 90 wt % of a polycarbonate resin; (B) 4 to 45 wt % of a polyesterether elastomer, said polyesterether elastomer consisting essentially of 40 to 75 wt % of a bifunctional carboxylic acid component and 60 to 25 wt % of a glycol component, said glycol component comprising 1 to 65 wt % of polyethylene glycol and 99 to 35 wt % of ethylene glycol; and (C) 1 to 25 wt % of a rubber-like elastomer.
Claim 8
Dependent Claim 23 words
The composition as claimed in claim 5, wherein the polycarbonate resin (A) has a viscosity average molecular weight of from 10,000 to 100,000.
Claim 9
Dependent Claim 22 words
The composition as claimed in claim 5, wherein the polyesterether elastomer (B) has an inherent viscosity of from 0.4 to 1.5 dl/g.
Claim 10
Dependent Claim 18 words
The composition as claimed in claim 5, wherein the bifunctional carboxylic acid component is an aromatic dicarboxylic acid.
Claim 11
Dependent Claim 42 words
The composition as claimed in claim 5, wherein the rubber-like elastomer (C) is at least one elastomer selected from the group consisting of MAS resinous elastomer, MS resinous elastomer, MABS resinous elastomer, MBS resinous elastomer, ABS resinous elastomer and AABS resinous elastomer.
Claim 12
Dependent Claim 84 words
A polycarbonate resin composition comprising: (A) 30 to 90 wt % of a polycarbonate resin; (B) 4 to 45 wt % of a polyesterether elastomer, said polyesterether elastomer consisting essentially of 40 to 75 wt % of a bifunctional carboxylic acid component and 60 to 25 wt % of a glycol component, said glycol component comprising 1 to 65 wt % of polyethylene glycol and 99 to 35 wt % of ethylene glycol; and (D) 2 to 40 wt % of a polyester resin.
Claim 13
Dependent Claim 84 words
A polycarbonate resin composition comprising: (A) 30 to 90 wt % of a polycarbonate resin; (B) 4 to 45 wt % of a polyesterether elastomer, said polyesterether elastomer consisting essentially of 40 to 75 wt % of a bifunctional carboxylic acid component and 60 to 25 wt % of a glycol component, said glycol component comprising 1 to 65 wt % of polyethylene glycol and 99 to 35 wt % of ethylene glycol; and (D) 2 to 40 wt % of a polyester resin.
Claim 14
Dependent Claim 23 words
The composition as claimed in claim 10, wherein the polycarbonate resin (A) has a viscosity average molecular weight of from 10,000 to 100,000.
Claim 15
Dependent Claim 22 words
The composition as claimed in claim 10, wherein the polyesterether elastomer (B) has an inherent viscosity of from 0.4 to 1.5 dl/g.
Claim 16
Dependent Claim 18 words
The composition as claimed in claim 10, wherein the bifunctional carboxylic acid component is an aromatic dicarboxylic acid.
Claim 17
Dependent Claim 15 words
The composition as claimed in claim 10, wherein the polyester resin (D) is polyethylene terephthalate.
Claim 18
Dependent Claim 94 words
A polycarbonate resin composition comprising: (A) 30 to 90 wt % of a polycarbonate resin; (B) 8 to 45 wt % of a polyesterether elastomer, said polyesterether elastomer consisting essentially of 40 to 75 wt % of a bifunctional carboxylic acid component and 60 to 25 wt % of a glycol component, said glycol component comprising 1 to 65 wt % of polyethylene glycol and 99 to 35 wt % of ethylene glycol; (C) 1 to 25 wt % of a rubber-like elastomer; and (D) 2 to 40 wt % of a polyester resin.
Claim 19
Dependent Claim 94 words
A polycarbonate resin composition comprising: (A) 30 to 90 wt % of a polycarbonate resin; (B) 8 to 45 wt % of a polyesterether elastomer, said polyesterether elastomer consisting essentially of 40 to 75 wt % of a bifunctional carboxylic acid component and 60 to 25 wt % of a glycol component, said glycol component comprising 1 to 65 wt % of polyethylene glycol and 99 to 35 wt % of ethylene glycol; (C) 1 to 25 wt % of a rubber-like elastomer; and (D) 2 to 40 wt % of a polyester resin.
Claim 20
Dependent Claim 23 words
The composition as claimed in claim 15, wherein the polycarbonate resin (A) has a viscosity average molecular weight of from 10,000 to 100,000.
Claim 21
