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US4657665A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for demetallation and desulfurization of heavy hydrocarbons

Assignee: BP Corp North America Inc
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Filing: 1985-12-20
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Granted: 1987-04-14
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Expires: 2005-12-20
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Abstract

Abstract Disclosed is an improved ebullated bed process for the hydroconversion of heavy hydrocarbon feedstocks containing asphaltenes, metals, and sulfur compounds. The disclosed process is characterized by the use of a catalyst comprising a relatively small amount of cobalt, i.e., 0.4 to 0.8 wt. % incorporated with a high macropore volume Group VIB metal containing catalyst.

Inventors

  • 👤 William I. Beaton
  • 👤 Albert L. Hensley
  • 👤 April J. Evans

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 05:36
CPC Classifications
C; C10; C10G; C10G45/00; C10G45/02; C10G45/14; C10G45/16; B; B01; B01J; B01J23/00; B01J23/70; B01J23/76; B01J23/84; B01J23/85; B01J35/00; B01J35/60; B01J35/61; B01J35/615; B01J35/63; B01J35/633; B01J35/635; B01J35/66; C10G45/04; C10G45/06; C10G45/08

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 179 words
A process for the hydrodemetallation, hydrodesulfurization and hydrocracking of a hydrocarbon feedstock containing asphaltenes, metals, and Shell hot filtration solids precursors and the conversion of at least 30 vol.% of the feedstock fraction boiling over 1,000° F. to material boiling below 1,000° F. which comprises contacting said feedstock in at least one ebullated bed reaction zone with hydrogen and a hydrocracking catalyst comprising a Group VIB metal component and a cobalt component on a porous inorganic oxide support, wherein said Group VIB metal is present in an amount ranging from about 3.5 to about 5.0 wt.% calculated as an oxide and based on total catalyst weight, wherein said cobalt is present in an amount ranging from about 0.4 to about 0.8 wt.% calculated as an oxide and based on total catalyst weight, and wherein said catalyst has a surface area of about 150 to about 220 m 2 /gm, a total pore volume of about 0.85 to about 1.5 cc/gm, and a pore volume in pores having diameters larger than 1,200 Å of about 0.15 to about 0.4 cc/gm.
Claim 2
Dependent Claim 179 words
A process for the hydrodemetallation, hydrodesulfurization and hydrocracking of a hydrocarbon feedstock containing asphaltenes, metals, and Shell hot filtration solids precursors and the conversion of at least 30 vol.% of the feedstock fraction boiling over 1,000° F. to material boiling below 1,000° F. which comprises contacting said feedstock in at least one ebullated bed reaction zone with hydrogen and a hydrocracking catalyst comprising a Group VIB metal component and a cobalt component on a porous inorganic oxide support, wherein said Group VIB metal is present in an amount ranging from about 3.5 to about 5.0 wt.% calculated as an oxide and based on total catalyst weight, wherein said cobalt is present in an amount ranging from about 0.4 to about 0.8 wt.% calculated as an oxide and based on total catalyst weight, and wherein said catalyst has a surface area of about 150 to about 220 m 2 /gm, a total pore volume of about 0.85 to about 1.5 cc/gm, and a pore volume in pores having diameters larger than 1,200 Å of about 0.15 to about 0.4 cc/gm.
Claim 3
Dependent Claim 12 words
The process of claim 1 wherein said Group VIB metal is molybdenum.
Claim 4
Dependent Claim 55 words
The process of claim 1 wherein said catalyst has a surface area of about 170 to about 200 m 2 /gm, a total pore volume of about 1.0 to about 1.35 cc/gm, and wherein the pore volume of pores having a pore diameter greater than 1,200 Å ranges from about 0.2 to about 0.35 cc/gm.
Claim 5
Dependent Claim 30 words
The process of claim 1 wherein at least 70 vol.% of said fraction of the hydrocarbon feedstock boiling above 1,000° F. is converted to a material boiling below 1,000° F.
Claim 6
Dependent Claim 19 words
The process of claim 1 wherein the effluent therefore contains less then about 1.3 wt.% Shell hot filtration solids.

References Cited (Backward Citations)

US3981796A Cited
US4181602A Cited
US4306965A Cited
US4224114A Cited
US4328127A Cited
US4404097A Cited
US4434048A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-04-13 1990-10-13 1991-04-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-04-13 1994-10-13 1995-04-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-04-13 1998-10-13 1999-04-14 $7700.00 Window Closed / Lapsed

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