US4656148A
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US
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Method for the reactivation of a catalyst used for removal of nitrogen oxides
Assignee: Didier Werke AG
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Filing: 1985-08-22
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Granted: 1987-04-07
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Expires: 2005-08-22
Abstract
Abstract In a process for the reactivation of a catalyst, which is used for the removal of NO x , oxides of nitrogen, from exhaust gases, the catalyst should be capable of easy reactivation. For this purpose, when the catalyst starts to lose its activity, it is exposed in a reducing atmosphere to a carbon monoxide current. In an apparatus for the execution of the process, the catalyst is placed in two separate chambers. The carbon monoxide stream is directed alternately to both chambers.
Inventors
- 👤 Hans-Eugen Buhler
- 👤 Hermann Stein
- 👤 Blagoje Levkov
- 👤 Hartmut Kainer
- 👤 Horst Kalfa
- 👤 Daniel Grimm
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 22:13
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/90; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01D53/8621; B01D53/8625; B01D53/8628; B01J21/00; B01J21/20; Y; Y10; Y10S; Y10S502/00; Y10S502/515
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
165 words
A method for reactivation of a catalyst which had been at least partially deactivated when used in removal of oxides of nitrogen from an exhaust gas, said catalyst comprising an iron-containing material, said iron-containing material being chosen from a member of the group consisting essentially of magnetite, hematite, siderite, chromium ore, iron pyrite, sinter, iron ore pellets, slag, red mud, Sydvarange iron ore concentrate, manganese ore, Lake iron ore, Konrad ore, and mixtures of the members of this group; said method comprising the steps of: stopping said flow of exhaust gas across said catalyst which has at least partially lost catalytic activity; and flowing heated carbon monoxide gas which has been heated to a temperature of about 500° C. over said at least partially deactivated catalyst; whereby at least a part of said carbon monoxide breaks down into carbon dioxide and carbon, thereby causing at least a part of an outermost inactive surface of said catalyst to break off and to expose active catalyst surface.
Claim 2
Independent Claim
165 words
A method for reactivation of a catalyst which had been at least partially deactivated when used in removal of oxides of nitrogen from an exhaust gas, said catalyst comprising an iron-containing material, said iron-containing material being chosen from a member of the group consisting essentially of magnetite, hematite, siderite, chromium ore, iron pyrite, sinter, iron ore pellets, slag, red mud, Sydvarange iron ore concentrate, manganese ore, Lake iron ore, Konrad ore, and mixtures of the members of this group; said method comprising the steps of: stopping said flow of exhaust gas across said catalyst which has at least partially lost catalytic activity; and flowing heated carbon monoxide gas which has been heated to a temperature of about 500° C. over said at least partially deactivated catalyst; whereby at least a part of said carbon monoxide breaks down into carbon dioxide and carbon, thereby causing at least a part of an outermost inactive surface of said catalyst to break off and to expose active catalyst surface.
Claim 3
Dependent Claim
30 words
The method for reactivation of a catalyst according to claim 1 wherein said flowing of said heated carbon monoxide gas is initiated when said catalyst begins to lose said activity.
Claim 4
Dependent Claim
23 words
The method for reactivation of a catalyst according to claim 1 wherein said slag is an intermediate product of production of pig iron.
Claim 5
Dependent Claim
26 words
The method for reactivation of a catalyst according to claim 1 wherein said red mud is a product obtained from a process for production of aluminum.
Claim 6
Dependent Claim
31 words
The method for the reactivation of a catalyst according to claim 1 wherein said flowing said heated carbon monoxide over said catalyst continues for about four hours to about eight hours.
Claim 7
Dependent Claim
34 words
The method for reactivation of a catalyst according to claim 1 wherein said material comprises: Fe=60%, of which Fe 2+ =11.15%, Mn=0.21%, SiO 2 =6.60%, Al 2 O 3 =2.17%, CaO=4.75%, MgO=1.44%, and P=0.08%.
