US4656238A — Soluble polyimide-siloxane precursor, process for…

Claim 1

Independent Claim 438 words

A soluble polyimide-siloxane precursor having an imide-amic acid chain part expressed by the formula (1) --R.sup.3 --(I)--R.sup.2 --(I)].sub.n R.sup.3 -- (1) bonded by a bonding structure expressed by the formula (5) --SiR.sup.4.sub.3-m Y.sup.1.sub.m-1 --O--SiR.sup.4.sub.3-m Y.sup.1.sub.m-1 -- (5) wherein said (I)s in the number of n+1 represent independently either one of constituting units expressed by the following formulas (2), (3) and (4): ##STR21## wherein R 1 represents a tetravalent carbocyclic aromatic group; R 2 represents an aliphatic group of 2 to 12 carbon atoms, an alicyclic group of 4 to 30 carbon atoms, an arylaliphatic group of 6 to 30 carbon atoms or a carbocyclic aryl group of 6 to 30 carbon atoms; R 3 s independently represent --CH 2 ) s --, ##STR22## wherein s represent an integer of 1 to 4; n is defined later; R 4 s independently represent an alkyl group of 1 to 6 carbon atoms, phenyl group or an alkyl-substituted phenyl group of 7 to 12 carbon atoms; Y 1 s independently represent an alkoxy group, acetoxy group, halogen atom, hydroxyl group, (--O--) 1/2 or a group expressed by the following formula (6) R.sup.5 R.sup.6 R.sup.7 Si--O-- (6) wherein R 5 , R 6 and R 7 independently represent an alkyl group of 1 to 6 carbon atoms, phenyl group or an alkyl-substituted phenyl group of 7 to 12 carbon atoms; and ms independently represent an integer of 1≦m≦3; said soluble polyimide-siloxane precursor further being terminated by a group expressed by the following formula (7): Y.sup.2.sub.m R.sup.4.sub.3-m Si-- (7) wherein Y 2 s independently represent an alkoxy group, acetoxy group, halogen atom, hydroxyl group or a group expressed by said formula (6); R 4 and m are as defined in said formula (5); and having a percentage imidization T of 50 to 100%, this T being defined in terms of the whole of the molecule by the following equation (8): ##EQU5## wherein W: the total number of constituting units expressed by said formula (2); P: the total number of constituting units expressed by said formula (3) and Q: the total number of constituting units expressed by said formula (4); and also having a relation expressed by the following expression (9): ##EQU6## wherein B 1 : the total number of R 2 s, and D 1 : the total number of R 3 s; and further having an inherent viscosity of 0.05 to 5 dl/g as measured in a concentration of 0.5 g/dl in N-methyl-2-pyrrolidone at a temperature of 30±0.01° C.; said n being an integer defined so as to give an inherent viscosity of said soluble polyimide-siloxane precursor of 0.05 to 5 dl/g.

Claim 2

Dependent Claim 438 words

A soluble polyimide-siloxane precursor having an imide-amic acid chain part expressed by the formula (1) --R.sup.3 --(I)--R.sup.2 --(I)].sub.n R.sup.3 -- (1) bonded by a bonding structure expressed by the formula (5) --SiR.sup.4.sub.3-m Y.sup.1.sub.m-1 --O--SiR.sup.4.sub.3-m Y.sup.1.sub.m-1 -- (5) wherein said (I)s in the number of n+1 represent independently either one of constituting units expressed by the following formulas (2), (3) and (4): ##STR21## wherein R 1 represents a tetravalent carbocyclic aromatic group; R 2 represents an aliphatic group of 2 to 12 carbon atoms, an alicyclic group of 4 to 30 carbon atoms, an arylaliphatic group of 6 to 30 carbon atoms or a carbocyclic aryl group of 6 to 30 carbon atoms; R 3 s independently represent --CH 2 ) s --, ##STR22## wherein s represent an integer of 1 to 4; n is defined later; R 4 s independently represent an alkyl group of 1 to 6 carbon atoms, phenyl group or an alkyl-substituted phenyl group of 7 to 12 carbon atoms; Y 1 s independently represent an alkoxy group, acetoxy group, halogen atom, hydroxyl group, (--O--) 1/2 or a group expressed by the following formula (6) R.sup.5 R.sup.6 R.sup.7 Si--O-- (6) wherein R 5 , R 6 and R 7 independently represent an alkyl group of 1 to 6 carbon atoms, phenyl group or an alkyl-substituted phenyl group of 7 to 12 carbon atoms; and ms independently represent an integer of 1≦m≦3; said soluble polyimide-siloxane precursor further being terminated by a group expressed by the following formula (7): Y.sup.2.sub.m R.sup.4.sub.3-m Si-- (7) wherein Y 2 s independently represent an alkoxy group, acetoxy group, halogen atom, hydroxyl group or a group expressed by said formula (6); R 4 and m are as defined in said formula (5); and having a percentage imidization T of 50 to 100%, this T being defined in terms of the whole of the molecule by the following equation (8): ##EQU5## wherein W: the total number of constituting units expressed by said formula (2); P: the total number of constituting units expressed by said formula (3) and Q: the total number of constituting units expressed by said formula (4); and also having a relation expressed by the following expression (9): ##EQU6## wherein B 1 : the total number of R 2 s, and D 1 : the total number of R 3 s; and further having an inherent viscosity of 0.05 to 5 dl/g as measured in a concentration of 0.5 g/dl in N-methyl-2-pyrrolidone at a temperature of 30±0.01° C.; said n being an integer defined so as to give an inherent viscosity of said soluble polyimide-siloxane precursor of 0.05 to 5 dl/g.

