Fusible fiber/microfine fiber laminate

Claim 2

A water-impervious, smooth-surfaced, gas-permeable, bacterial barrier, laminated material comprising at least one layer of conjugate fibers, said layer of conjugate fibers having a first face and an opposite face, said conjugate fibers being composed of a lower melting component and a higher melting component, wherein a substantial proportion of the surfaces of said conjugate fibers comprises said lower melting component, said lower melting component of said conjugate fibers which lie on said first face being fuse bonded to at least one compatible hydrophobic ply of theremoplastic microfine fibers having a fiber diameter of up to 50 microns, said lower melting component of said conjugate fibers having been fuse bonded at a temperature below the melt temperature of said higher melting component of said conjugate fibers so that the latter component retains its initial fiber-like integrity, said material having been treated with a water repellent finish and impregnated with a repellent binder.

Claim 3

The material of claim 1, said material being highly compacted and also resistant to delamination, and to steam sterilization.

Claim 4

The material of claim 1, in which the ply of hydrophobic microfine fibers comprises ethylene/vinyl acetate copolymer.

Claim 5

The material of claim 1, wherein the conjugate fiber is a polyethylene/polyester sheath/core bi-component fiber.

Claim 6

The material of claim 1, wherein the conjugate fiber is a polypropylene/polyester sheath/core bi-component fiber.

Claim 7

The material of claim 1, in which the ply of hydrophobic microfine fibers is selected from the group consisting of ethylene/vinyl acetate copolymer, polyethylene, chlorinated polyethylene, polyvinyl chloride, and polypropylene.

Claim 8

The material of claim 1, wherein the ply of hydrophobic microfine fibers comprises polypropylene.

Claim 9

The material of claim 1, comprising two plies of hydrophobic microfine fibers which were initially prepared by melt-blowing, each ply having been extruded from one die only.

Claim 10

The material of claim 1, said material having been calendered between smooth heated rolls, direct heat having been applied to both outer surfaces of said material so that said surfaces are regular and the material has good strength properties.

Claim 11

The material of claim 1, wherein said material has been bonded by means of smooth heated calenders, said conjugate fibers having been initially oriented.

Claim 12

A sterile packaging barrier comprising the material of claim 1, said opposite face of said conjugate fibers being highly printable, said microfine fiber ply being compatible with seal coat systems that are required for heat sealing said ply to a formed polymer blister.

Claim 13

The material of claim 1 in which said layer of conjugate fibers is blended with non-conjugate fusible fibers, with the proviso that said first face of said layer of conjugate fibers contains a plurality of conjugate fibers in said blend.

Claim 14

A sterile package comprising a polymer blister sealed with the laminated material of claim 1.

Claim 15

A sterile package comprising a sealed envelope consisting of the laminated material of claim 1.

Claim 16

The material of claim 1 in which said water repellent finish comprises at least about 0.05% by weight of the untreated material.

Claim 17

The material of claim 2 in which said water repellent finish comprises between about 0.05% and 5% by weight of the untreated material.

Claim 18

The material of claim 2 in which said water repellent finish is selected from the group consisting of wax emulsions, polyurethane emulsions, silicones and fluorochemicals.

Claim 19

The material of claim 2, in which said repellent binder comprises at least 1% by weight of the unimpregnated material.

Claim 20

The material of claim 2, in which said repellent binder comprises between about 1% and 25% by weight of the unimpregnated material.

Claim 21

The material of claim 2, in which said water repellent finish comprises a fluorochemical.

Claim 22

The material of claim 2, in which said repellent binder is selected from the group consiting of polybutyl acrylate, styrene-acrylic copolymer, acrylic vinyl chloride copolymer, ethylene-acrylic acid copolymer, ethylene-vinyl acetate copolymer, ethylene-vinyl chloride copolymer, acrylic copolymer latex, styrene-butadiene latex and vinyl chloride latex.

Claim 23

The material of claim 21 in which said repellent binder comprises ethylene-acrylic acid copolymer.

Claim 24

A water-impervious, smooth-surfaced, gas-permeable, bacterial barrier, laminated material comprising at least one inner hydrophobic microfine fiber ply sandwiched between two layers of conjugate fibers, each of said layers of conjugate fibers having a first face and an opposite face, said conjugate fibers being composed of a lower melting component which is compatible with said microfine fibers, and a higher melting component, wherein a substantial proportion of the surfaces of said fibers coprises said lower melting component, said hydrophobic microfine fibers having a fiber diameter of up to 50 microns, said lower melting components of both layers of said conjugate fibers which lie on said first faces having been fuse bonded to opposite sides of said hydrophobic microfine fiber ply at a temperature below the melt temperature of said higher melting component of said conjugate fibers, so that the latter component retains its initial fiber-like integrity, said material having been treated with a water repellent finish and impregnated with a repellent binder.

Claim 25

A water-impervious, smooth-surfaced, gas-permeable, bacterial barrier, laminated material comprising at least one inner hydrophobic microfine fiber ply sandwiched between two layers of conjugate fibers, each of said layers of conjugate fibers having a first face and an opposite face, said conjugate fibers being composed of a lower melting component which is compatible with said microfine fibers, and a higher melting component, wherein a substantial proportion of the surfaces of said fibers coprises said lower melting component, said hydrophobic microfine fibers having a fiber diameter of up to 50 microns, said lower melting components of both layers of said conjugate fibers which lie on said first faces having been fuse bonded to opposite sides of said hydrophobic microfine fiber ply at a temperature below the melt temperature of said higher melting component of said conjugate fibers, so that the latter component retains its initial fiber-like integrity, said material having been treated with a water repellent finish and impregnated with a repellent binder.

Claim 26

The material of claim 23, said material having been highly compacted and also resistant to delamination and steam sterilization.

Claim 27

The material of claim 23, wherein the ply of hydrophobic microfine fibers is selected from the group consisting of ethylene/vinyl acetate copolymer, polyethylene, polypropylene, chlorinated polyethylene and polyvinyl chloride.

Claim 28

A process for preparing a water-impervious, smooth-surfaced, gas-permeable, bacterial barrier, laminated material comprising at least one layer of conjugate fibers, said layer of conjugate fibers having a first face and an opposite face, said conjugate fibers being composed of a lower melting component and a higher melting component, wherein a substantial proportion of the surfaces of said conjugate fibers comprises said lower melting component, said lower melting component of said conjugate fibers which lie on said first face being fuse bonded to at least one hydrophobic ply of microfine fibers having a fiber diameter of up to 50 microns, said lower melting component of said conjugate fibers having been fuse bonded at a temperature below the melt temperature of said higher melting component of said conjugate fibers so that the latter component retains its initial fiber-like integrity, said material being resistant to steam sterilization; said process comprising forming an assembly of said ply of hydrophobic microfine fibers and at least one layer of said conjugate fibers placed adjacent to said ply of said hydrophobic microfine fibers; subjecting said assembly to smooth calendering at a temperature sufficient to fuse said lower melting component of said conjugate fibers which lie on said first face as well as the ply of the hydrophobic microfine fibers without fusing the higher melting component of said conjugate fibers, direct heat being applied to both outer surfaces of said assembly so that said surfaces are regular and the resultant material has good strength properties; cooling said assembly to resolidify said lower melting component of the conjugate fibers as well as said ply of said hydrophobic microfine fibers, whereby said conjugate fibers are firmly bonded to said hydrophobic microfine fiber structure without impairing the integrity of said higher melting component of said fibers and treating said resultant laminated material with a water repellent finish and a repellent binder, or utilizing a layer of conjugate fibers which has been pretreated with a water repellent finish and a repellent binder, before forming said assembly of said ply of microfine fibers and said layer of conjugate fibers.

Claim 29

A process for preparing a water-impervious, smooth-surfaced, gas-permeable, bacterial barrier, laminated material comprising at least one layer of conjugate fibers, said layer of conjugate fibers having a first face and an opposite face, said conjugate fibers being composed of a lower melting component and a higher melting component, wherein a substantial proportion of the surfaces of said conjugate fibers comprises said lower melting component, said lower melting component of said conjugate fibers which lie on said first face being fuse bonded to at least one hydrophobic ply of microfine fibers having a fiber diameter of up to 50 microns, said lower melting component of said conjugate fibers having been fuse bonded at a temperature below the melt temperature of said higher melting component of said conjugate fibers so that the latter component retains its initial fiber-like integrity, said material being resistant to steam sterilization; said process comprising forming an assembly of said ply of hydrophobic microfine fibers and at least one layer of said conjugate fibers placed adjacent to said ply of said hydrophobic microfine fibers; subjecting said assembly to smooth calendering at a temperature sufficient to fuse said lower melting component of said conjugate fibers which lie on said first face as well as the ply of the hydrophobic microfine fibers without fusing the higher melting component of said conjugate fibers, direct heat being applied to both outer surfaces of said assembly so that said surfaces are regular and the resultant material has good strength properties; cooling said assembly to resolidify said lower melting component of the conjugate fibers as well as said ply of said hydrophobic microfine fibers, whereby said conjugate fibers are firmly bonded to said hydrophobic microfine fiber structure without impairing the integrity of said higher melting component of said fibers and treating said resultant laminated material with a water repellent finish and a repellent binder, or utilizing a layer of conjugate fibers which has been pretreated with a water repellent finish and a repellent binder, before forming said assembly of said ply of microfine fibers and said layer of conjugate fibers.