Dependent Claim 22 words
The composition as claimed in claim 15, wherein the polyesterether elastomer (B) has an inherent viscosity of from 0.4 to 1.5 dl/g.
Claim 22
Dependent Claim 18 words
The composition as claimed in claim 15, wherein the bifunctional carboxylic acid component is an aromatic dicarboxylic acid.
Claim 23
Dependent Claim 42 words
The composition as claimed in claim 15, wherein the rubber-like elastomer (C) is at least one elastomer selected from the group consisting of MAS resinous elastomer, MS resinous elastomer, MABS resinous elastomer, MBS resinous elastomer, ABS resinous elastomer and AABS resinous elastomer.
Claim 24
Dependent Claim 15 words
The composition as claimed in claim 15, wherein the polyester resin (D) is polyethylene terephthalate.
Claim 25
Dependent Claim 99 words
The composition as claimed in claim 1 wherein (A) 90 to 30 wt % of a polycarbonate resin having a viscosity average molecular weight of from 20,000 to 40,000; and (B) 10 to 70 wt % of a polyesterether elastomer having an inherent viscosity of from 0.5 to 1.2 dl/g, said polyesterether elastomer consisting essentially of 50 to 70 wt % of a bifunctional aromatic carboxylic acid component and 50 to 30 wt % of a glycol component, said glycol component comprising 20 to 60 wt % of polyethylene glycol and 80 to 40 wt % of ethylene glycol.
Claim 26
Dependent Claim 134 words
The composition as claimed in claim 5, wherein (A) 40 to 70 wt % of a polycarbonate resin having a viscosity average molecular weight of from 20,000 to 40,000; (B) 8 to 42 wt % of a polyesterether elastomer having an inherent viscosity of from 0.5 to 1.2 dl/g, said polyesterether elastomer consisting essentially of 50 to 70 wt % of a bifunctional aromatic carboxylic acid component and 50 to 30 wt % of a glycol component, said glycol component comprising 20 to 60 wt % of polyethylene glycol and 80 to 40 wt % of ethylene glycol; and (C) 5 to 20 wt % of a rubber-like elastomer selected from the group consisting of MAS resinous elastomer, MS resinous elastomer, MABS resinous elastomer, MBS resinous elastomer, ABS resinous elastomer and AAABS resinous elastomer.
Claim 27
Dependent Claim 110 words
The composition as claimed in claim 10, wherein (A) 40 to 70 wt % of a polycarbonate resin having a viscosity average molecular weight of from 20,000 to 40,000; (B) 8 to 42 wt % of a polyesterether elastomer having an inherent viscosity of from 0.5 to 1.2 dl/g, said polyesterether elastomer consisting essentially of 50 to 70 wt % of a bifunctional aromatic carboxylic acid component and 50 to 30 wt % of a glycol component, said glycol component comprising 20 to 60 wt % of polyethylene glycol and 80 to 40 wt % of ethylene glycol; and (D) 3 to 30 wt % of a polyethylene terephthalate resin.
Claim 28
Dependent Claim 145 words
The composition as claimed in claim 15, wherein (A) 40 to 70 wt % of a polycarbonate resin having a viscosity average molecular weight of from 20,000 to 40,000; (B) 8 to 42 wt % of a polyesterether elastomer having an inherent viscosity of from 0.5 to 1.2 dl/g, said polyesterether elastomer consisting essentially of 50 to 70 wt % of a bifunctional aromatic carboxylic acid component and 50 to 30 wt % of a glycol component, said glycol component comprising 20 to 60 wt % of polyethylene glycol and 80 to 40 wt % of ethylene glycol; (C) 5 to 20 wt % of a rubber-like elastomer selected from the group consisting of MAS resinous elastomer, MS resinous elastomer, MABS resinous elastomer, MBS resinous elastomer, ABS resinous elastomer and AAABS resinous elastomer; and (D) 3 to 30 wt % of a polyethylene terephthalate resin.

References Cited (Backward Citations)

US3957905A Cited
JPS5397049A Cited
US4212791A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-04-13 1990-10-13 1991-04-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-04-13 1994-10-13 1995-04-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-04-13 1998-10-13 1999-04-14 $7700.00 Window Closed / Lapsed

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