Claim 8
Dependent Claim
92 words
The method for reactivation of a catalyst according to claim 1 wherein said slag comprises one of the members of the group consisting essentially of LDAG slag, Bessemer slag and LD slag; said LDAG slag having the following composition: Fe--23.60% Fe 2+ --14.63% Mn--3.28% P 2 O 5 --5.78% CaO--40.10% and MgO said Bessemer slag having the following composition: Fe--14.02% Fe 2+ --6.00% Mn--2.56% P 2 O 5 --15.42% CaO--48.85% MgO--1.14% said LD slag having the following composition: Fe--23.40% Fe 2+ --9.03% Mn--3.60% P 2 O 5 --3.46% and CaO and MgO.
Claim 9
Dependent Claim
36 words
The method for reactivation of a catalyst according to claim 1 wherein said red mud comprises: SiO 2 --11.10% Al 2 O 3 --33.50% TiO 2 --14.40% Fe 2 O 3 --37.50% CaO--1.50% ZrO 2 --0.46%.
Claim 10
Dependent Claim
30 words
The method for reactivation of a catalyst according to claim 1 wherein said catalyst includes at least 3% transition elements, said transition elements being in their lowest stable oxidation state.
Claim 11
Dependent Claim
38 words
The method for reactivation of a catalyst according to claim 9 wherein said transition elements are chosen from at least one member of the group consisting of Periodic Table Group IV B, Zirconium, Hafnium, Nickel, Cobalt and Manganese.
Claim 12
Dependent Claim
20 words
The method for reactivation of a catalyst according to claim 9 wherein said transition elements include iron, chromium and titanium.
Claim 13
Dependent Claim
26 words
The method for reactivation of a catalyst according to claim 11 wherein said transition element comprises Fe 2+ , Cr 3+ , and Ti 4+ .
Claim 14
Dependent Claim
150 words
The method for reactivation of a catalyst according to claim 11 wherein said catalyst which is chosen from said member of the group consisting of said Sydvarange Iron Ore Concentrates, said mixture of Urkutsk Manganese Ore and Chromium Ore, and said mixture of Lake Iron Ore and Konrad Ore; and wherein said Sydvarange Iron Ore Concentrate has the following composition: Fe--65.51% Fe 2+ --21.50% Mn--0.13% P--0.01% SiO 2 --7.73% Al 2 O 3 --0.55% CaO--0.10% MgO--0.68% and wherein said mixture of Urkutsk Manganese Ore and Chromium Ore has the following composition: Fe--10.00% including a portion thereof as Fe 2+ SiO 2 --5.00% Al 2 O 3 --11.80% CaO--0.58% MgO--16.50% Cr 2 O 3 --49.60% with Mn and P and further wherein said mixture of Lake Iron Ore and Konrad Ore has the following composition: Fe--32.22% Fe 2+ --3.83% Mn--0.24% P--0.36% SiO 2 --14.52% Al 2 O 3 --5.30% CaO--12.52% MgO--3.83%.
Claim 15
Dependent Claim
55 words
The method for reactivation of a catalyst according to claim 11, wherein said material comprises a mixture of Urkutsk Manganese Ore and Chromium Ore has the following composition: Fe--10.00% including a portion thereof as Fe 2+ SiO 2 --5.00% Al 2 O 3 --11.80% CaO--0.58% MgO--16.50% Cr 2 O 3 --49.60% with Mn and P.
Claim 16
Dependent Claim
44 words
The method for reactivation of a catalyst according to claim 11, wherein said material comprises a mixture of Lake Iron Ore and Konrad Ore has the following composition: Fe--32.22% Fe 2+ --3.83% Mn--0.24% P--0.36% SiO 2 --14.52% Al 2 O 3 --5.30% CaO--12.52% MgO--3.83%.
