Grain-oriented silicon steel sheet having a low iron loss free from deterioration due to stress-relief annealing and a method of producing the same

Claim 2

In a method of producing a grain-oriented silicon steel sheet having a low iron loss free from deterioration due to stress-relief annealing, wherein a hot rolled sheet produced from a steel slab, containing about 2.0-4.0% by weight of Si, through a hot rolling is subjected to one cold rolling or two or more cold rollings with an intermediate annealing between them to produce a cold rolled sheet having a final gauge, the cold rolled sheet is subjected to a decarburization primary recrystallization annealing, an annealing separator consisting mainly of MgO is applied to the surface of the decarburized and primarily recrystallized steel sheet, and the thus treated steel sheet is subjected to a final annealing to form a forsterite film on the steel sheet surface, the improvement comprising forming a forsterite film locally having regions, which have a thickness different from that of the remaining regions in the film, by a process wherein a water-repelling substance for an annealing separator slurry is locally adhered to the surface of the decarburized and primarily recrystallized steel sheet in an amount of not more than 0.1 g/m 2 before the application of the annealing separator.

Claim 3

In a method of producing a grain-oriented silicon steel sheet having a low iron loss free from deterioration due to stress-relief annealing, wherein a hot rolled sheet produced from a steel slab, containing about 2.0-4.0% by weight of Si, through a hot rolling is subjected to one cold rolling or two or more cold rollings with an intermediate annealing between them to produce a cold rolled sheet having a final gauge, the cold rolled sheet is subjected to a decarburization primary recrystallization annealing, an annealing separator consisting mainly of MgO is applied to the surface of the decarburized and primarily recrystallized steel sheet, and the thus treated steel sheet is subjected to a final annealing to form a forsterite film on the steel sheet surface, the improvement comprising forming a forsterite film locally having regions, which have a thickness different from that of the remaining regions in the film, by a process wherein an oxidizing agent for Si contained in the steel is locally adhered to the surface of the decarburized and primarily recrystallized steel sheet in an amount of not more than 2.0 g/m 2 before the application of the annealing separator.

Claim 4

In a method of producing a grain-oriented silicon steel sheet having a low iron loss free from deterioration due to stress-relief annealing, wherein a hot rolled sheet produced from a steel slab, containing about 2.0-4.0% by weight of Si, through a hot rolling is subjected to one cold rolling or two or more cold rollings with an intermediate annealing between them to produce a cold rolled sheet having a final gauge, the cold rolled sheet is subjected to a decarburization primary recrystallization annealing, an annealing separator consisting mainly of MgO is applied to the surface of the decarburized and primarily recrystallized steel sheet, and the thus treated steel sheet is subjected to a final annealing to form a forsterite film on the steel sheet surface, the improvement comprising forming a forsterite film locally having regions, which have a thickness different from that of the remaining regions in the film, by a process wherein an oxidizing agent for Si contained in the steel is locally adhered to the surface of the decarburized and primarily recrystallized steel sheet in an amount of not more than 2.0 g/m 2 before the application of the annealing separator.

Claim 5

In a method of producing a grain-oriented silicon steel sheet having a low iron loss free from deterioration due to stress-relief annealing, wherein a hot rolled sheet produced from a steel slab, containing about 2.0-4.0% by weight of Si, through a hot rolling is subjected to one cold rolling or two or more cold rollings with an intermediate annealing between them to produce a cold rolled sheet having a final gauge, the cold rolled sheet is subjected to a decarburization primary recrystallization annealing, an annealing separator consisting mainly of MgO is applied to the surface of the decarburized and primarily recrystallized steel sheet, and the thus treated steel sheet is subjected to a final annealing to form a forsterite film on the steel sheet surface and then to a top coating treatment, the improvement comprising applying onto the forsterite film a top coating liquid which forms a tension-giving type insulating top coating film having a linear thermal expansion coefficient of not higher than 9.8×10 -6 1/°C., baking the coating liquid to the forsterite film to form the top coating film on the forsterite film, removing locally the top coating film and a part of the forsterite film without causing a plastic strain in the interior of the steel sheet matrix, to form different thickness regions in the forsterite film, and then subjecting the thus treated steel sheet to an annealing at a temperature range of 600°-900° C. to repair the top coating film.

Claim 6

In a method of producing a grain-oriented silicon steel sheet having a low iron loss free from deterioration due to stress-relief annealing, wherein a hot rolled sheet produced from a steel slab, containing about 2.0-4.0% by weight of Si, through a hot rolling is subjected to one cold rolling or two or more cold rollings with an intermediate annealing between them to produce a cold rolled sheet having a final gauge, the cold rolled sheet is subjected to a decarburization primary recrystallization annealing, an annealing separator consisting mainly of MgO is applied to the surface of the decarburized and primarily recrystallized steel sheet, and the thus treated steel sheet is subjected to a final annealing to form a forsterite film on the steel sheet surface and then to a top coating treatment, the improvement comprising applying onto the forsterite film a top coating liquid which forms a tension-giving type insulating top coating film having a linear thermal expansion coefficient of not higher than 9.8×10 -6 1/°C., baking the coating liquid to the forsterite film to form the top coating film on the forsterite film, removing locally the top coating film and a part of the forsterite film without causing a plastic strain in the interior of the steel sheet matrix, to form different thickness regions in the forsterite film, and then subjecting the thus treated steel sheet to an annealing at a temperature range of 600°-900° C. to repair the top coating film.

