US4650830A
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Thermoplastic elastomer composition and process for preparation thereof
Assignee: Mitsui Chemicals Inc
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Filing: 1984-05-30
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Granted: 1987-03-17
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Expires: 2004-05-30
Abstract
Abstract Disclosed is a thermoplastic elastomer composition excellent in the injection fusion bondability and the surface gloss, which comprises (1) an amorphous ethylene/ alpha -olefin copolymer (a) and (2) (i) a lowly crystalline copolymer (b) of propylene with an alpha -olefin having at least 4 carbon atoms, (ii) a polymer (d) composed mainly of 1-butene or (iii) a combination of the copolymer (b) or the polymer (d) with a crystalline polymer (c) composed mainly of propylene, wherein the component (1) is present in an amount of 10 to 95% by weight based on the total amount of the components (1) and (2), the component (2) is present in an amount of 5 to 90% by weight based on the total amount of the components (1) and (2), and the component (1) or the components (1) and (2) are partially crosslinked. The partial crosslinking is effected by grafting of a radical-polymerizable monomer having at least two polymerizable groups.
Inventors
- 👤 Katsuyoshi Yonekura
- 👤 Akira Uchiyama
- 👤 Akira Matsuda
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 09:09
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/0008; C08K5/0025; C08F; C08F255/00; C08F255/02; C08L; C08L23/00; C08L23/02; C08L23/16; C08L2205/00; C08L2205/03; C08L2205/035; C08L2207/00; C08L2207/04; C08L23/10; C08L23/14; C08L23/18; C08L23/20; C08L23/22
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
132 words
A thermoplastic elastomer composition having excellent injection fusion bondability and surface gloss, which comprises an amorphous ethylene/α-olefin copolymer (a) and a propylene/1-butene copolymer having a propylene unit content of 55 to 85 mole %, a crystallization degree of 10 to 30% and a melt flow rate of 1 to 40 g/10 min (b) wherein component (a) is present in an amount of 10 to 95% by weight based on the total amount of components (a) and (b), and component (a) or components (a) and (b) are partially crosslinked, and which further comprises a radical-polymerizable monomer (c) having at least two polymerizable groups in an amount of 0.05 to 1% by weight based on the total amount of components (a) and (b), wherein the partial crosslinking is effected by grafting of said monomer.
Claim 2
Dependent Claim
132 words
A thermoplastic elastomer composition having excellent injection fusion bondability and surface gloss, which comprises an amorphous ethylene/α-olefin copolymer (a) and a propylene/1-butene copolymer having a propylene unit content of 55 to 85 mole %, a crystallization degree of 10 to 30% and a melt flow rate of 1 to 40 g/10 min (b) wherein component (a) is present in an amount of 10 to 95% by weight based on the total amount of components (a) and (b), and component (a) or components (a) and (b) are partially crosslinked, and which further comprises a radical-polymerizable monomer (c) having at least two polymerizable groups in an amount of 0.05 to 1% by weight based on the total amount of components (a) and (b), wherein the partial crosslinking is effected by grafting of said monomer.
Claim 3
Dependent Claim
37 words
The composition as set forth in claim 1, wherein the copolymer (a) is an ethylene/propylene copolymer or ethylene/1-butene copolymer having an ethylene unit content of 50 to 95 mole % and a crystallization degree lower than 20%.
Claim 4
Dependent Claim
61 words
The composition as set forth in claim 1, wherein the copolymer (a) is a terpolymer having an ethylene unit content of 50 to 95 mole %, a propylene or 1-butene unit content of 5 to 50 mole %, an unconjugated diene unit content of 0.1 to 20 mole % and a Mooney viscosity ML 1+4 (100° C.) of 40 to 160.
Claim 5
Dependent Claim
45 words
The composition as set forth in claim 1, wherein the copolymer (b) is a propylene/1-butene copolymer having a propylene unit content of 55 to 85 mole %, a crystallization degree of 10 to 30% and a melt flow rate of 1 to 40 g/10 min.
Claim 6
Dependent Claim
92 words
A process for the preparation of a thermoplastic elastomer composition having excellent surface gloss, which comprises adding an organic peroxide (f) and a radical-polymerizable monomer (e) having at least two polymerizable groups to a composition comprising an amorphous ethylene/α-olefin copolymer (a), a propylene/1-butene copolymer having a propylene unit content of 55 to 85 mole %, a crystallization degree of 10 to 30% and a melt flow rate of 1 to 40 g/10 min (b) and optionally a polypropylene having a crystallization degree higher than 50% (c), and dynamically heat-treating the resultant mixture.
Claim 7
Dependent Claim
92 words
A process for the preparation of a thermoplastic elastomer composition having excellent surface gloss, which comprises adding an organic peroxide (f) and a radical-polymerizable monomer (e) having at least two polymerizable groups to a composition comprising an amorphous ethylene/α-olefin copolymer (a), a propylene/1-butene copolymer having a propylene unit content of 55 to 85 mole %, a crystallization degree of 10 to 30% and a melt flow rate of 1 to 40 g/10 min (b) and optionally a polypropylene having a crystallization degree higher than 50% (c), and dynamically heat-treating the resultant mixture.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-03-16 | 1990-09-15 | 1991-03-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-03-16 | 1994-09-15 | 1995-03-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-03-16 | 1998-09-15 | 1999-03-17 | $7700.00 | Window Closed / Lapsed |