Claim 3

Dependent Claim 425 words

A process for producing a soluble polyimide-siloxane precursor, which comprises a first step of reacting A mols of a tetracarboxylic acid dianhydride expressed by the following formula (10), B 2 mols of a diamine expressed by the following formula (11) and D 2 mols of an aminosilicon compound expressed by the following formula (12), A, B 2 and D 2 satisfying the following expression (14) and also approximately satisfying the following equation (15), in the presence of a solvent at a temperature of 0° to 60° C. for a time of 0.2 to 6 hours to effect a uniform reaction; and a second step of heating the resulting reaction material in the presence of E mols of a silylating agent expressed by the following formula (13) in the range expressed by the following expression (16) at a temperature of 60° to 200° C. for a time of 0.5 to 30 hours to effect an imidization reaction, and hydrolyzing X 1 in said aminosilicon compound expressed by the formula (12) and X 2 in said silylating agent expressed by the formula (13), with water generated during said imidization reaction and if necessary, water from other sources, and further effecting siloxane condensation, to make the percentage imidization T of the resulting product defined by the following equation (17), 50 to 100%, and also make the inherent viscosity thereof as measured in N-methyl-2-pyrrolidone in a concentration of 0.5 g/dl at a temperature of 30±0.01° C., 0.05 to 5 dl/g: ##STR23## wherein R 1 represents a tetravalent carbocyclic aromatic group; R 2 represents an aliphatic group of 2 to 12 carbon atoms, an alicyclic group of 4 to 30 carbon atoms, an arylaliphatic group of 6 to 30 carbon atoms or a carbocyclic aryl group of 6 to 30 carbon atoms; R 3 represents --CH 2 ) s --, ##STR24## wherein s represents an integer of 1 to 4; R 4 , R 5 , R 6 and R 7 each represent an alkyl group of 1 to 6 carbon atoms, phenyl group or an alkyl-substituted phenyl group of 7 to 12 carbon atoms; X 1 represents an alkoxy group, acetoxy group or a halogen atom; X 2 represents an alkoxy group, acetoxy group, a halogen atom or hydroxyl group; and m represents an integer of 1≦m≦3; ##EQU7## wherein W, P and Q each represent the total number in the molecule, of the following three kinds of constituting units formed by reaction of the tetracarboxylic acid dianhydride with the diamine and/or the aminosilicon, and further, dehydration or non-dehydration: ##STR25##

Claim 4

Dependent Claim 425 words

A process for producing a soluble polyimide-siloxane precursor, which comprises a first step of reacting A mols of a tetracarboxylic acid dianhydride expressed by the following formula (10), B 2 mols of a diamine expressed by the following formula (11) and D 2 mols of an aminosilicon compound expressed by the following formula (12), A, B 2 and D 2 satisfying the following expression (14) and also approximately satisfying the following equation (15), in the presence of a solvent at a temperature of 0° to 60° C. for a time of 0.2 to 6 hours to effect a uniform reaction; and a second step of heating the resulting reaction material in the presence of E mols of a silylating agent expressed by the following formula (13) in the range expressed by the following expression (16) at a temperature of 60° to 200° C. for a time of 0.5 to 30 hours to effect an imidization reaction, and hydrolyzing X 1 in said aminosilicon compound expressed by the formula (12) and X 2 in said silylating agent expressed by the formula (13), with water generated during said imidization reaction and if necessary, water from other sources, and further effecting siloxane condensation, to make the percentage imidization T of the resulting product defined by the following equation (17), 50 to 100%, and also make the inherent viscosity thereof as measured in N-methyl-2-pyrrolidone in a concentration of 0.5 g/dl at a temperature of 30±0.01° C., 0.05 to 5 dl/g: ##STR23## wherein R 1 represents a tetravalent carbocyclic aromatic group; R 2 represents an aliphatic group of 2 to 12 carbon atoms, an alicyclic group of 4 to 30 carbon atoms, an arylaliphatic group of 6 to 30 carbon atoms or a carbocyclic aryl group of 6 to 30 carbon atoms; R 3 represents --CH 2 ) s --, ##STR24## wherein s represents an integer of 1 to 4; R 4 , R 5 , R 6 and R 7 each represent an alkyl group of 1 to 6 carbon atoms, phenyl group or an alkyl-substituted phenyl group of 7 to 12 carbon atoms; X 1 represents an alkoxy group, acetoxy group or a halogen atom; X 2 represents an alkoxy group, acetoxy group, a halogen atom or hydroxyl group; and m represents an integer of 1≦m≦3; ##EQU7## wherein W, P and Q each represent the total number in the molecule, of the following three kinds of constituting units formed by reaction of the tetracarboxylic acid dianhydride with the diamine and/or the aminosilicon, and further, dehydration or non-dehydration: ##STR25##

Claim 5

Dependent Claim 34 words

A process for producing a soluble polyimide-siloxane precursor according to claim 2 wherein said second stage reaction is carried out by adding water in addition to said water generated during said second stage reaction.

Claim 6

Dependent Claim 21 words

A crosslinked polyimide-siloxane obtained by heating a soluble polyimide-siloxane precursor of claim 1 to a temperature of 100° to 300° C.

Claim 7

Dependent Claim 21 words

A crosslinked polyimide-siloxane according to claim 4 wherein said heating is carried out for a period of 0.5 to 1.5 hour.

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	1990-04-06	1990-10-06	1991-04-07	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	1994-04-06	1994-10-06	1995-04-07	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	1998-04-06	1998-10-06	1999-04-07	$7700.00	Window Closed / Lapsed

Soluble polyimide-siloxane precursor, process for producing same, and cross-linked polyimide-siloxane

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