Claim 7

In a method of producing a grain-oriented silicon steel sheet having a low iron loss free from deterioration due to stress-relief annealing, wherein a hot rolled sheet produced from a steel slab, containing about 2.0-4.0% by weight of Si, through a hot rolling is subjected to one cold rolling or two or more cold rollings with an intermediate annealing between them to produce a cold rolled sheet having a final gauge, the cold rolled sheet is subjected to a decarburization primary recrystallization annealing, an annealing separator consisting mainly of MgO is applied to the surface of the decarburized and primarily recrystallized steel sheet, and the thus treated steel sheet is subjected to a final annealing to form a forsterite film on the steel sheet surface, the improvement comprising forming a forsterite film, which has locally filmless regions in the film, by a process, wherein a water-repelling substance for an annealing separator slurry is locally adhered to the surface of the decarburized and primarily recrystallized steel sheet in an amount of more than 0.1 g/m 2 before the application of the annealing separator.

Claim 8

In a method of producing a grain-oriented silicon steel sheet having a low iron loss free from deterioration due to stress-relief annealing, wherein a hot rolled sheet produced from a steel slab, containing about 2.0-4.0% by weight of Si, through a hot rolling is subjected to one cold rolling or two or more cold rollings with an intermediate annealing between them to produce a cold rolled sheet having a final gauge, the cold rolled sheet is subjected to a decarburization primary recrystallization annealing, an annealing separator consisting mainly of MgO is applied to the surface of the decarburized and primarily recrystallized steel sheet, and the thus treated steel sheet is subjected to a final annealing to form a forsterite film on the steel sheet surface, the improvement comprising forming a forsterite film, which has locally filmless regions in the film, by a process, wherein a water-repelling substance for an annealing separator slurry is locally adhered to the surface of the decarburized and primarily recrystallized steel sheet in an amount of more than 0.1 g/m 2 before the application of the annealing separator.

Claim 9

In a method of producing a grain-oriented silicon steel sheet having a low iron loss free from deterioration due to stress-relief annealing, wherein a hot rolled sheet produced from a steel slab, containing about 2.0-4.0% by weight of Si, through a hot rolling is subjected to one cold rolling or two or more cold rollings with an intermediate annealing between them to produce a cold rolled sheet having a final gauge, the cold rolled sheet is subjected to a decarburization primary recrystallization annealing, an annealing separator consisting mainly of MgO is applied to the surface of the decarburized and primarily recrystallized steel sheet, and the thus treated steel sheet is subjected to a final annealing to form a forsterite film on the steel sheet surface and then to a top coating treatment, the improvement comprising applying onto the forsterite film a top coating liquid which forms a tension-giving type insulating top coating film having a linear thermal expansion coefficient of not higher than 9.8×10 -6 1/°C., baking the coating liquid to the forsterite film to form the top coating film on the forsterite film, removing locally the top coating film and the forsterite film without causing a plastic strain in the interior of the steel sheet matrix, to form filmless regions in the forsterite film, and then subjecting the thus treated steel sheet to an annealing at a temperature range of 600°-900° C. to repair the top coating film.

Claim 10

In a method of producing a grain-oriented silicon steel sheet having a low iron loss free from deterioration due to stress-relief annealing, wherein a hot rolled sheet produced from a steel slab, containing about 2.0-4.0% by weight of Si, through a hot rolling is subjected to one cold rolling or two or more cold rollings with an intermediate annealing between them to produce a cold rolled sheet having a final gauge, the cold rolled sheet is subjected to a decarburization primary recrystallization annealing, an annealing separator consisting mainly of MgO is applied to the surface of the decarburized and primarily recrystallized steel sheet, and the thus treated steel sheet is subjected to a final annealing to form a forsterite film on the steel sheet surface and then to a top coating treatment, the improvement comprising applying onto the forsterite film a top coating liquid which forms a tension-giving type insulating top coating film having a linear thermal expansion coefficient of not higher than 9.8×10 -6 1/°C., baking the coating liquid to the forsterite film to form the top coating film on the forsterite film, removing locally the top coating film and the forsterite film without causing a plastic strain in the interior of the steel sheet matrix, to form filmless regions in the forsterite film, and then subjecting the thus treated steel sheet to an annealing at a temperature range of 600°-900° C. to repair the top coating film.