US4650740A
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Heat-sensitive recording material
Assignee: Fujifilm Holdings Corp
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Filing: 1984-09-13
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Granted: 1987-03-17
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Expires: 2004-09-13
Abstract
Abstract A heat-sensitive recording material is described, comprising a support having provided thereon a recording layer comprising a binder containing a diazonium compound and a coupling component, said diazonium compound being a diazonium salt represented by formula (I) ArN.sub.2.sup.+ X.sup.- (I) wherein Ar represents a substituted or unsubstituted aromatic moiety; and X - represents an acid anion containing an alkyl group having three or more fluorine atoms.
Inventors
- 👤 Toshimasa Usami
- 👤 Toshiharu Tanaka
- 👤 Fumiaki Shinozaki
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 16:06
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/002; G03C1/52; Y; Y10; Y10S; Y10S430/00; Y10S430/165
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
188 words
A heat-sensitive recording material comprising a support having provided thereon a recording layer, wherein said recording layer comprises, in admixture: a binder, a diazonium compound, a coupling component and a basic substance, wherein said diazonium compound is a diazonium salt represented by formula (I) ArN.sub.2.sup.+ X.sup.- (I) wherein Ar represents a substituted or unsubstituted aromatic moiety; and X - represents an acid anion containing an alkyl group having 4 or more carbon atoms and three or more fluorine atoms, wherein said acid anion is selected from the group consisting of COO - , SO 3 - and PO 4 - , wherein said diazonium compound is present in the recording layer in an amount from 0.05 to 2.0 g/m 2 , when said binder is present in an amount of from 0.5 to 5 g/m 2 , wherein said coupling component is present in an amount of from 0.1 to 10 parts by weight per part by weight of said diazonium compound and, wherein said basic substance is present in an amount of from 0.1 to 20 parts by weight per part by weight of said diazonium compound.
Claim 2
Dependent Claim
188 words
A heat-sensitive recording material comprising a support having provided thereon a recording layer, wherein said recording layer comprises, in admixture: a binder, a diazonium compound, a coupling component and a basic substance, wherein said diazonium compound is a diazonium salt represented by formula (I) ArN.sub.2.sup.+ X.sup.- (I) wherein Ar represents a substituted or unsubstituted aromatic moiety; and X - represents an acid anion containing an alkyl group having 4 or more carbon atoms and three or more fluorine atoms, wherein said acid anion is selected from the group consisting of COO - , SO 3 - and PO 4 - , wherein said diazonium compound is present in the recording layer in an amount from 0.05 to 2.0 g/m 2 , when said binder is present in an amount of from 0.5 to 5 g/m 2 , wherein said coupling component is present in an amount of from 0.1 to 10 parts by weight per part by weight of said diazonium compound and, wherein said basic substance is present in an amount of from 0.1 to 20 parts by weight per part by weight of said diazonium compound.
Claim 3
Dependent Claim
178 words
A heat-sensitive recording material as in claim 1, wherein the aromatic moiety represented by Ar is represented by formula (II) ##STR9## wherein R 1 represents a hydrogen atom, a substituted amino group, an alkoxy group having from 1 to 18 carbon atoms, an aryloxy group having from 6 to 18 carbon atoms, an alkylthio group having from 1 to 18 carbon atoms, an arylthio group having from 6 to 18 carbon atoms, an arylamino group having from 6 to 18 carbon atoms, or an acylamino group having from 1 to 18 carbon atoms; said substituted amino group including a dialkylamino group having from 1 to 36 carbon atoms, an arylamino group having from 6 to 18 carbon atoms, a morpholino group, a piperidino group, a pyrrolidino group; and R 2 represents a hydrogen atom, an alkyl group having from 1 to 5 carbon atoms, a halogen atom, an alkoxy group having from 1 to 18 carbon atoms, an aryloxy group having from 6 to 18 carbon atoms, or an arylamino group having from 1 to 18 carbon atoms.
Claim 4
Dependent Claim
25 words
A heat-sensitive recording material as in claim 1, wherein X - represents an acid anion containing an alkyl group having 4 to 20 carbon atoms.
Claim 5
Dependent Claim
25 words
A heat-sensitive recording material as in claim 2, wherein X - represents an acid anion containing an alkyl group having 4 to 20 carbon atoms.
Claim 6
Dependent Claim
83 words
A heat-sensitive recording material as in claim 1, wherein the acid anion represented by X - is represented by formula (III) Y--Z--W.sup.- (III) wherein Y represents a saturated fluorine-containing alkyl group represented by formula (IV) C.sub.n H.sub.m F.sub.2n-m+1.sup.- (IV) wherein n represents an integer of 4 to 18, and m represents an integer of 0 to 2n-2; Z represents a linkage connecting Y and W - to each other directly or through a divalent linking group; and W - represents an anion moiety.
