← Back to Patent Explorer
US4650808A Expired / Lapsed US ⏱️ 0.0 years remaining

Synergistic compositions containing hydroxypropyl methanethiolsulfonate and methods of using same

Assignee: Buckman Laboratories International Inc
•
Filing: 1984-03-28
•
Granted: 1987-03-17
•
Expires: 2004-03-28
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Compositions comprising 2-hydroxypropyl methanethiolsulfonate in combination with a mixture of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one show synergistic results in controlling the growth and proliferation of microorganisms in aqueous systems.

Inventors

  • 👤 Oscar W. May
  • 👤 Betty S. Johnson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 07:47
CPC Classifications
C; C02; C02F; C02F1/00; C02F1/50; A; A01; A01N; A01N43/00; A01N43/72; A01N43/80

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 73 words
A synergistic bactericidal composition comprising in admixture (a) 2-hydroxypropyl methanethiosulfonate; and (b) a mixture of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one, wherein the approximate weight ratio of the compounds in the mixture (b) is from about 70 to 80 parts by weight 5-chloro-2-methyl-4-isothiazolin-3-one to about 20 to 30 parts by weight 2-methyl-4-isothiozolin-3-one; and characterized further in that the weight ratio of the thiosulfonate (a) to the isothiazoline mixture (b) ranges from about 95:5 to about 5:95.
Claim 2
Dependent Claim 73 words
A synergistic bactericidal composition comprising in admixture (a) 2-hydroxypropyl methanethiosulfonate; and (b) a mixture of 5-chloro-2-methyl-4-isothiazolin-3-one and 2-methyl-4-isothiazolin-3-one, wherein the approximate weight ratio of the compounds in the mixture (b) is from about 70 to 80 parts by weight 5-chloro-2-methyl-4-isothiazolin-3-one to about 20 to 30 parts by weight 2-methyl-4-isothiozolin-3-one; and characterized further in that the weight ratio of the thiosulfonate (a) to the isothiazoline mixture (b) ranges from about 95:5 to about 5:95.
Claim 3
Dependent Claim 15 words
The composition of claim 1 where said ratio of (a) to (b) is about 87:13.
Claim 4
Dependent Claim 15 words
The composition of claim 1 where said ratio of (a) to (b) is about 90:10.
Claim 5
Dependent Claim 15 words
The composition of claim 1 where said ratio of (a) to (b) is about 50:50.
Claim 6
Dependent Claim 27 words
The composition of claim 1 wherein the approximate weight ratio of the compounds in the mixture (b) is 70 parts of 5-chloro-2-methyl-4-isothiazolin-3-one to 30 parts of 2-methyl-4-isothiazolin-3-one.
Claim 7
Dependent Claim 27 words
The composition of claim 1 wherein the approximate weight ratio of the compounds in the mixture (b) is 75 parts of 5-chloro-2-methyl-4-isothiazolin-3-one to 25 parts of 2-methyl-4-isothiazolin-3-one.
Claim 8
Dependent Claim 27 words
The composition of claim 1 wherein the approximate weight ratio of the compounds in the mixture (b) is 80 parts of 5-chloro-2-methyl-4-isothiazolin-3-one to 20 parts of 2-methyl-4-isothiazolin-3-one.
Claim 9
Dependent Claim 45 words
A method of controlling the growth of bacteria in aqueous systems which comprises adding to the water in such system a composition as defined in claim 1 in an amount between approximately 0.01 and approximately 1000 parts of the composition per million parts of water.
Claim 10
Dependent Claim 19 words
The method of claim 8 in which the aqueous system is that of a pulp and paper mill system.
Claim 11
Dependent Claim 17 words
The method of claim 8 in which the aqueous system is that of a cooling water system.
Claim 12
Dependent Claim 20 words
The method of claim 8 in which the aqueous system is that of a petroleum enhanced oil recovery waterflood system.
Claim 13
Dependent Claim 30 words
The synergistic bactericidal composition of claim 2, wherein said composition is synergistic against at least one bacterium selected from the group consisting of Enterobacter aerogenes, Psuedomonas aeruginosa and Sphaerotilus natans.
Claim 14
Dependent Claim 15 words
The synergistic bactericidal composition of claim 12, wherein said composition is synergistic against Enterobacter aerogenes.

References Cited (Backward Citations)

US3859322A Cited
US3929561A Cited
US4379137A Cited
US4295932A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-03-16 1990-09-15 1991-03-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-03-16 1994-09-15 1995-03-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-03-16 1998-09-15 1999-03-17 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag