US4654261A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Support of photographic paper
Assignee: Fujifilm Holdings Corp
•
Filing: 1986-04-14
•
Granted: 1987-03-31
•
Expires: 2006-04-14
Abstract
Abstract A water-proof support of photographic paper comprising a substrate and a white pigment-containing resin layer provided on at least one surface of the substrate, in which the resin layer comprises a white pigment dispersed in a polymer binder made by polymerization of a unsaturated compound containing a tetraacrylate ester of pentaerythrithol alkylene oxide adduct. An adhesive layer may be provided between the substrate and the white pigment-containing resin layer.
Inventors
- 👤 Takashi Takayanagi
- 👤 Yasuzi Asao
- 👤 Tetsuro Fuchizawa
- 👤 Tetusji Jitsumatsu
- 👤 Kiyoshi Murase
- 👤 Hiroyuki Kato
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 03:36
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/775; G03C1/79; D; D21; D21H; D21H19/00; D21H19/36; D21H19/44; D21H19/56; D21H19/58; Y; Y10; Y10T; Y10T428/00; Y10T428/26; Y10T428/263; Y10T428/264; Y10T428/265; Y10T428/31504; Y10T428/31855; Y10T428/3188; Y10T428/31895; Y10T428/31906; Y10T428/31909; Y10T428/31928; Y10T428/31935
Claims Analysis
Total Claims: 32
Claim 1
Independent Claim
54 words
A water-proof support of photographic paper comprising a substrate and a white pigment-containing resin layer provided on at least one surface of the substrate, in which the resin layer comprises a white pigment dispersed in a polymer binder made by polymerization of a unsaturated compound containing a tetraacrylate ester of pentaerythrithol alkylene oxide adduct.
Claim 2
Dependent Claim
54 words
A water-proof support of photographic paper comprising a substrate and a white pigment-containing resin layer provided on at least one surface of the substrate, in which the resin layer comprises a white pigment dispersed in a polymer binder made by polymerization of a unsaturated compound containing a tetraacrylate ester of pentaerythrithol alkylene oxide adduct.
Claim 3
Dependent Claim
34 words
The support as claimed in claim 1, wherein the pentaerythrithol alkylene oxide adduct is composed of pentaerythrithol and alkylene oxide in an amount of 5 moles or more per 1 mole of the pentaerythrithol.
Claim 4
Dependent Claim
33 words
The support as claimed in claim 1, wherein the petnaerythrithol alkylene oxide has the following formula: ##STR2## in which X is an oxyalkylene group, and k+l+m+n is a value of 5 or more.
Claim 5
Dependent Claim
29 words
The support as claimed in claim 3, wherein the X in the formula is at least one group selected from the group consisting of oxyethylene, oxypropylene, oxybutylene and oxybutylene.
Claim 6
Dependent Claim
38 words
The support as claimed in any one of claims 1 to 3, wherein the polymer binder is made by polymerization of a unsaturated compound containing 50 wt.% or more of a tetraacrylate ester of pentaerythrithol alkylene oxide adduct.
Claim 7
Dependent Claim
35 words
The support as claimed in any one of claims 1 to 3, wherein the polymer binder is made by polymerization of a unsaturated compound consisting essentially of a tetraacrylate ester of pentaerythrithol alkylene oxide adduct.
Claim 8
Dependent Claim
36 words
The support as claimed in any one of claims 1 to 3, wherein the white pigment is present in the polymer binder of the resin layer in a ratio by weight ranging from 3/1 to 1/9.
Claim 9
Dependent Claim
29 words
The support as claimed in any one of claims 1 to 3, wherein the white pigment-containing resin layer has a thickness in the range from 3 to 100 μm.
Claim 10
Dependent Claim
29 words
The support as claimed in any one of claims 1 to 3, wherein the substrate is composed of a paper sheet coated on both surfaces thereof a water-proofing resin.
Claim 11
Dependent Claim
75 words
In a process for the preparation of a water-proof support of photographic paper which comprises forming at least one white pigment-containing water-proofing resin layer on a substrate, the improvement in which the white pigment-containing water-proofing is formed by coating a coating dispersion containing a white pigment and a unsaturated compound containing a tetraacrylate ester of pentaerythrithol alkylene oxide adduct on the substrate and irradiating the coated layer with electron beam to cure the coated compound.
Claim 12
Dependent Claim
75 words
In a process for the preparation of a water-proof support of photographic paper which comprises forming at least one white pigment-containing water-proofing resin layer on a substrate, the improvement in which the white pigment-containing water-proofing is formed by coating a coating dispersion containing a white pigment and a unsaturated compound containing a tetraacrylate ester of pentaerythrithol alkylene oxide adduct on the substrate and irradiating the coated layer with electron beam to cure the coated compound.
Claim 13
Dependent Claim
40 words
The process for the preparation of a support as claimed in claim 10, wherein the pentaerythrithol alkylene oxide adduct is composed of pentaerythrithol and alkylene oxide in an amount of 5 moles or more per 1 mole of the pentaerythrithol.
Claim 14
Dependent Claim
28 words
The process for the preparation of a support as claimed in claim 10, wherein the unsaturated compound consists essentially of a tetraacrylate ester of pentaerythrithol alkylene oxide adduct.
