Phenylene group-containing organopolysiloxanes modified with functional groups and method of their preparation

Claim 2

Phenylene group-containing organopolysiloxanes modified by incorporation of at least one functional group comprising a plurality of identical or different units represented by the formula: ##STR15## where in each case all three possible isomers in relation to the position of the SiO 3/2 --R 1 substituents on the phenylene group can be present concurrently, in which the bridge groups R 1 represent the groups --CH 2 --CH 2 -- or CH 3 --CH<, and can be identical or different, X represents Cl, Br, CH 2 Cl, P(C 6 H 5 ) 2 , CH 2 P(C 6 H 5 ) 2 , and the free valences of the oxygen atoms are saturated by silicon atoms of other groups of ##STR16## and/or by cross-linking bridge groups: SiO.sub.4/2 or R'SiO.sub.3/2 or R.sub.2 'SiO.sub.2/2 or TiO.sub.4/2 or R'TiO.sub.3/2 or R.sub.2 'TiO.sub.2/2 or ZrO.sub.4/2 or R'ZrO.sub.3/2 or R.sub.2 'ZrO.sub.2/2 or AlO.sub.3/2 or R'AlO.sub.2/2 in which R' is a methyl or ethyl group, and/or by phenylene units of the general formula (1), in which the bridge groups R 1 have the same meaning as in formula (2) and can be identical or different, and the ratio of the sum of Si atoms of the units in formulas (1) and (2) to the bridge atoms silicon, titanium, zirconium, and aluminum can be 1:0 to 1:15.

Claim 3

A process for the preparation of the compounds according to claim 1, comprising reacting a phenylene group-containing organopolysiloxane, which has a plurality of identical of different units represented by the formula: ##STR17## where in each case all three possible isomers, in relation to the position of the SiO 3/2 --R 1 substituents on the phenylene group, can be present concurrently, in which the bridge groups R 1 represent the groups --CH 2 --CH 2 -- or CH 3 --CH< and can be identical or different, and the free valences of the oxygen atoms are saturated by silicon atoms of other groups of formula (2) and/or by cross-linking bridge groups: SiO.sub.4/2 or R'SiO.sub.3/2 or R.sub.2 'SiO.sub.2/2 or TiO.sub.4/2 or R'TiO.sub.3/2 or R.sub.2 'TiO.sub.2/2 or ZrO.sub.4/2 or R'ZrO.sub.3/2 or R.sub.2 'ZrO.sub.2/2 or AlO.sub.3/2 or R'AlO.sub.2/2 in which R' is a methyl or ethyl group, and the ratio of the sum of the Si atoms in formula (2) to the bridge atoms silicon, titanium, zirconium, and aluminum can be 1:0 to 1:15, with stoichiometric, reduced or excess amounts of a partially or totally dissolved, gaseous, liquid, or solid functional reagent containing the substituent X for the substitution of at least one hydrogen atom on the ring of said organopolysiloxane by the functional substituent X; in a solvent at temperatures of -80° C. to 200° C. at standard or gage pressure corresponding to the sum of the partial pressures of the components of the reaction mixture at the specific temperature, for a period from a few minutes to several days at temperatures of -78° C. to 200° C., separating the solid from the liquid phase.

Claim 4

The process according to claim 2 wherein the solid is separated from the liquid phase by distilling the solvent.

Claim 5

The process according to claim 2 wherein the solid is washed with another solvent and dried.

Claim 6

The process according to claim 2 wherein the solid is dried under a protective atmosphere or in vacuum.

Claim 7

The process according to claim 5 wherein the drying is carried out at a temperature of up to 200° C.

Claim 8

The process according to claim 2 wherein the product is tempered for 1 hour to 5 days at a temperature of 100° to 400° C. in air or under a protective gas at standard pressure, in vacuum or at gage pressure.

Claim 9

The process according to claim 2 wherein the dry, solid product is subject to grinding to produce a finely divided product.

Claim 10

The process according to claim 2, wherein the functional reagent is selected from the group consisting of chlorine, bromine, chloromethyl methyl ether, chloromethyl ethyl ether, formaldehyde, the methyl acetal or ethyl acetal of formaldehyde, paraformaldehyde in each case in combination with hydrogen chloride; and lithium, sodium and potassium diphenylphosphide.