Claim 7
Dependent Claim
83 words
A heat-sensitive recording material as in claim 2, wherein the acid anion represented by X - is represented by formula (III) Y--Z--W.sup.- (III) wherein Y representes a saturated fluorine-containing alkyl group represented by formula (IV) C.sub.n H.sub.m F.sub.2n-m+1.sup.- (IV) wherein n represents an integer of 4 to 18, and m represents an integer of 0 to 2n-2; Z represents a linkage connecting Y and W - to each other directly or through a divalent linking group; and W - represents an anion moiety.
Claim 8
Dependent Claim
83 words
A heat-sensitive recording material as in claim 1, wherein the acid anion represented by X - is represented by formula (III) Y--Z--W.sup.- (III) wherein Y represents an unsaturated fluorine-containing alkyl group represented by formula (V) C.sub.n H.sub.m F.sub.2n-m-1.sup.- (V) wherein n represents an integer of 4 to 18, and m represents an integer of 0 to 2n-4; Z represents a linkage connecting Y and W - to each other directly or through a divalent linking group; and W - represents an anion moiety.
Claim 9
Dependent Claim
83 words
A heat-sensitive recording material as in claim 2, wherein the acid anion represented by X - is represented by formula (III) Y--Z--W.sup.- (III) wherein Y represents an unsaturated fluorine-containing alkyl group represented by formula (V) C.sub.n H.sub.m F.sub.2n-m-1.sup.- (V) wherein n represents an integer of 4 to 18, and m represents an integer of 0 to 2n-4; Z represents a linkage connecting Y and W - to each other directly or through a divalent linking group; and W - represents an anion moiety.
Claim 10
Dependent Claim
17 words
A heat-sensitive recording material as in claim 5, wherein X - has 9 or more fluorine atoms.
Claim 11
Dependent Claim
17 words
A heat-sensitive recording material as in claim 6, wherein X - has 9 or more fluorine atoms.
Claim 12
Dependent Claim
17 words
A heat-sensitive recording material as in claim 7, wherein X - has 9 or more fluorine atoms.
Claim 13
Dependent Claim
17 words
A heat-sensitive recording material as in claim 8, wherein X - has 9 or more fluorine atoms.
Claim 14
Dependent Claim
38 words
A heat-sensitive recording material as in claim 1, wherein the coupling component is selected from the group consisting of 2-hydroxy-3-naphthoic acid anilide, 1-hydroxy-2-naphthoic acid morpholinopropylamide, 2-hydroxy-3-naphthoic acid morpholinopropylamide, 2-hydroxy-3-naphthoic acid-2'-methylanilide, 2-hydroxy-3-naphthoic acid octylamide, 2-hydroxy-3-naphthoic acid N-dodecyloxypropylamide and 1-phenyl-3-methyl-5-pyrazolone.
Claim 15
Dependent Claim
35 words
A heat-sensitive recording material as in claim 1, wherein the binder is selected from the group consisting of polyvinyl alcohol, methyl cellulose, carboxymethyl cellulose, hydroxymethyl cellulose, gum arabic, gelatin, casein, styrene-maleic anhydride copolymer and polyacrylamide.
Claim 16
Dependent Claim
30 words
A heat-sensitive recording material as in claim 1, wherein the basic substance is selected from the group consisting of triphenylguanidine, diphenyl-o-tolylguanidine, diphenyl-p-tolylguanidine, 2-benzylimidazole, 4-phenylimidazole, 2-phenyl-4-methylimidazole, 2-undecylimidazoline, 4,4'-dithiomorpholine, 2-aminobenzothiazole and 2-benzoylhydrazinobenzothiazole.
Claim 17
Dependent Claim
30 words
A heat-sensitive recording material as in claim 2, wherein the basic substance is selected from the group consisting of triphenylguanidine, diphenyl-o-tolylguanidine, diphenyl-p-tolylguanidine, 2-benzylimidazole, 4-phenylimidazole, 2-phenyl-4-methylimidazole, 2-undecylimidazoline, 4,4'-dithiomorpholine, 2-aminobenzothiazole and 2-benzoylhydrazinobenzothiazole.
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1990-03-16 | 1990-09-15 | 1991-03-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-03-16 | 1994-09-15 | 1995-03-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-03-16 | 1998-09-15 | 1999-03-17 | $7700.00 | Window Closed / Lapsed |