Claim 30

The process of claim 26, in which said assembly is initially formed by passing a prebonded layer of said conjugate fibers beneath a melt blown dye whch deposits said ply of microfine fibers on the surface of said layer of conjugate fibers.

Claim 31

The process of claim 26 in which the layer of conjugate fibers is initially unbonded and said ply of microfine fibers is formed separately before being assembled with said layer of conjugate fibers.

Claim 32

A process for preparing a water-impervious, smooth-surfaced, gas-permeable, bacterial barrier, lamined material comprising at least one inner ply of hydrophobic microfine fibers sandwiched between two layers of conjugate fibers, each of said layers of conjugate fibers having a first face and an opposite face, said conjugate fibers being composed of a lower melting component and a higher melting component, wherein a substantial proportion of the surfaces of said fibers comprise said lower melting component, said ply of hydrophobic microfine fibers having a fiber diameter of up to 50 microns, said lower melting components of both layers of said conjugate fibers which lie on said first faces having been fuse bonded to said ply of hydrophobic microfine fibers at a temperature below the melt temperature of said higher melting component of said conjugate fibers, so that the latter component retains its initial fiber-like integrity, said material being resistant to steam sterilization; said process comprising forming an assembly of said ply of hydrophobic microfine fibers sandwiched between two layers of said conjugate fibers, subjecting said assembly to smooth calendering at a temperature sufficient to fuse said lower melting components of said conjugate fibers which lie on said first faces in both of said layers thereof as well as said ply of said hydrophobic microfine fibers without fusing the higher melting components of said conjugate fibers, direct heat being applied to both outer surfaces of said assembly so that said surfaces are regular and the resultant material has good strength properties; cooling said assembly to resolidify said lower melting components of the fibers as well as said ply of hydrophobic microfine fibers, whereby said fibers are firmly bonded to said hydrophobic microfine fibers without impairing the integrity of said higher melting component of said fibers, and treating said resultant laminated material with a water repellent finish and a repellent binder, or utilizing layers of conjugate fibers which have been pretreated with a repellent before forming said assembly of said ply of microfine fibers and said two layers of conjugate fibers.

Claim 33

A process for preparing a water-impervious, smooth-surfaced, gas-permeable, bacterial barrier, lamined material comprising at least one inner ply of hydrophobic microfine fibers sandwiched between two layers of conjugate fibers, each of said layers of conjugate fibers having a first face and an opposite face, said conjugate fibers being composed of a lower melting component and a higher melting component, wherein a substantial proportion of the surfaces of said fibers comprise said lower melting component, said ply of hydrophobic microfine fibers having a fiber diameter of up to 50 microns, said lower melting components of both layers of said conjugate fibers which lie on said first faces having been fuse bonded to said ply of hydrophobic microfine fibers at a temperature below the melt temperature of said higher melting component of said conjugate fibers, so that the latter component retains its initial fiber-like integrity, said material being resistant to steam sterilization; said process comprising forming an assembly of said ply of hydrophobic microfine fibers sandwiched between two layers of said conjugate fibers, subjecting said assembly to smooth calendering at a temperature sufficient to fuse said lower melting components of said conjugate fibers which lie on said first faces in both of said layers thereof as well as said ply of said hydrophobic microfine fibers without fusing the higher melting components of said conjugate fibers, direct heat being applied to both outer surfaces of said assembly so that said surfaces are regular and the resultant material has good strength properties; cooling said assembly to resolidify said lower melting components of the fibers as well as said ply of hydrophobic microfine fibers, whereby said fibers are firmly bonded to said hydrophobic microfine fibers without impairing the integrity of said higher melting component of said fibers, and treating said resultant laminated material with a water repellent finish and a repellent binder, or utilizing layers of conjugate fibers which have been pretreated with a repellent before forming said assembly of said ply of microfine fibers and said two layers of conjugate fibers.