Photopolymerizable composition

Claim 2

A photopolymerizable composition comprising an addition polymerizable compound having at least two ethylenically unsaturated bonds in the molecule, at least one photopolymerization initiator and at least one of 2-mercapto-5-substituted thiadiazole compounds represented by formulae (I) and (II) ##STR9## wherein R represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted alkylthio group, or a substituted or unsubstituted aralkylthio group; and R' represents a substituted or unsubstituted alkylene group.

Claim 3

A photopolymerizable composition as in claim 1, wherein said photopolymerization initiator is selected from compounds represented by formula (IIIa) ##STR10## wherein X 1 and X 2 each represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms, an alkoxycarboxyl group having from 1 to 6 carbon atoms, an alkoxycarbonyl group having from 1 to 6 carbon atoms, an alkyldisubstituted amino group having from 1 to 6 carbon atoms, or a halogen atom; and Y 1 represents a single chemical bond or ##STR11## wherein R 1 represents a hydrogen atom or OR 2 ; and R 2 represents a hydrogen atom or an alkyl group having from 1 to 6 carbon atoms; compounds respresented by formula (IIIb) ##STR12## wherein X 3 , X 4 , X 5 , and X 6 each represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms, an alkoxy group having from 1 to 6 carbon atoms, a carboxyl group, an alkoxycarbonyl group having from 1 to 6 carbon atoms, an aryloxycarbonyl group having from 6 to 12 carbon atoms, or a halogen atom; Y 2 represents a single chemical bond, an oxygen atom, a sulfur atom, an amino group, an amino group substituted with an alkyl group having from 1 to 6 carbon atoms or a carbonyl group; compounds represented by formula (IIIc) ##STR13## wherein R 3 represents an alkyl group having from 1 to 6 carbon atoms, an alkoxy group having from 1 to 6 carbon atoms, a cyano group, a halogen atom, a phenyl group, a phenyl group substituted with a methylenedioxy group, a naphthyl group, a styryl group, or a styrylphenyl group; and Z represents a halogen atom; compounds represented by formula (IIId) ##STR14## wherein R 4 and Z have the same meanings as defined for R 3 and Z in formula (IIIc), respectively; and compounds represented by formula (IIIe) R.sup.5 --SO.sub.2 CZ.sub.3 (IIIe) wherein R 5 represents an alkyl group having from 1 to 6 carbon atoms, an alkoxy group having from 1 to 6 carbon atoms, a halogen atom, a phenyl group, a phenyl group substituted with a cyano group, or a naphthyl group; and Z is as defined above.

Claim 4

A photopolymerizable composition as in claim 1, wherein said polymerization initiator is present in a total amount of from 0.1 to 100 parts by weight per 100 parts by weight of addition polymerizable compound.

Claim 5

A photopolymerizable composition as in claim 3, wherein said polymerization initiator is present in a total amount of from 1 to 50 parts by weight per 100 parts by weight of addition polymerizable compound.

Claim 6

A photopolymerizable composition as in claim 1, wherein said 2-mercapto-5-substituted thiadiazole compound is present in a total amount of from 0.01 to 100 parts by weight per 100 parts by weight of addition polymerizable compound.

Claim 7

A photopolymerizable composition as in claim 5, wherein said 2-mercapto-5-substituted thiadiazole compound is present in a total amount of from 0.1 to 50 parts by weight per 100 parts by weight of addition polymerizable compound.

Claim 8

A photopolymerizable composition as in claim 2, wherein said polymerization initiator is present in a total amount of from 0.1 to 100 parts by weight per 100 parts by weight of addition polymerizable compound.

Claim 9

A photopolymerizable composition as in claim 7, wherein said polymerization initiator is present in a total amount of from 1 to 50 parts by weight per 100 parts by weight of addition polymerizable compound.

Claim 10

A photopolymerizable composition as in claim 2, wherein said 2-mercapto-5-substituted thiadiazole compound is present in a total amount of from 0.01 to 100 parts by weight per 100 parts by weight of addition polymerizable compound.

Claim 11

A photopolymerizable composition as in claim 9, wherein said 2-mercapto-5-substituted thiadiazole compound is present in a total amount of from 0.1 to 50 parts by weight per 100 parts by weight of addition polymerizable compound.

Claim 12

A photopolymerizable composition as in claim 3, wherein said 2-mercapto-5-substituted thiadiazole compound is present in a total amount of from 0.01 to 100 parts by weight per 100 parts by weight of addition polymerizable compound.

Claim 13

A photopolymerizable composition as in claim 4, wherein said 2-mercapto-5-substituted thiadiazole compound is present in a total amount of from 0.1 to 50 parts by weight per 100 parts by weight of addition polymerizable compound.

Claim 14

A photopolymerizable composition as in claim 1, wherein said composition further comprises one or more members selected from the group consisting of a polymeric binder, a heat polymerization inhibitor, a plasticizer, a dye, a color changing agent, a monofunctional ethylenically unsaturated compound, and an adhesion accelerator.

Claim 15

A photopolymerizable composition as in claim 11, wherein said composition further comprises one or more members selected from the group consisting of a polymeric binder in an amount up to 10,000 parts by weight, a heat polymerization inhibitor in an amount up to 50 parts by weight, a plasticizer in an amount up to 1,000 parts by weight, a dye in an amount up to 100 parts by weight, a color changing agent in an amount up to 100 parts by weight, a monofunctional ethylenically unsaturated compound in an amount up to 1,000 parts by weight, and an adhesion accelerator in an amount up to 50 parts by weight, per 100 parts by weight of addition polymerizable compound.

Claim 16

A photopolymerizable composition as in claim 12, wherein said composition further comprises one or more members selected from the group consisting of a polymeric binder in an amount up to 1,000 parts by weight, a heat polymerization inhibitor in an amount up to 20 parts by weight, a plasticizer in an amount up to 100 parts by weight, a dye in an amount up to 50 parts by weight, a color changing agent in an amount up to 100 parts by weight, a monofunctional ethylenically unsaturated compound in an amount up to 100 parts by weight, and an adhesion accelerator in an amount up to 20 parts by weight, per 100 parts by weight of addition polymerizable compound.

Claim 17

A photopolymerizable composition as in claim 1, wherein R represents an alkyl group substituted with a hydroxyl group or a dialkylamino group, an aralkyl group substituted with a hydroxyl group or a dialkylamino group, an alkylthio group substituted with a hydroxyl group or a dialkylamino gorup, or an aralkylthio group substituted with a hydroxyl group or a dialkylamino group.

Claim 18

A photopolymerizable composition as in claim 1, wherein R represents an alkyl group having from 1 to 12 carbon atoms, an aralkyl group having from 7 to 18 carbon atoms, an alkylthio group having from 1 to 12 carbon atoms, or an aralkylthio group having from 7 to 18 carbon atoms.