Claim 15
Dependent Claim
47 words
The process for the preparation of a support as claimed in claim 10, wherein the irradiation with electron beam is performed at an acceleration voltage in the range of 100-1,000 kV to have the coated layer to absorb radiation in the range of 2 to 10 megarads.
Claim 16
Dependent Claim
66 words
A water-proof support of photographic paper comprising: a substrate, a white pigment-containing resin layer provided on at least one surface of the substrate, in which the resin layer comprises a white pigment dispersed in a polymer binder made by polymerization of a unsaturated compound containing a tetraacrylate ester of pentaerythrithol alkylene oxide adduct, and an adhesive layer provided between the substrate and white pigment-containing resin layer.
Claim 17
Dependent Claim
66 words
A water-proof support of photographic paper comprising: a substrate, a white pigment-containing resin layer provided on at least one surface of the substrate, in which the resin layer comprises a white pigment dispersed in a polymer binder made by polymerization of a unsaturated compound containing a tetraacrylate ester of pentaerythrithol alkylene oxide adduct, and an adhesive layer provided between the substrate and white pigment-containing resin layer.
Claim 18
Dependent Claim
34 words
The support as claimed in claim 14, wherein the pentaerythrithol alkylene oxide adduct is composed of pentaerythrithol and alkylene oxide in an amount of 5 moles or more per 1 mole of the pentaerythrithol.
Claim 19
Dependent Claim
33 words
The support as claimed in claim 14, wherein the petnaerythrithol alkylene oxide has the following formula: ##STR3## in which X is an oxyalkylene group, and k+l+m+n is a value of 5 or more.
Claim 20
Dependent Claim
29 words
The support as claimed in claim 16, wherein the X in the formula is at least one group selected from the group consisting of oxyethylene, oxypropylene, oxybutylene and oxybutylene.
Claim 21
Dependent Claim
38 words
The support as claimed in any one of claims 14 to 16, wherein the polymer binder is made by polymerization of a unsaturated compound containing 50 wt.% or more of a tetraacrylate ester of pentaerythrithol alkylene oxide adduct.
Claim 22
Dependent Claim
35 words
The support as claimed in any one of claims 14 to 16, wherein the polymer binder is made by polymerization of a unsaturated compound consisting essentially of a tetraacrylate ester of pentaerythrithol alkylene oxide adduct.
Claim 23
Dependent Claim
36 words
The support as claimed in any one of claims 14 to 16, wherein the white pigment is present in the polymer binder of the resin layer in a ratio by weight ranging from 3/1 to 1/9.
Claim 24
Dependent Claim
29 words
The support as claimed in any one of claims 14 to 16, wherein the white pigment-containing resin layer has a thickness in the range from 3 to 100 μm.
Claim 25
Dependent Claim
29 words
The support as claimed in any one of claims 14 to 16, wherein the substrate is composed of a paper sheet coated on both surfaces thereof a water-proofing resin.
Claim 26
Dependent Claim
27 words
The support as claimed in any one of claims 14 to 16, wherein the adhesive layer has a thickness in the range of 5 to 50 μm.
Claim 27
Dependent Claim
43 words
The support as claimed in any one of claims 14 to 16, wherein the adhesive layer is made of at least one material selected from the group consisting of urea resin, melamine resin, phenol resin, vinyl acetate resin, and a hot melt resin.
Claim 28
Dependent Claim
88 words
A process for the preparation of a water-proof support of photographic paper which comprises: combining a substrate and at least one white pigment-containing water-proofing resin film which has been formed by coating a coating dispersion containing a white pigment and a unsaturated compound containing a tetraacrylate ester of pentaerythrithol alkylene oxide adduct on a temporary substrate other than the above substrate, irradiating the coated layer with electron beam to cure the coated compound, via an adhesive, and separating the combined substrate and cured film from the temporary substrate.
Claim 29
Dependent Claim
88 words
A process for the preparation of a water-proof support of photographic paper which comprises: combining a substrate and at least one white pigment-containing water-proofing resin film which has been formed by coating a coating dispersion containing a white pigment and a unsaturated compound containing a tetraacrylate ester of pentaerythrithol alkylene oxide adduct on a temporary substrate other than the above substrate, irradiating the coated layer with electron beam to cure the coated compound, via an adhesive, and separating the combined substrate and cured film from the temporary substrate.
Claim 30
Dependent Claim
40 words
The process for the preparation of a support as claimed in claim 25, wherein the pentaerythrithol alkylene oxide adduct is composed of pentaerythrithol and alkylene oxide in an amount of 5 moles or more per 1 mole of the pentaerythrithol.
Claim 31
Dependent Claim
28 words
The process for the preparation of a support as claimed in claim 25, wherein the unsaturated compound consists essentially of a tetraacrylate ester of pentaerythrithol alkylene oxide adduct.
Claim 32
Dependent Claim
47 words
The process for the preparation of a support as claimed in claim 25, wherein the irradiation with electron beam is performed at an acceleration voltage in the range of 100-1,000 kV to have the coated layer to absorb radiation in the range of 2 to 10 megarads.
References Cited (Backward Citations)
No citation records indexed.
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-03-30 | 1990-09-29 | 1991-03-31 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-03-30 | 1994-09-29 | 1995-03-31 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-03-30 | 1998-09-29 | 1999-03-31 | $7700.00 | Window Closed / Lapsed |