US4648951A
Expired / Lapsed
US
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Photoionization technique to enrich mercury isotopes and apparatus therefor
Assignee: Osram Sylvania Inc
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Filing: 1983-11-16
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Granted: 1987-03-10
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Expires: 2003-11-16
Abstract
Abstract A simple photoionization technique for enriching a particular isotope of mercury in a naturally-occurring mixture employing an isotopically pure radiation source separately optimized for 253.7 nm. and 404.7 nm. emission, respectively. A vessel is provided for containing the naturally occurring mercury. This vessel may be part of either a flow or closed system. The radiation source brings the isotope from the 6 1 S 0 ground state to the 6 3 P 1 state wherein the nitrogen gas deactivates the isotope to bring the isotope to the long-lived 6 3 P 0 state. Thereafter, the source optimized at 404.7 nm. brings the isotope to the 7 3 S 1 state. At this level the atom may be easily photoionized either by a laser or a powerful visible incoherent radiation source.
Inventors
- 👤 Jakob Maya
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 11:19
CPC Classifications
B; B01; B01D; B01D59/00; B01D59/34; B01J; B01J19/00; B01J19/08; B01J19/12; B01J19/121; B01J19/122
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
109 words
A method of photoionizing naturally-occurring mercury to enrich a predetermined isotope of mercury comprising the steps of: radiating the mercury from an isotopically pure lamp radiation source so as to bring the isotope from the 6 1 S 0 ground state to the 6 3 P 1 state, deactivating the isotope to bring the isotope to the long lived 6 3 P 0 state of mercury using a relatively large inert quenching molecule, radiating the mercury from said source to bring the isotope to the 7 3 S 1 state, photoionizing the isotope atom by means of a powerful optical incoherent radiation source, and collecting the predetermined ionic isotope.
Claim 2
Independent Claim
109 words
A method of photoionizing naturally-occurring mercury to enrich a predetermined isotope of mercury comprising the steps of: radiating the mercury from an isotopically pure lamp radiation source so as to bring the isotope from the 6 1 S 0 ground state to the 6 3 P 1 state, deactivating the isotope to bring the isotope to the long lived 6 3 P 0 state of mercury using a relatively large inert quenching molecule, radiating the mercury from said source to bring the isotope to the 7 3 S 1 state, photoionizing the isotope atom by means of a powerful optical incoherent radiation source, and collecting the predetermined ionic isotope.
Claim 3
Dependent Claim
40 words
A method as set forth in claim 1 wherein the mercury is radiated from a first source emitting 253.7 nm. radiation to bring the isotope from the 6 1 S 0 ground state to the 6 3 P 1 state.
Claim 4
Dependent Claim
39 words
A method as set forth in claim 2 wherein the mercury is radiated from a second source emitting 404.7 nm. radiation to bring the isotope from the 6 3 P 0 state to the 7 3 S 1 state.
Claim 5
Dependent Claim
16 words
A method as set forth in claim 3 wherein the mercury isotope is deactivated by nitrogen.
Claim 6
Dependent Claim
17 words
A method as set forth in claim 4 wherein the collecting step includes applying a biasing charge.
Claim 7
Dependent Claim
117 words
Apparatus for photoionizing naturally-occurring mercury to enrich a predetermined isotope of mercury comprising: an isotopically pure lamp radiation source means having radiation means for bringing the isotope from the 6 1 S 0 ground state to the 6 3 P 1 state, a vessel for containing the naturally-occurring mercury, a relatively large inert quenching molecule means feeding gas to the vessel to deactivate the isotope to bring the isotope to the long-lived 6 3 P 0 state, said source means further having means for bringing the isotope from the 6 3 P 0 state to the 7 3 S 1 state, and a powerful optical incoherent radiation source for photoionizing the isotope atom to enable collection thereof.
Claim 8
Dependent Claim
117 words
Apparatus for photoionizing naturally-occurring mercury to enrich a predetermined isotope of mercury comprising: an isotopically pure lamp radiation source means having radiation means for bringing the isotope from the 6 1 S 0 ground state to the 6 3 P 1 state, a vessel for containing the naturally-occurring mercury, a relatively large inert quenching molecule means feeding gas to the vessel to deactivate the isotope to bring the isotope to the long-lived 6 3 P 0 state, said source means further having means for bringing the isotope from the 6 3 P 0 state to the 7 3 S 1 state, and a powerful optical incoherent radiation source for photoionizing the isotope atom to enable collection thereof.
Claim 9
Dependent Claim
39 words
Apparatus as set forth in claim 6 wherein said radiation source means comprises a first source emitting 253.7 nm. radiation to bring the isotope from the 6 1 S 0 ground state to the 6 3 P 1 state.
Claim 10
Dependent Claim
39 words
Apparatus as set forth in claim 7 wherein said radiation source means further comprises a second source emitting 404.7 nm. radiation to bring the isotope from the 6 3 P 0 state to the 7 3 S 1 state.
Claim 11
Dependent Claim
16 words
Apparatus as set forth in claim 6 wherein said vessel comprises part of a flow system.
Claim 12
Dependent Claim
16 words
Apparatus as set forth in claim 6 wherein said vessel comprises part of a closed system.
Claim 13
Dependent Claim
15 words
Apparatus as set forth in claim 6 including means for collecting the predetermined ionic isotope.
Claim 14
Dependent Claim
21 words
Apparatus as set forth in claim 11 wherein said means for collecting comprises negatively charged collection plates associated with said vessel.
Claim 15
Dependent Claim
17 words
Apparatus as set forth in claim 11 wherein said means for collecting comprises a biased collection wire.
Claim 16
Dependent Claim
27 words
Apparatus as set forth in claim 11 including a set of first lamp sources and a set of second lamp sources alternately disposed in a circumferential focus.
References Cited (Backward Citations)
US3673406A
Cited
US4302676A
Cited
US4107537A
Cited
US4023038A
Cited
US4379252A
Cited
US4286152A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-03-09 | 1990-09-08 | 1991-03-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-03-09 | 1994-09-08 | 1995-03-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-03-09 | 1998-09-08 | 1999-03-10 | $7700.00 | Window Closed / Lapsed |