Claim 17
Independent Claim
373 words
A method for reactivation of a catalyst which had been at least partially deactivated when used in removal of oxides of nitrogen from an exhaust gas, said catalyst comprising an iron-containing material used in a process of producing steel, said iron-containing material being chosen from a member of the group consisting essentially of magnetite, hematite, siderite, chromium ore, iron pyrite, sinter, iron ore pellets, slag, red mud, Sydvarange iron ore concentrate, manganese ore, Lake iron ore, Konrad ore and mixtures of the members of this group; said method comprising the steps of: switching said exhaust gas from a first chamber having said catalyst therein to a second chamber having a reactivated catalyst therein; and flowing heated carbon monoxide gas, which has been heated to a temperature of about 500° C., over said at least partially deactivated catalyst in said first chamber; whereby at least a part of said carbon monoxide, in said first chamber, breaks down into carbon dioixde and carbon, thereby causing at least a part of the outermost inactive surface of said catalyst in said first chamber to break off to expose active catalyst surface; turning off said flow of heated carbon monoxide to said first chamber after a predetermined length of time whereby at least a portion of said catalyst in said first chamber is reactivated; holding said first chamber in preparation for introduction of said exhaust gas; then determining when said catalyst in said second chamber loses activity; switching said exhaust gas from said second chamber having said catalyst therein to said first chamber; flowing heated carbon monoxide gas which has been heated to a temperature of about 500° C. into said second chamber; whereby at least a part of said carbon monoxide in said second chamber breaks down into carbon dioixde and carbon, thereby causing at least a part of the outermost inactive surface of said catalyst in said second chamber to break off to expose active catalyst surface; turning off said flow of heated carbon monoxide to said second chamber after a predetermined length of time whereby at least a portion of said catalyst in said second chamber is reactivated; holding said second chamber in preparation for introduction of said exhaust gas; and repeating the above steps.
Claim 18
Independent Claim
373 words
A method for reactivation of a catalyst which had been at least partially deactivated when used in removal of oxides of nitrogen from an exhaust gas, said catalyst comprising an iron-containing material used in a process of producing steel, said iron-containing material being chosen from a member of the group consisting essentially of magnetite, hematite, siderite, chromium ore, iron pyrite, sinter, iron ore pellets, slag, red mud, Sydvarange iron ore concentrate, manganese ore, Lake iron ore, Konrad ore and mixtures of the members of this group; said method comprising the steps of: switching said exhaust gas from a first chamber having said catalyst therein to a second chamber having a reactivated catalyst therein; and flowing heated carbon monoxide gas, which has been heated to a temperature of about 500° C., over said at least partially deactivated catalyst in said first chamber; whereby at least a part of said carbon monoxide, in said first chamber, breaks down into carbon dioixde and carbon, thereby causing at least a part of the outermost inactive surface of said catalyst in said first chamber to break off to expose active catalyst surface; turning off said flow of heated carbon monoxide to said first chamber after a predetermined length of time whereby at least a portion of said catalyst in said first chamber is reactivated; holding said first chamber in preparation for introduction of said exhaust gas; then determining when said catalyst in said second chamber loses activity; switching said exhaust gas from said second chamber having said catalyst therein to said first chamber; flowing heated carbon monoxide gas which has been heated to a temperature of about 500° C. into said second chamber; whereby at least a part of said carbon monoxide in said second chamber breaks down into carbon dioixde and carbon, thereby causing at least a part of the outermost inactive surface of said catalyst in said second chamber to break off to expose active catalyst surface; turning off said flow of heated carbon monoxide to said second chamber after a predetermined length of time whereby at least a portion of said catalyst in said second chamber is reactivated; holding said second chamber in preparation for introduction of said exhaust gas; and repeating the above steps.
References Cited (Backward Citations)
US3072457A
Cited
US3791103A
Cited
US4323544A
Cited
US3909204A
Cited
DE2402094A1
Cited
JPS5062246A
Cited
US3967933A
Cited
US4044102A
Cited
US4043939A
Cited
US4049777A
Cited
JPS535094A
Cited
US4165233A
Cited
US4235604A
Cited
US4259312A
Cited
US4398948A
Cited
JPS5715824A
Cited
US4448895A
Cited
US4503162A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1990-04-06 | 1990-10-06 | 1991-04-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-04-06 | 1994-10-06 | 1995-04-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-04-06 | 1998-10-06 | 1999-04-07 | $7700.00 | Window Closed / Lapsed |